IP Library Granted Patent US 11,186,666
Granted Patent B2
US 11,186,666 · App. 16/064,307 · Granted Nov 30, 2021

Ethylene-vinyl alcohol copolymer composition pellets, and multilayer structure

Inventors: Daichi Nishimura (Osaka, JP); Takuya Nakajima (Osaka, JP); Masahiko Taniguchi (Osaka, JP); Koji Yamada (Osaka, JP)
Assignee: MITSUBISHI CHEMICAL CORPORATION
C08F216/06B29B9/12B32B27/28B32B27/306B65D65/20B65D65/40C08K3/08C08K3/11C08L29/04B29B9/06C08F2800/10C08K2003/0856
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Quick Facts
Patent No.
US 11,186,666
App. No.
16/064,307
Granted
Nov 30, 2021
Kind
B2
Abstract

An ethylene-vinyl alcohol copolymer composition is provided, which contains an ethylene-vinyl alcohol copolymer and an iron compound, wherein the ethylene-vinyl alcohol copolymer has an ethylene content of 20 to 60 mol %, wherein the iron compound is present in a proportion of 0.01 to 100 ppm on a metal basis based on the weight of the ethylene-vinyl alcohol copolymer composition.

Claims (23)

1. A pellet of an ethylene-vinyl alcohol copolymer composition comprising:

an ethylene-vinyl alcohol copolymer; and

an iron compound;

wherein the ethylene-vinyl alcohol copolymer has an ethylene content of 20 to 60 mol %;

wherein the iron compound is present in a proportion of 0.01 to 40 ppm on a metal basis based on weight of the ethylene-vinyl alcohol copolymer composition; and

wherein the ethylene-vinyl alcohol copolymer is present in a proportion of not less than 90 wt. % in the ethylene-vinyl alcohol copolymer composition.

2. A multilayer structure comprising at least one layer comprising an ethylene-vinyl alcohol copolymer composition,

wherein the ethylene-vinyl alcohol copolymer composition comprises an ethylene-vinyl alcohol copolymer and an iron compound,

wherein the ethylene-vinyl alcohol copolymer has an ethylene content of 20 to 60 mol %; and

wherein the iron compound is present in a proportion of 0.01 to 40 ppm on a metal basis based on weight of the ethylene-vinyl alcohol copolymer composition; and

wherein the ethylene-vinyl alcohol copolymer is present in a proportion of not less than 90 wt. % in the ethylene-vinyl alcohol copolymer composition.

3. The pellet of an ethylene-vinyl alcohol copolymer composition according to claim 1 , wherein the pellet has a water content of 0.01 to 0.35 wt. %.

4. The pellet of an ethylene-vinyl alcohol copolymer composition according to claim 1 , wherein the ethylene-vinyl alcohol copolymer has a vinyl ester saponification degree of 90 to 100 mol %.

5. The pellet of an ethylene-vinyl alcohol copolymer composition according to claim 1 , wherein the ethylene-vinyl alcohol copolymer has a melt flow rate of 0.5 to 100 g/10 minutes as measured at 210° C. with a load of 2,160 g.

6. A method comprising:

providing a pellet of an ethylene-vinyl alcohol copolymer composition according to claim 1 , and

melt-forming a product from the pellet.

7. The method according to claim 6 , wherein at least one layer of a multilayer structure is melt-formed by using the pellet of an ethylene-vinyl alcohol copolymer composition.

8. The pellet of an ethylene-vinyl alcohol copolymer composition according to claim 1 , wherein the iron compound is at least one selected from ferric oxide, ferrosoferric oxide, ferrous chloride, ferric chloride, ferrous hydroxide, ferric hydroxide, ferrous oxide, and iron phosphate.

9. The pellet of an ethylene-vinyl alcohol copolymer composition according to claim 1 , wherein a lubricant is applied to a surface of the pellet of an ethylene-vinyl alcohol copolymer composition.

10. The multilayer structure according to claim 2 , wherein the ethylene-vinyl alcohol copolymer has a vinyl ester saponification degree of 90 to 100 mol %.

11. The multilayer structure according to claim 2 , wherein the ethylene-vinyl alcohol copolymer has a melt flow rate of 0.5 to 100 g/10 minutes as measured at 210° C. with a load of 2160 g.

12. The multilayer structure according to claim 2 , wherein the iron compound is at least one selected from ferric oxide, ferrosoferric oxide, ferrous chloride, ferric chloride, ferrous hydroxide, ferric hydroxide, ferrous oxide, and iron phosphate.

Assignments (2)
MERGER Recorded May 2, 2019
From: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 049110/0285 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 20, 2018
From: NISHIMURA, DAICHI; NAKAJIMA, TAKUYA; TANIGUCHI, MASAHIKO; YAMADA, KOJI
To: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.
Reel/Frame 046148/0438 →