Semiconductor devices including ferroelectric materials
View Patent ↗A method of forming a ferroelectric memory cell. The method comprises forming an electrode material exhibiting a desired dominant crystallographic orientation. A hafnium-based material is formed over the electrode material and the hafnium-based material is crystallized to induce formation of a ferroelectric material having a desired crystallographic orientation. Additional methods are also described, as are semiconductor device structures including the ferroelectric material.
1. A semiconductor device comprising:
titanium nitride in a dominant (111) crystallographic orientation adjacent to a ferroelectric material, the ferroelectric material comprising a hafnium-based material in a dominant (200) crystallographic orientation; and
an electrode material adjacent to the ferroelectric material.
2. The semiconductor device of claim 1 , wherein a first surface of the ferroelectric material directly contacts the titanium nitride in the dominant (111) crystallographic orientation.
3. The semiconductor device of claim 1 , wherein a second surface of the ferroelectric material directly contacts the electrode material.
4. The semiconductor device of claim 1 , wherein the hafnium-based material comprises hafnium silicate, hafnium aluminate, hafnium zirconate, strontium-doped hafnium oxide, magnesium-doped hafnium oxide, gadolinium-doped hafnium oxide, yttrium-doped hafnium oxide, or combinations thereof.
5. The semiconductor device of claim 1 , wherein the hafnium-based material in the dominant (200) crystallographic orientation comprises hafnium oxide comprising from about 4 mol % to about 6 mol % silicon.
6. The semiconductor device of claim 1 , wherein the hafnium-based material in the dominant (200) crystallographic orientation comprises hafnium oxide comprising from about 5 mol % to about 7 mol % aluminum.
7. The semiconductor device of claim 1 , wherein the electrode material comprises crystalline titanium nitride.
8. The semiconductor device of claim 1 , wherein the electrode material comprises crystalline titanium nitride in a (001), (002), (100), (110), (111), or (200) crystallographic orientation, or combinations thereof.
9. A semiconductor device comprising:
a ferroelectric material comprising hafnium silicate in a dominant (200) crystallographic orientation, a surface of the ferroelectric material adjacent to a titanium nitride material in a dominant (111) crystallographic orientation and an opposing surface of the ferroelectric material adjacent to another material.
10. The semiconductor device of claim 9 , wherein the hafnium silicate comprises orthorhombic hafnium silicate.
11. The semiconductor device of claim 9 , wherein the another material comprises an electrode material.
12. The semiconductor device of claim 9 , wherein the another material comprises a different material than the titanium nitride material.
13. The semiconductor device of claim 9 , wherein the another material comprises a titanium nitride material.
14. A semiconductor device comprising:
a titanium nitride material in a dominant (111) crystallographic orientation adjacent to a ferroelectric material comprising hafnium silicate, the hafnium silicate comprising a dominant (200) crystallographic orientation; and
another titanium nitride material adjacent to the ferroelectric material.
15. The semiconductor device of claim 14 , wherein a surface of the ferroelectric material directly contacts the titanium nitride material in the dominant (111) crystallographic orientation and an opposing surface of the ferroelectric material directly contacts the another titanium nitride material.
16. The semiconductor device of claim 14 , wherein the ferroelectric material comprises orthorhombic hafnium silicate in the dominant (200) crystallographic orientation.
17. A semiconductor device comprising:
a ferroelectric material comprising hafnium silicate comprising a dominant (200) crystallographic orientation, a surface of the ferroelectric material adjacent to a titanium nitride material in a dominant (111) crystallographic orientation and an opposing surface of the ferroelectric material adjacent to another titanium nitride material.
18. The semiconductor device of claim 17 , further comprising a silicide material on the another titanium nitride material.
19. The semiconductor device of claim 17 , wherein a dipole mechanism of the ferroelectric material is oriented perpendicular to the titanium nitride material.
20. The semiconductor device of claim 17 , wherein the titanium nitride material and the another titanium nitride material exhibit the same crystallographic orientation.