IP Library Granted Patent US 11,098,141
Granted Patent B2
US 11,098,141 · App. 16/063,572 · Granted Aug 24, 2021

Articles with improved optical properties

Inventors: Jingbo Wang (Linz, AT); Markus Gahleitner (Neuhofen/Krems, AT); Katja Klimke (Abu Dhabi, AE); Juliane Braun (Linz, AT); Pauli Leskinen (Helsinki, FI)
Assignee: BOREALIS AG
C08F110/06C08F2/001C08F4/6435C08F4/6494C08K5/0083C08L23/14C08F2500/12C08L2201/10C08L2203/10C08L2205/025C08L2205/24C08L2308/00C08L2314/02
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Quick Facts
Patent No.
US 11,098,141
App. No.
16/063,572
Granted
Aug 24, 2021
Kind
B2
Abstract

Moulded articles comprising a polypropylene homopolymer with rather high melt flow rate, high stiffness, improved optical properties and an advantageous balance between stiffness and optical properties.

Claims (22)

1. Moulded article comprising a polypropylene homopolymer, wherein the polypropylene homopolymer is polymerised in the presence of a Ziegler-Natta catalyst and wherein the polypropylene homopolymer:

a) comprises 0.40-0.90 wt % of ethylene and/or a C4-C10 α-olefin determined according to 13 C-NMR,

b) comprises at least one α-nucleating agent,

c) is free of phthalic acid esters as well as their respective decomposition products,

d) has a MFR230/2.16 determined according to ISO1133 in the range of 20-200 g/10 min, and

e) has a haze of ≤42% (ASTM 1003-D) when measured on 1 mm plaques,

wherein the Ziegler-Natta catalyst is self-supported by being free of any external support material and comprises:

a) compounds of a transition metal of Group 4 to 6 of IUPAC,

b) a Group 2 metal compound,

c) an internal donor, wherein said internal donor is a citraconate,

d) a co-catalyst, and

e) optionally, an external donor.

2. Moulded article according to claim 1 , wherein the at least one α-nucleating agent is either a polymeric nucleating agent and/or a soluble nucleating agent selected from sorbitol derivatives, nonitol derivatives, and benzene-trisamides.

3. Moulded article according to claim 1 , wherein the polypropylene homopolymer:

has a Heat Distortion Temperature (ISO 75B) of at least 90° C.

4. Moulded article according to claim 1 , wherein the polypropylene homopolymer:

has a haze of ≤35% when measured on 1 mm plaques.

5. Moulded article according to claim 1 , wherein the polypropylene homopolymer:

has top load of 360 N or more.

6. Moulded article according to claim 1 , wherein the moulded article is an injection moulded article.

7. Moulded article according to claim 1 , wherein the moulded article has a wall thickness of 2 mm or below.

8. Moulded article according to claim 1 , wherein the moulded article is a container.

Assignments (2)
CHANGE OF ADDRESS Recorded Feb 23, 2022
From: BOREALIS AG
To: BOREALIS AG
Reel/Frame 059219/0949 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 27, 2018
From: WANG, JINGBO; GAHLEITNER, MARKUS; KLIMKE, KATJA; BRAUN, JULIANE; LESKINEN, PAULI
To: BOREALIS AG
Reel/Frame 046480/0934 →