IP Library Granted Patent US 11,508,501
Granted Patent B2
US 11,508,501 · App. 16/065,532 · Granted Nov 22, 2022

Grain-oriented electrical steel sheet and method for manufacturing grain-oriented electrical steel sheet

Inventors: Min Serk Kwon (Pohang-si, KR); Heon Jo Choi (Pohang-si, KR); Taeyoung No (Pohang-si, KR); Byung Deug Hong (Pohang-si, KR)
Assignee: POSCO
H01F1/147C21D6/005C21D6/008C21D8/005C21D8/1222C21D8/1233C21D9/46C22C38/008C22C38/02C22C38/04C22C38/06C23C4/10C23C4/134C22C2202/02Y10T428/24917
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Quick Facts
Patent No.
US 11,508,501
App. No.
16/065,532
Granted
Nov 22, 2022
Kind
B2
Abstract

Provided is an oriented electrical steel sheet including: a forsterite film formed on one side or both sides of an oriented electrical steel sheet substrate; and a ceramic layer formed on an entire or partial region of the forsterite film. Provided is a manufacturing method for an oriented electrical steel sheet including: preparing an oriented electrical steel sheet having a forsterite film formed on one surface or both surfaces thereof; and forming a ceramic layer by spraying ceramic powder on the forsterite film.

Claims (26)

1. An oriented electrical steel sheet comprising:

a forsterite film formed on one side or both sides of an oriented electrical steel sheet substrate; and

a ceramic layer formed on an entire or partial region of the forsterite film, and

a portion where the ceramic layer is formed and a portion where the ceramic layer is not formed alternately repeating in a width direction of the oriented electrical steel sheet to form a pattern,

wherein an area ratio C of the portion where the ceramic layer is formed with respect to the entire surface of the oriented electrical steel sheet is 15 to 80%.

2. The oriented electrical steel sheet of claim 1 , wherein: a width of the portion where the ceramic layer is formed is 2 mm or more.

3. The oriented electrical steel sheet of claim 1 , wherein: a thickness of the ceramic layer is 0.1 to 4 μm.

4. The oriented electrical steel sheet of claim 3 , wherein:

the ceramic layer satisfies the following Equation 1.

1.00≤ A/B≤ 200   [Equation 1]

wherein A represents a film tension (MPa) of the ceramic layer and B represents a thickness (μm) of the ceramic layer.

5. The oriented electrical steel sheet of claim 1 , wherein:

the ceramic layer satisfies the following Equation 2.

0.01≤( A/B )/ C≤ 10   [Equation 2]

wherein A represents a film tension (MPa) of the ceramic layer, B represents a thickness (μm) of the ceramic layer, and C represents an area ratio (%) of the portion where the ceramic layer is formed with respect to the entire surface of the oriented electrical steel sheet.

6. The oriented electrical steel sheet of claim 1 , wherein: the ceramic layer is made of ceramic powder.

7. The oriented electrical steel sheet of claim 6 , wherein: the ceramic powder is oxide, nitride, carbide, or oxynitride including at least one kind of component selected from Li, B, Ca, Sr, Mg, Al, Si, P, Ti, V, Mn, Fe, Co, Ni, Cu, Zn, Zr, Sn and Ba.

8. The oriented electrical steel sheet of claim 6 , wherein:

the ceramic powder includes at least one kind selected from Al 2 O 3 , SiO 2 , TiO 2 , ZrO 2 , MgO.Al 2 O 3 , 2MgO.SiO 2 , MgO.SiO 2 , 2MgO.TiO 2 , MgO.TiO 2 , MgO.2TiO 2 , Al 2 O 3 .SiO 2 , 3Al 2 O 3 .2SiO 2 , Al 2 O 3 .SiO 2 , ZnO 2 .SiO 2 , ZrO 2 .SiO 2 , ZrO 2 .TiO 2 , 9Al 2 O 3 .2B 2 O 3 , 2Al 2 O 3 .B 2 O 3 , 2MgO.2Al 2 O 3 .5SiO 2 , Li 2 O.Al 2 O 3 .SiO 2 , Li 2 O.Al 2 O 3 .4SiO 2 , BaO.Al 2 O 3 .SiO 2 , AlN, SiC, TiC, TiN, BN, ZrN, CrN, BaTiO 3 , SrTiO 3 , FeTiO 3 , MgTiO 3 , CaO, FeAl 2 O 4 , CaTiO 3 , MgAl 2 O 4 , FeTiO 4 , SrZrO 3 , Y 2 O 3 and ZrSiO 4 .

9. The oriented electrical steel sheet of claim 6 , wherein: a particle size of the ceramic powder is 10 to 1000 nm.

10. The oriented electrical steel sheet of claim 1 , further comprising: an insulating film layer including metal phosphate formed on the ceramic layer.

11. The oriented electrical steel sheet of claim 10 , wherein:

the metal phosphate includes at least one kind selected from Mg, Ca, Ba, Sr, Zn, Al and Mn.

12. The oriented electrical steel sheet of claim 1 , wherein:

the oriented electrical steel sheet substrate includes 2.6 to 5.5 wt % of silicon (Si), 0.020 to 0.040 wt % of aluminum (Al), 0.01 to 0.20 wt % of manganese (Mn), and 0.01 to 0.15 wt % of antimony (Sb), tin (Sn), or combinations thereof, and a remaining amount consisting of Fe and other unavoidable impurities.

13. The oriented electrical steel sheet of claim 1 , wherein: a grain size in the oriented electrical steel sheet substrate is 10 to 60 mm.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 26, 2022
From: POSCO HOLDINGS INC.
To: POSCO CO., LTD
Reel/Frame 061774/0129 →
CHANGE OF NAME Recorded Sep 28, 2022
From: POSCO
To: POSCO HOLDINGS INC.
Reel/Frame 061561/0705 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 25, 2018
From: KWON, MIN SERK; CHOI, HEON JO; NO, TAEYOUNG; HONG, BYUNG DEUG
To: POSCO
Reel/Frame 046186/0795 →
Priority Claims (1)
KR 10-2015-0183790 · Dec 22, 2015 · national
Continuity (1)
Related Publication 20210202143A1 · Jul 1, 2021