IP Library Granted Patent US 11,420,419
Granted Patent B2
US 11,420,419 · App. 16/063,808 · Granted Aug 23, 2022

Austenite-based molten aluminum-plated steel sheet having excellent properties of plating and weldability

Inventors: Young-Ha Kim (Gwangyang-si, KR); Hyeon-Seok Hwang (Gwangyang-si, KR); Kwang-Geun Chin (Gwangyang-si, KR); Heung-Yun Kim (Gwangyang-si, KR)
Assignee: POSCO
B32B15/012B32B15/04B32B15/043B32B15/18C21D6/005C21D6/008C21D9/46C22C21/00C22C21/02C22C21/04C22C21/06C22C38/008C22C38/02C22C38/04C22C38/06C22C38/10C22C38/12C22C38/14C22C38/18C22C38/22C22C38/24C22C38/26C22C38/28C22C38/44C22C38/46C22C38/48C22C38/50C22C38/60C23C2/02C23C2/12C23C2/28C23C2/40C23C28/021C23C28/022C23C28/023C23C30/00C23C30/005C21D2211/001C21D2211/004Y10T428/12757Y10T428/12951Y10T428/12958Y10T428/12972Y10T428/2495Y10T428/24959Y10T428/24967Y10T428/26Y10T428/263Y10T428/264Y10T428/265
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Quick Facts
Patent No.
US 11,420,419
App. No.
16/063,808
Granted
Aug 23, 2022
Kind
B2
Abstract

Provided are an austenite-based molten aluminum-plated steel sheet comprising: a steel plate which contains, by weight %, 0.3 to 0.9% of C, 12 to 25% of Mn, 0.5 to 2.5% of Si, 0.3 to 3.0% of Al, 0.01 to 0.5% of Ti, 0.05 to 0.5% of V, 0.01-0.5% of Mo, 0.01-0.2% of Sn, 0.001-0.1% of Co, and 0.001-0.1% of W, the remainder being Fe and unavoidable impurities; and a molten aluminum-based plated layer formed on a surface of the steel plate, and a method for producing the same.

Claims (31)

1. An austenite-based steel plate having an aluminum-based plated layer, the austenite-based steel plate comprising:

a base steel plate including 0.3 to 0.9% of carbon (C), 12 to 25% of manganese (Mn), 0.5 to 2.5% of silicon (Si), 0.3 to 3.0% of aluminum (Al), 0.01 to 0.5% of titanium (Ti), 0.05 to 0.5% of vanadium (V), 0.01 to 0.5% of molybdenum (Mo), 0.01 to 0.2% of tin (Sn), 0.001 to 0.1% of cobalt (Co), 0.001 to 0.1% of tungsten (W), and a balance of iron (Fe) and inevitable impurities, on a wt % basis; and

an aluminum-based plated layer formed on a surface of the base steel plate,

wherein the base steel plate includes carbonitride having an average equivalent circular diameter of 100 nm or less.

2. The austenite-based steel plate of claim 1 , wherein the base steel plate further includes one or more selected from the group consisting of 0.5% or less of chromium (Cr) (excluding 0%), 0.05% or less of niobium (Nb) (excluding 0%), and 0.1% or less of antimony (Sb) (excluding 0%), on a wt % basis.

3. The austenite-based steel plate of claim 1 , wherein a sum of the W and the Co is 0.01% or more.

4. The austenite-based steel plate of claim 1 , wherein a sum of the Mo and the V is 0.6% or more.

5. The austenite-based steel plate of claim 1 , wherein the base steel plate has a yield ratio (yield strength/tensile strength) of 0.68 or more.

6. The austenite-based steel plate of claim 1 , wherein the aluminum-based plated layer includes Si of 7 to 12 wt %.

7. The austenite-based steel plate of claim 6 , wherein the aluminum-based plated layer further includes Mg of 3 to 5 wt %.

8. The austenite-based steel plate of claim 1 , further comprising:

an Al-Fe-Si-Mn-based alloy layer formed on a boundary surface between the base steel plate and the aluminum-based plated layer,

wherein the Al-Fe-Si-Mn-based alloy layer includes Fe and Mn, a sum of which is 23 wt % or more.

9. The austenite-based steel plate of claim 8 , wherein, when a thickness of the Al-Fe-Si-Mn-based alloy layer is x and a thickness of the aluminum-based plated layer is y, y/x is 1 or more or 6 or less.

