Method for manufacturing grain-oriented electrical steel sheet
A manufacturing method of an oriented electrical steel sheet according to an exemplary embodiment of the present invention includes: a step of manufacturing a steel slab including one kind or more among Si at 2 to 7%, Sn at 0.03 to 0.10%, and Sb at 0.01 to 0.05% as wt %; a step of hot-rolling the steel slab to manufacture a hot rolled sheet; a step of cold-rolling the hot rolled sheet to manufacture a cold rolled sheet; a step of decarburizing and nitriding the cold rolled sheet for primary recrystallization annealing; a step of coating and drying an annealing separating agent on the primary recrystallization-annealed cold rolled sheet; and a step of secondary recrystallization-annealing the cold rolled sheet coated with the annealing separating agent.
1. A manufacturing method of an oriented electrical steel sheet, comprising:
a step of manufacturing a steel slab including one kind or more among Si at 2 to 7%, Sn at 0.03 to 0.10%, and Sb at 0.01 to 0.05% as wt %;
a step of hot-rolling the steel slab to manufacture a hot rolled sheet;
a step of cold-rolling the hot rolled sheet to manufacture a cold rolled sheet;
a step of decarburizing and nitriding the cold rolled sheet for primary recrystallization annealing;
a step of coating and drying an annealing separating agent on the primary recrystallization-annealed cold rolled sheet; and
a step of secondary recrystallization-annealing the cold rolled sheet coated with the annealing separating agent,
wherein the primary recrystallization annealing is performed by passing through a heating zone, a primary soaking zone, and a secondary soaking zone, and satisfies Equation 1, Equation 2 and Equation 3 below when each dew point is t1, t2, and t3, the annealing separating agent includes a magnesium oxide or a magnesium hydroxide, and a metal iodide, and a forsterite (Mg 2 SiO 4 ) film is removed in the step of the secondary recrystallization annealing:
50° C.≤ t 1< t 2< t 3≤70° C. (1)
t 2− t 1≥4° C. (2)
t 3− t 2≥4° C. (3).
2. The manufacturing method of the oriented electrical steel sheet of claim 1 , wherein after the primary recrystallization annealing, a mother material metal layer, a segregation layer, and an oxidation layer are sequentially formed, and the segregation layer includes 50 to 100 wt % of one kind or more of Sb and Sn.
3. The manufacturing method of the oriented electrical steel sheet of claim 2 , wherein the thickness of the oxidation layer is from 0.5 to 2.5 μm, and an oxygen amount of the oxidation layer is 600 ppm or more.
4. The manufacturing method of the oriented electrical steel sheet of claim 1 , wherein the annealing separating agent includes the magnesium oxide or magnesium hydroxide at 100 parts by weight and the metal iodide at 5 to 20 parts by weight.
5. The manufacturing method of the oriented electrical steel sheet of claim 1 , wherein a metal forming the metal iodide includes one selected from Ag, Co, Cu, and Mo, and combinations thereof.
6. The manufacturing method of the oriented electrical steel sheet of claim 1 , wherein the step of the secondary recrystallization annealing is performed in a temperature range of 650 to 1200° C.
7. The manufacturing method of the oriented electrical steel sheet of claim 6 , wherein in the step of the secondary recrystallization annealing, the cold rolled sheet is heated from 650 to 1200° C. with a temperature raising rate of 0.1 to 20° C./h, and is maintained for 20 hours or more in a temperature range of 1150 to 1250° C. after reaching 1200° C.
8. The manufacturing method of the oriented electrical steel sheet of claim 1 , wherein a surface roughness of the oriented electrical steel sheet is 0.8 μm or less as a Ra value.
9. The manufacturing method of the oriented electrical steel sheet of claim 8 , wherein the surface of the oriented electrical steel sheet includes protrusions and depressions parallel to a rolling direction.