Electrode device and metal foil manufacturing method using same
View Patent ↗Provided are a novel electrode device capable of simultaneously solving a problem of sludge coat covering an anode surface, and a problem of increase in the inter-electrode distance between the anode and cathode, and a method for manufacturing a metal foil using the same. Disclosed is an electrode device, used while being immersed in an electroconductive liquid, the electrode device comprising: a barrel which has an outer wall having plural through holes and can store a metal soluble in the liquid during current application; a shaft passing through the inside of the barrel and having a peripheral surface to which current can be applied; and a metal introducing portion for introducing the metal into the barrel, wherein the barrel rotates on its axis. The barrel is preferably provided with plural partition walls each extending inward from the outer wall and having a gap with respect to the peripheral surface of the shaft, and plural chambers separated in the peripheral direction of the shaft by the plural partition walls.
1. A method for manufacturing a metal foil, comprising:
immersing, in an electroconductive liquid, an electrode device in which a metal soluble in the liquid during current application is stored and a part of a peripheral surface of a drum having a different polarity from that of the electrode device, the electrode device comprising a barrel which has an outer wall having plural through holes and can store a metal soluble in the liquid during current application, a shaft passing through the inside of the barrel and having a peripheral surface to which current can be applied, and a metal introducing portion for introducing the metal into the barrel, wherein the barrel rotates on its axis;
applying current between the peripheral surface of the drum and the peripheral surface of the shaft of the electrode device while allowing the barrel of the electrode device to rotate on its axis and also allowing the drum to rotate on its axis in one direction;
electrodepositing a metal film containing a component of the metal on the peripheral surface of the drum; and
peeling the metal film from the peripheral surface of the drum, thereby forming the metal foil.
2. The method for manufacturing a metal foil according to claim 1 , which comprises a process for introducing the metal into the barrel of the electrode device during current application.
3. The method for manufacturing a metal foil according to claim 1 , wherein the barrel of the electrode device is intermittently rotated.
4. The method for manufacturing a metal foil according to claim 1 , wherein the metal contains 97% by mass or more of aluminum.