10. The austenite-based steel plate of claim 8 , wherein an Al-Si-Mg alloy phase with a thickness of 1μm or less (excluding 0μm) are intermittently formed on a boundary surface between the Al-Fe-Si-Mn-based alloy layer and the aluminum-based plated layer at an interval of 2μm or less (excluding 0μm) in a horizontal direction of the base steel plate.

11. An austenite-based steel plate having an aluminum-based plated layer, the austenite-based steel plate comprising:

a base steel plate including 0.3 to 0.9% of carbon (C), 12 to 25% of manganese (Mn), 0.5 to 2.5% of silicon (Si), 0.3 to 3.0% of aluminum (Al), 0.01 to 0.5% of titanium (Ti), 0.05 to 0.5% of vanadium (V), 0.01 to 0.5% of molybdenum (Mo), 0.01 to 0.2% of tin (Sn), 0.001 to 0.1% of cobalt (Co), 0.001 to 0.1% of tungsten (W), and a balance of iron (Fe) and inevitable impurities, on a wt % basis; and

an aluminum-based plated layer formed on a surface of the base steel plate,

wherein the base steel plate has a yield ratio (yield strength/tensile strength) of 0.68 or more.

12. The austenite-based steel plate of claim 11 , wherein the base steel plate further includes one or more selected from the group consisting of 0.5% or less of chromium (Cr) (excluding 0%), 0.05% or less of niobium (Nb) (excluding 0%), and 0.1% or less of antimony (Sb) (excluding 0%), on a wt % basis.

13. The austenite-based steel plate of claim 11 , wherein a sum of the W and the Co is 0.01% or more.

14. The austenite-based steel plate of claim 11 , wherein a sum of the Mo and the V is 0.6% or more.

15. The austenite-based steel plate of claim 11 , wherein the aluminum-based plated layer includes Si of 7 to 12 wt %.

16. The austenite-based steel plate of claim 15 , wherein the aluminum-based plated layer further includes Mg of 3 to 5 wt %.

17. An austenite-based steel plate having an aluminum-based plated layer, the austenite-based steel plate comprising:

a base steel plate including 0.3 to 0.9% of carbon (C), 12 to 25% of manganese (Mn), 0.5 to 2.5% of silicon (Si), 0.3 to 3.0% of aluminum (Al), 0.01 to 0.5% of titanium (Ti), 0.05 to 0.5% of vanadium (V), 0.01 to 0.5% of molybdenum (Mo), 0.01 to 0.2% of tin (Sn), 0.001 to 0.1% of cobalt (Co), 0.001 to 0.1% of tungsten (W), and a balance of iron (Fe) and inevitable impurities, on a wt % basis;

an aluminum-based plated layer formed on a surface of the base steel plate; and

an Al-Fe-Si-Mn-based alloy layer formed on a boundary surface between the base steel plate and the aluminum-based plated layer,

wherein the Al-Fe-Si-Mn-based alloy layer includes Fe and Mn, a sum of which is 23 wt % or more.

18. The austenite-based steel plate of claim 17 , wherein, when a thickness of the Al-Fe-Si-Mn-based alloy layer is x and a thickness of the aluminum-based plated layer is y, y/x is 1 or more or 6 or less.

19. The austenite-based steel plate of claim 17 , wherein an Al-Si-Mg alloy phase with a thickness of 1μm or less (excluding 0μm) are intermittently formed on a boundary surface between the Al-Fe-Si-Mn-based alloy layer and the aluminum-based plated layer at an interval of 2μm or less (excluding 0μm) in a horizontal direction of the base steel plate.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 26, 2022
From: POSCO HOLDINGS INC.
To: POSCO CO., LTD
Reel/Frame 061778/0785 →
CHANGE OF NAME Recorded Sep 28, 2022
From: POSCO
To: POSCO HOLDINGS INC.
Reel/Frame 061561/0923 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 19, 2018
From: KIM, YOUNG-HA; HWANG, HYEON-SEOK; CHIN, KWANG-GEUN; KIM, HEUNG-YUN
To: POSCO
Reel/Frame 046128/0352 →
Priority Claims (1)
KR 10-2015-0186138 · Dec 24, 2015 · national
Continuity (1)
Related Publication 20200262181A1 · Aug 20, 2020