Articles with improved optical properties
Moulded articles comprising a polypropylene homopolymer with rather high melt flow rate, high stiffness, improved optical properties and an advantageous balance between stiffness and optical properties.
1. Moulded article comprising a polypropylene homopolymer, wherein the polypropylene homopolymer is polymerised in the presence of a Ziegler-Natta catalyst and wherein the polypropylene homopolymer:
a) comprises 0.40-0.90 wt % of ethylene and/or a C4-C10 α-olefin determined according to 13 C-NMR,
b) comprises at least one α-nucleating agent,
c) is free of phthalic acid esters as well as their respective decomposition products,
d) has a MFR230/2.16 determined according to ISO1133 in the range of 20-200 g/10 min, and
e) has a haze of ≤42% (ASTM 1003-D) when measured on 1 mm plaques,
wherein the Ziegler-Natta catalyst is self-supported by being free of any external support material and comprises:
a) compounds of a transition metal of Group 4 to 6 of IUPAC,
b) a Group 2 metal compound,
c) an internal donor, wherein said internal donor is a citraconate,
d) a co-catalyst, and
e) optionally, an external donor.
2. Moulded article according to claim 1 , wherein the at least one α-nucleating agent is either a polymeric nucleating agent and/or a soluble nucleating agent selected from sorbitol derivatives, nonitol derivatives, and benzene-trisamides.
3. Moulded article according to claim 1 , wherein the polypropylene homopolymer:
has a Heat Distortion Temperature (ISO 75B) of at least 90° C.
4. Moulded article according to claim 1 , wherein the polypropylene homopolymer:
has a haze of ≤35% when measured on 1 mm plaques.
5. Moulded article according to claim 1 , wherein the polypropylene homopolymer:
has top load of 360 N or more.
6. Moulded article according to claim 1 , wherein the moulded article is an injection moulded article.
7. Moulded article according to claim 1 , wherein the moulded article has a wall thickness of 2 mm or below.
8. Moulded article according to claim 1 , wherein the moulded article is a container.