IP Library Granted Patent US 10,279,219
Granted Patent B2
US 10,279,219 · App. 16/054,703 · Granted May 7, 2019

Graphene core for a golf ball

Inventors: Vijay Chavan (Vista, CA); David Bartels (Carlsbad, CA)
Assignee: Callaway Golf Company
A63B37/0051A63B37/0031A63B37/0033A63B37/0043A63B37/0045A63B37/0065A63B37/0069A63B37/0074A63B37/0075A63B37/0076A63B37/0092C01B32/182C08F36/06C08K3/042
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Quick Facts
Patent No.
US 10,279,219
App. No.
16/054,703
Granted
May 7, 2019
Kind
B2
Abstract

A golf ball with a core comprising polybutadiene and graphene is disclosed herein. The golf ball has a single core comprising polybutadiene and graphene. Alternatively, the golf ball has a dual core with an inner core comprising polybutadiene and graphene. Alternatively, the golf ball has a dual core with an outer core comprising polybutadiene and graphene.

Claims (44)

1. A golf ball comprising:

an inner core comprising a polybutadiene material;

an outer core comprising polybutadiene material and a graphene material in an amount ranging from 0.1 to 5.0 weight percent of the outer core, wherein the outer core has a flexural modulus ranging from 80 MPa to 95 MPa; and

a cover layer disposed over the outer core, the cover layer composed of an ionomer material;

wherein a dual core comprising the inner core and the outer core has a compression value ranging from 40 to 55.

2. The golf ball according to claim 1 wherein the graphene material ranges from 0.4 to 2.5 weight percent of the outer core.

3. The golf ball according to claim 1 wherein the graphene material ranges from 0.6 to 1.5 weight percent of the outer core.

4. The golf ball according to claim 1 further comprising:

an inner mantle layer disposed over the outer core, the inner mantle layer having a thickness ranging from 0.03 inch to 0.09 inch, the inner mantle layer composed of an ionomer material, the inner mantle layer material having a plaque Shore D hardness ranging from 34 to 55;

an outer mantle layer disposed over the inner mantle layer, the outer mantle layer having a thickness ranging from 0.025 inch to 0.050 inch;

and

wherein the cover layer is disposed over the outer mantle layer, the cover layer has a thickness ranging from 0.025 inch to 0.040 inch;

wherein the cover layer has a lower Shore D hardness than the outer mantle layer, the outer mantle layer has a higher Shore D hardness than the inner mantle layer, the outer core has a higher Shore D hardness than the inner mantle layer and the inner core.

5. The golf ball according to claim 1 further comprising:

an inner mantle layer disposed over the outer core, the inner mantle layer having a thickness ranging from 0.030 inch to 0.090 inch, the inner mantle layer material having a plaque Shore D hardness ranging from 30 to 50;

an outer mantle layer disposed over the inner mantle layer, the outer mantle layer having a thickness ranging from 0.025 inch to 0.070 inch, the outer mantle layer material having a plaque Shore D hardness ranging from 50 to 71, wherein the inner mantle is thicker than the outer mantle, and the outer mantle is harder than the inner mantle; and

wherein the cover layer is disposed over the outer mantle layer, the cover layer having a thickness ranging from 0.025 inch to 0.050 inch, wherein the cover layer has a Shore D hardness less than the hardness of the outer mantle layer, the outer mantle layer has a higher Shore D hardness than the inner mantle layer, the outer core has a higher Shore D hardness than the inner mantle layer and the inner core.

6. The golf ball according to claim 1 further comprising:

an inner mantle layer disposed over the outer core, the inner mantle layer having a thickness ranging from 0.070 inch to 0.090 inch, the inner mantle layer composed of an ionomer material, the inner mantle layer material having a plaque Shore D hardness ranging from 36 to 44;

an outer mantle layer disposed over the inner mantle layer, the outer mantle layer having a thickness ranging from 0.025 inch to 0.040 inch, the outer mantle layer composed of an ionomer material, the outer mantle layer material having a plaque Shore D hardness ranging from 65 to 71; and

wherein the cover layer is disposed over the outer mantle layer, the cover layer having a thickness ranging from 0.025 inch to 0.040 inch;

wherein the cover layer has a lower Shore D hardness than the outer mantle layer, the outer mantle layer has a higher Shore D hardness than the inner mantle layer, the outer core has a higher Shore D hardness than the inner mantle layer and the inner core.

7. The golf ball according to claim 1 wherein the graphene material has a surface area ranging from 400 m 2 /g to 800 m 2 /g.

