Stainless steel for polymer fuel cell separation plate having improved hydrophilicity and contact resistance and method for manufacturing same
Stainless steel with improved hydrophilicity and contact resistance for a Polymer Electrolyte Membrane Fuel Cell (PEMFC) separator, and a method of manufacturing the stainless steel Stainless steel are disclosed. Stainless steel for a Polymer Electrolyte Membrane Fuel Cell (PEMFC) separator according to an embodiment of the present disclosure may include: by weight percent, 0 to 0.02% of C (excluding 0), 0 to 0.02% of N (excluding 0), 0 to 0.25% of Si (excluding 0), 0 to 0.2% of Mn (excluding 0), 0 to 0.04% of P (excluding 0), 0 to 0.02% of S (excluding 0), 20 to 34% of Cr, 0 to 0.6% of V (excluding 0), 0 to 0.5% of Ti (excluding 0), 0 to 0.5% of Nb (excluding 0), and the remainder comprising iron (Fe) and other unavoidable impurities, wherein a plurality of patterns may be formed on a surface of the stainless steel in a direction that is inclined with respect to a rolling direction, and the plurality of patterns are arranged repeatedly in the rolling direction.
1. Stainless steel with improved hydrophilicity and contact resistance for a Polymer Electrolyte Membrane Fuel Cell (PEMFC) separator, the stainless steel comprising:
by weight percent, 0 to 0.02% of C (excluding 0), 0 to 0.02% of N (excluding 0), 0 to 0.25% of Si (excluding 0), 0 to 0.2% of Mn (excluding 0), 0 to 0.04% of P (excluding 0), 0 to 0.02% of S (excluding 0), 20 to 34% of Cr, 0 to 0.6% of V (excluding 0), 0 to 0.5% of Ti (excluding 0), 0 to 0.5% of Nb (excluding 0), and the remainder comprising iron (Fe) and other unavoidable impurities,
wherein a plurality of patterns are formed on a surface of the stainless steel in a direction that is inclined with respect to a rolling direction, and the plurality of patterns are arranged repeatedly in the rolling direction, and
wherein micro pits are formed on the surface of the stainless steel, and the patterns have different area fractions of the micro pits.
2. The stainless steel of claim 1 , wherein the patterns are formed in a direction that is inclined at 35 to 60 degrees with respect to the rolling direction.
3. The stainless steel of claim 1 , wherein the patterns are parallel to each other in the rolling direction.
4. The stainless steel of claim 1 , wherein the patterns intersect with each other in the rolling direction.
5. The stainless steel of claim 1 , wherein the patterns have a width of 0.5 to 3 mm.
6. The stainless steel of claim 1 , wherein the area fractions of the micro pits formed on the patterns are in a range of 2 to 50%.
7. The stainless steel of claim 6 , wherein a difference between the area fractions of the micro pits of the patterns is 2% or more.
8. The stainless steel of claim 1 , wherein an average diameter of the micro pits formed on the patterns is in a range of 0.05 to 20 μm.
9. The stainless steel of claim 1 , further comprising molybdenum (Mo) of 0.05 to 2.5 wt %.
10. The stainless steel of claim 1 , wherein a ratio of Cr hydroxide/Cr oxide contained in the passive film of the stainless steel is in a range of 0.5 to 1.7.
11. The stainless steel of claim 1 , wherein a thickness of the passive film of the stainless steel is 3.5 nm or thinner (except for zero).
12. The stainless steel of claim 1 , wherein a contact angle α of the surface of the stainless steel is 70 degrees or smaller.
13. The stainless steel of claim 1 , wherein contact resistance of the stainless steel is 10 mΩcm 2 or smaller.
14. The stainless steel of claim 1 , wherein a corrosion potential of the passive film of the stainless steel is 0.3 V (SCE) or higher.