Processes and systems for removing a vinyl iodide impurity from a recycle gas stream in the production of ethylene oxide

1. A process comprising:

contacting at least a portion of a recycle gas stream comprising a vinyl iodide impurity with a guard bed material to yield a treated recycle gas stream, wherein the guard bed material comprises a support material, palladium and gold; and

contacting an epoxidation feed gas comprising ethylene, oxygen and at least a portion of the treated recycle gas stream with an epoxidation catalyst to yield an epoxidation reaction product comprising ethylene oxide.

2. The process of claim 1 , further comprising:

contacting at least a portion of the epoxidation reaction product comprising ethylene oxide with a lean absorbent in the presence of an iodide-containing carboxylation catalyst to yield a fat absorbent stream comprising ethylene carbonate and/or ethylene glycol and the recycle gas stream comprising the vinyl iodide impurity.

3. The process of claim 1 , wherein palladium is present in the guard bed material in an amount of from 0.1% to 3% by weight.

4. The process of claim 1 , wherein palladium is present in the guard bed material in an amount of from 0.8% to 2.2% by weight.

5. The process of claim 1 , wherein gold is present in the guard bed material in an amount of from 0.1% to 3% by weight.

6. The process of any one of claim 1 , wherein gold is present in the guard bed material in an amount of from 0.5% to 1.5% by weight.

7. The process of claim 1 , wherein the support material comprises silica.

8. The process of claim 1 , wherein the treated recycle gas stream comprises no more than 20 ppbv of vinyl iodide.

9. The process of claim 1 , wherein the treated recycle gas stream comprises no more than 1 ppbv of vinyl iodide.

10. The process of any claim 1 , wherein the treated recycle gas stream is supplied to a carbon dioxide absorber before being contacted with the epoxidation catalyst.

11. A reaction system for the production of ethylene carbonate and/or ethylene glycol comprising:

a recycle gas loop fluidly connected to a source of ethylene and oxygen;

an epoxidation reactor comprising an epoxidation catalyst, an inlet, and an outlet, wherein the inlet of the epoxidation reactor is fluidly connected to the recycle gas loop;

an ethylene oxide absorber comprising an iodide-containing carboxylation catalyst, an inlet, and an outlet, wherein the outlet of the epoxidation reactor is fluidly connected to the inlet of the ethylene oxide absorber, the outlet of the ethylene oxide absorber is fluidly connected to the recycle gas loop, and the ethylene oxide absorber is configured to produce a recycle gas stream comprising a vinyl iodide impurity and a fat absorbent stream comprising ethylene carbonate and/or ethylene glycol; and

a guard bed system comprising an inlet, an outlet, and one or more guard bed vessels comprising a guard bed material, wherein the guard bed material comprises a support material, palladium and gold, wherein the inlet and the outlet of the guard bed system is fluidly connected to the recycle gas loop, and the guard bed material is configured to remove at least a portion of the vinyl iodide impurity from at least a portion of the recycle gas stream.

12. The reaction system of claim 11 , further comprising a carbon dioxide absorber fluidly connected to the recycle gas loop.

13. The reaction system of claim 11 , wherein the guard bed system comprises two or more guard bed vessels.

14. The reaction system of claim 11 , wherein palladium is present in the guard bed material in an amount of from 0.1% to 3% by weight.

15. The reaction system of claim 11 , wherein gold is present in the guard bed material in an amount of from 0.1% to 3% by weight.