Ligand-containing conjugated microporous polymer and use thereof
The present invention relates to a ligand-containing conjugated microporous polymer, which is obtained by covalent coupling of a conjugated microporous polymer and a uranium complexing ligand. The conjugated microporous polymer comprises an aromatic ring and/or a heterocyclic ring. The uranium complexing ligand is selected from the group consisting of a compound with a group containing phosphorus, a compound with a group containing nitrogen, and a compound with a group containing sulfur. The invention further provides use of the ligand-containing conjugated microporous polymer as a uranium adsorbent. The ligand-containing conjugated microporous polymer the invention is capable of adsorbing the radioactive element uranium in strongly acidic and strong-radiation environments.
1. A ligand-containing conjugated microporous polymer, obtained by covalent coupling of a conjugated microporous polymer and a uranium complexing ligand, wherein the conjugated microporous polymer comprises an aromatic ring and/or a heterocyclic ring, and the uranium complexing ligand is selected from a compound with a group containing phosphorus, a compound with a group containing nitrogen, a compound with a group containing sulfur and any combination thereof,
wherein the uranium complexing ligand comprises one or more of the following groups:
wherein R 1 , R 2 , R 3 and R 4 are independently selected from alkyl, hydrogen, phenyl and a heterocyclic group.
2. The ligand-containing conjugated microporous polymer as claimed in claim 1 , wherein the conjugated microporous polymer is obtained by copolymerization of a first monomer and a second monomer, the first monomer and the second monomer being independently selected from the group consisting of benzene, a benzene derivative, fluorene, a fluorene derivative, porphyrin, a porphyrin derivative, pyridine, a pyridine derivative, thiophene and a thiophene derivative.
3. The ligand-containing conjugated microporous polymer as claimed in claim 2 , wherein the group containing phosphorus is selected from a phosphonic acid group, a phosphate ester group, a phosphonooxy group and any combination thereof.
4. The ligand-containing conjugated microporous polymer as claimed in claim 2 , wherein the group containing nitrogen is an amido group and/or a propanediamido group.
5. The ligand-containing conjugated microporous polymer as claimed in claim 1 , wherein the compound with a group containing phosphorus has a structure of
6. The ligand-containing conjugated microporous polymer as claimed in claim 1 , wherein the compound with a group containing nitrogen has a structure of
wherein R is CH 2 CH 3 , CH 2 CH 2 CH 3 , or phenyl.
7. The ligand-containing conjugated microporous polymer as claimed in claim 2 , wherein the polymer is synthesized by the step of:
copolymerizing the first monomer and the second monomer, and then reacting with the uranium complexing ligand compound, to obtain the ligand-containing conjugated microporous polymer, wherein the uranium complexing ligand compound is phosphonic acid, a phosphate ester, a phosphonooxy compound, an amide or a propanediamide compound.
8. The ligand-containing conjugated microporous polymer as claimed in claim 2 , wherein the polymer is synthesized by the step of:
reacting the first monomer with the uranium complexing ligand compound, and then copolymerizing with the second monomer, to obtain the ligand-containing conjugated microporous polymer, wherein the uranium complexing ligand compound is phosphonic acid, a phosphate ester, a phosphonooxy compound, an amide or a propanediamide compound.
9. A uranium adsorbent comprising the ligand-containing conjugated microporous polymer as claimed in claim 1 .
10. The uranium adsorbent as claimed in claim 9 , wherein the adsorbent is used in acidic and radiation environments.
11. The uranium adsorbent as claimed in claim 10 , wherein the acidic and radiation environments comprise an acid with a concentration of 4-6 mol/L and a radiation intensity of 200-1,000 KGy.