Methods for manufacturing azoic pigments

1. A method for manufacturing an azoic pigment, the method comprising the steps of

i) obtaining a slurry of an azoic pigment, the slurry including residual primary aromatic amine (PAA);

ii) derivatization of the residual PAA in the slurry;

iii) encapsulation of the slurry;

iv) final processing of the slurry, the final processing including forming PAA migration free azoic pigment;

wherein the derivatization and encapsulation synergistically reduce PAA content thereby inhibiting migration of PAA from the pigment to a surface in contact.

2. The method of claim 1 , wherein the method further comprises an acidification or basification of the slurry.

3. The method of claim 1 , wherein the method further comprises a method of working up the slurry, the method comprising the steps of filtering and washing the pigment to obtain a pigment paste, and reslurrying the pigment paste by adding an amount of solvent; stirring said dispersion in a temperature range comprised between 10° C. and 180° C.

4. The method of claim 3 , wherein the working up of the slurry is performed prior to step ii).

5. The method of claim 3 , wherein the working up of the slurry performed prior to step iii).

6. The method of claim 2 , wherein the acidification or basification step is performed after step i), or after step ii) or after step iii).

7. The method of claim 1 , wherein the derivatization of the slurry includes addition of a derivatization agent into the slurry, wherein the derivatization agent is a haloalkane, an aldehyde, a ketone, an acyl halide, a sulfonyl halide, an organic acid anhydride, an epoxide, an epoxy wax, an isocyanate, an isothiocyanate, a (substituted) acrylic acid, a (substituted) acrylic acid ester, a (substituted) acrylamide, a (substituted) unsaturated aldehyde, a (substituted) unsaturated ketone, a (substituted) ethylene sulfonate, a lactone, a lactam, a haloalkane, hydrogen peroxide, sodium nitrite, an organic peroxide, phosgene, thionyl chloride, carbonyl diimidazole, or any combination thereof.

8. The method of claim 1 , wherein encapsulation includes the addition of a monomer, or a set of monomers to the slurry.

9. The method of claim 8 , wherein the monomer comprises one or more functional polymerizable groups selected from a vinyl group or an unsaturated carboxylic group.

10. The method of claim 7 , wherein the derivatization agent is a bifunctional agent for the derivatization and encapsulation.

11. The method of claim 2 , wherein the acidification or basification is performed by adding an acid selected from the group of hydrogen halides, sulfuric acid, sulfurous acid, phosphorous acid, phosphoric acid, phosphorous acid, hypophosphorous acid, nitric acid, sulphamic acid, carboxylic acids, or organic sulfonic acids, or a base selected from the group of caustic soda, potassium hydroxide, lithium hydroxide, calcium hydroxide or sodium (bi)carbonate.

12. The method of claim 6 , wherein the reslurrying of azo based pigment is carried out in a temperature range comprised between 10° C. and 180° C.

13. The method of claim 3 , wherein the stirring said dispersion occurs in the temperature range between 15° C. to 60° C. until an equilibrium on particle size distribution is reached.

14. The method of claim 8 , wherein the set of monomers comprises [A] one or more monomers selected from a halogen leaving group, an organic acid, an ester, an acyl halogenide, an organic acid anhydride, a sulfonyl halide, a nitrile, an isocyanate, an isothiocyanate, a ketone, an aldehyde, an epoxide, an organosilane, a halosilane, an organomodified siloxane, a lactone, a lactam, a vinyl group and [B] one or more monomers selected from an alcohol, a thiol, an amine, or any combination thereof.

15. The method of claim 3 , wherein the stirring said dispersion occurs in the temperature range between 15° C. to 60° C. until particle size at equilibrium of the pigment paste is less than 5 μm.

16. The method of claim 9 , wherein the one of more functional polymerizable groups comprise an acrylate group, an acrylamide group, a methacrylate group, an unsaturated sulfonic group, an organosilane group, a halosilane group, an organomodified siloxane group, an isocyanate group, an epoxide group, a lactone, a lactam, or any combination thereof.

17. The method of claim 11 , wherein the organic sulfonic acids comprise methanesulfonic acid.

18. A pigment obtained from a method of claim 1 , suitable for being loaded into or onto a substrate comprising kraft paper, layered paper, meat paper, regenerated cellulose, board, (L)LDPE (linear low density polyethylene), PP (polypropylene), cellulose acetate, PET (polyethylene terephthalate), PA (polyamide), PVC (polyvinyl chloride), silicone, or nonwoven fabric, or any combination thereof.

19. The method of claim 14 , wherein the set of monomers comprise a dual layer.

20. The method of claim 16 , wherein the one or more polymerizable groups comprise a dual layer coating.

21. A pigment obtained from a method of claim 1 , suitable for being incorporated into an ink in a range of 0.1-50% by weight with respect to the ink.

22. A pigment obtained from a method of claim 1 , suitable for being incorporated into water-based acrylic, mineral offset, vegetable offset, polyamide, polyvinylbutyral, polyvinylchloride, solvent based nitrocellulose, cellulose acetate or UV-curable inks.

23. The method of claim 18 , wherein the substrate is a multi-layered material.