8. The golf ball according to claim 1 further comprising:

an inner mantle layer disposed over the outer core, the inner mantle layer having a thickness ranging from 0.030 inch to 0.050 inch, the inner mantle layer material having a plaque Shore D hardness ranging from 30 to 40, the inner mantle layer composed of an ionomer material;

a first center mantle layer disposed over the inner mantle layer, the first center mantle layer having a thickness ranging from 0.030 inch to 0.050 inch, the first center mantle layer material having a plaque Shore D hardness ranging from 40 to 55, the first center mantle layer composed of a fully neutralized polymer material;

a second center mantle layer disposed over the second center mantle layer, the second center mantle layer having a thickness ranging from 0.030 inch to 0.050 inch, the second center mantle layer material having a plaque Shore D hardness ranging from 45 to 55, the second center mantle layer composed of a fully neutralized polymer material;

an outer mantle layer disposed over the second center mantle layer, the outer mantle layer having a thickness ranging from 0.030 inch to 0.050 inch, the outer mantle layer composed of a blend of ionomers, the outer mantle layer material having a plaque Shore D hardness ranging from 60 to 75; and

wherein the cover layer is disposed over the outer mantle layer, the cover layer having a thickness ranging from 0.025 inch to 0.040 inch.

9. The golf ball according to claim 1 wherein the outer core has a tensile modulus ranging from 8 MPa to 10 MPa.

10. The golf ball according to claim 1 wherein the graphene material has a surface area ranging from 15 m 2 /g to 50 m 2 /g.

11. The golf ball according to claim 1 wherein the graphene material has a surface area ranging from 300 m 2 /g to 400 m 2 /g.

12. A golf ball comprising:

an inner core comprising a polybutadiene and a graphene material in an amount ranging from 0.1 to 5.0 weight percent of the inner core;

an outer core comprising a polybutadiene and a graphene material in an amount ranging from 0.1 to 5.0 weight percent of the outer core, wherein the outer core has a flexural modulus ranging from 80 MPa to 95 MPa;

a mantle layer; and

a cover composed of a thermoplastic polyurethane material and having a Shore A hardness less than 100;

wherein a core comprising the inner core and the outer core has a compression value ranging from 40 to 55.

13. The golf ball according to claim 12 wherein the mantle layer comprises an inner mantle layer and an outer mantle layer.

14. The golf ball according to claim 12 wherein the graphene material in the outer core ranges from 0.4 to 2.5 weight percent of the outer core, and wherein the graphene material in the inner core ranges from 0.4 to 2.5 weight percent of the inner core.

15. The golf ball according to claim 12 wherein the outer core has a tensile modulus ranging from 8 MPa to 10 MPa.

16. The golf ball according to claim 12 wherein the graphene material has a surface area ranging from 15 m 2 /g to 50 m 2 /g.

17. The golf ball according to claim 12 wherein the graphene material has a surface area ranging from 300 m 2 /g to 400 m 2 /g.

18. The golf ball according to claim 12 wherein the graphene material has a surface area ranging from 400 m 2 /g to 800 m 2 /g.

Assignments (7)
SECURITY INTEREST Recorded May 17, 2023
From: TOPGOLF CALLAWAY BRANDS CORP.; OGIO INTERNATIONAL, INC.; TOPGOLF INTERNATIONAL, INC.; TRAVISMATHEW, LLC; WORLD GOLF TOUR, LLC
To: BANK OF AMERICA, N.A.
Reel/Frame 063692/0009 →
SECURITY AGREEMENT Recorded May 16, 2023
From: TOPGOLF CALLAWAY BRANDS CORP. (FORMERLY CALLAWAY GOLF COMPANY); OGIO INTERNATIONAL, INC.; TOPGOLF INTERNATIONAL, INC.; TRAVISMATHEW, LLC; WORLD GOLF TOUR, LLC
To: BANK OF AMERICA, N.A, AS COLLATERAL AGENT
Reel/Frame 063665/0176 →
RELEASE (REEL 048172 / FRAME 0001) Recorded Mar 17, 2023
From: BANK OF AMERICA, N.A.
To: TOPGOLF CALLAWAY BRANDS CORP. (F/K/A CALLAWAY GOLF COMPANY); OGIO INTERNATIONAL, INC.
Reel/Frame 063622/0187 →
CHANGE OF NAME Recorded Jan 25, 2023
From: CALLLAWAY GOLF COMPANY
To: TOPGOLF CALLAWAY BRANDS CORP.
Reel/Frame 062512/0585 →
SECURITY INTEREST Recorded Jan 23, 2019
From: CALLAWAY GOLF COMPANY; CALLAWAY GOLF SALES COMPANY; CALLAWAY GOLF BALL OPERATIONS, INC.; OGIO INTERNATIONAL, INC.; CALLAWAY GOLF INTERACTIVE, INC.; CALLAWAY GOLF INTERNATIONAL SALES COMPANY; TRAVISMATHEW, LLC
To: BANK OF AMERICA, N.A.
Reel/Frame 048110/0352 →
SECURITY AGREEMENT Recorded Jan 4, 2019
From: CALLAWAY GOLF COMPANY; OGIO INTERNATIONAL, INC.
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 048172/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 3, 2018
From: CHAVAN, VIJAY; BARTELS, DAVID
To: CALLAWAY GOLF COMPANY
Reel/Frame 046553/0748 →
Continuity (4)
Continuation 15705011 · Sep 14, 2017
Continuation In Part 15436169 · Feb 17, 2017
Provisional Application 62401034 · Sep 28, 2016
Related Publication 20180339199A1 · Nov 29, 2018