Grain-oriented electrical steel sheet and manufacturing method therefor
An oriented electrical steel sheet according to an exemplary embodiment of the present invention includes Si: 2.0 to 7.0%, C: 0.005% or less (excluding 0%), Al: 0.05% or less (excluding 0%), N: 0.005% or less (excluding 0%), S: 0.005% or less (excluding 0%), a content of each of Ba and Y or a sum thereof: 0.001 to 0.3%, and Fe and other unavoidable impurities as a balance by wt %.
1. An oriented electrical steel sheet including Si: 2.0 to 7.0%, C: 0.005% or less, excluding 0%, Al: 0.05% or less, excluding 0%, N: 0.005% or less, excluding 0%, S: 0.005% or less, excluding 0%, a content of a sum of Ba and Y: 0.001 to 0.3%, and Fe and other unavoidable impurities as a balance by wt % as a composition of the oriented electrical steel sheet, wherein the oriented electrical steel sheet composition further includes Ba: 0.001% to 0.3% by wt %.
2. The oriented electrical steel sheet of claim 1 , further comprising Mn at 0.005 to 0.5 wt %.
3. The oriented electrical steel sheet of claim 1 , further comprising P at 0.005 to 0.075 wt %.
4. The oriented electrical steel sheet of claim 1 , further comprising Cr at 0.005 to 0.35 wt %.
5. The oriented electrical steel sheet of claim 1 , further comprising Sb and Sn at 0.005 to 0.2 wt % as a content of each or a sum thereof.
6. The oriented electrical steel sheet of claim 1 , wherein an area ratio of a grain having a size of 1 mm or less among the grain existing in the electrical steel sheet is 10% or less.
7. The oriented electrical steel sheet of claim 1 , wherein an angle difference between a <100> surface and a sheet surface of the steel sheet in the electrical steel sheet is 3.5° or less.
8. The oriented electrical steel sheet of claim 1 , further comprising Ba and Y segregated on a grain boundary, or a combination thereof.
9. A manufacturing method of an oriented electrical steel sheet, comprising:
a step of heating a slab including Si: 2.0 to 7.0%, C: 0.001 to 0.1%, Al: 0.05% or less (excluding 0%), a content of a sum of Ba and Y: 0.001 to 0.3%; and Fe and other unavoidable impurities as a balance, by wt %, wherein the slab includes Ba: 0.001% to 0.3% by wt %;
a step of hot rolling the slab to manufacture a hot rolled sheet; a step of cold-rolling the hot roped sheet to manufacture a cold roiled sheet; a step of primary recrystallization-annealing the cold roiled sheet; and a step of secondary recrystallization-annealing the electrical steel sheet of which the primary recrystallization annealing is completed thus forming the oriented electrical steel sheet of claim 1 .
10. The manufacturing method of claim 9 , wherein the slab includes Al at 0.005 wt % or less (excluding 0%).
11. The manufacturing method of claim 9 , wherein the slab further includes N at 0.03 wt % or less (excluding 0%) and S at 0.03 wt % or less (excluding 0%).
12. The manufacturing method of claim 9 , wherein the slab further includes Mn at 0.005 to 0.5 wt %.
13. The manufacturing method of claim 9 , wherein, in the step of heating the slab, the slab is heated to 1040 to 1280° C.
14. The manufacturing method of claim 9 , further comprising, after the step of hot rolling, a step of performing hot rolled sheet annealing.
15. The manufacturing method of claim 9 , wherein the primary recrystallization annealing maintains the cold rolled sheet at a temperature of 750° C. or more for 30 seconds or more.
16. The manufacturing method of claim 9 , wherein a soaking temperature of the secondary recrystallization annealing is 900° C. to 1250° C.
17. The manufacturing method of claim 9 , wherein a nitriding step after the step of manufacturing the cold rolled sheet and before the step of the secondary recrystallization annealing, and after the nitriding step, the steel sheet includes N at 140 to 500 ppm.
18. The manufacturing method of claim 9 , wherein after the step of secondary recrystallization annealing, the steel sheet includes N at 50 ppm or less.