Separator for electrochemical device and electrochemical device including the same
The present disclosure relates to a separator for an electrochemical device. The separator includes a porous coating layer containing inorganic particles on the surface of a porous polymer substrate, wherein the porous coating layer includes plate-like inorganic particles and spherical inorganic particles as inorganic particles, and shows a step-wise or successive increase in content of inorganic particles a) from the bottom close to the porous polymer substrate to the top, when viewed from the thickness direction of the porous coating layer, and shows a step-wise or successive decrease in content of inorganic particles b) from the bottom close to the porous polymer substrate to the top, when viewed from the thickness direction of the porous coating layer.
1. A separator for an electrochemical device which comprises:
a porous polymer substrate including a polymer resin; and
a porous coating layer formed on at least one surface of both surfaces of the porous polymer substrate,
the inorganic particles a) are plate-like inorganic particles and the inorganic particles b) are spherical inorganic particles,
the porous coating layer comprises the inorganic particles b) in an amount of 50 wt % or more based on 100 wt % of the combined weight of the inorganic particles a) and b) in the portion from the bottom close to the porous polymer substrate to 10% of the thickness, when viewed from the thickness direction, and
the porous coating layer comprises the inorganic particles a) in an amount of 50 wt % or more based on 100 wt % of the combined weight of the inorganic particles a) and b) in the portion from the surface of the porous coating layer facing to an electrode to 10% of the thickness, when viewed from the thickness direction,
wherein the porous coating layer is a bilayer formed by the sequential steps of:
applying a first slurry comprising inorganic particles b) to the porous polymer substrate,
drying the applied first slurry,
applying a second slurry comprising inorganic particles a) to the porous polymer substrate, and
drying the applied second slurry.
2. The separator for an electrochemical device according to claim 1 , wherein the plate-like inorganic particles a) have an aspect ratio more than 3 and equal to or less than 100.
3. The separator for an electrochemical device according to claim 2 , wherein the plate-like inorganic particles a) are boehmite.
4. The separator for an electrochemical device according to claim 1 , wherein the spherical inorganic particles b) have an aspect ratio of 1-3.
5. The separator for an electrochemical device according to claim 1 , wherein the porous coating layer comprises a mixture of the plate-like inorganic particles a), the spherical inorganic particles b) and a binder resin, wherein the binder resin is present in an amount of 3-10 wt % based on the total weight of the porous coating layer.
6. The separator for an electrochemical device according to claim 1 , which has a puncture strength of 0.26 kgf or more.
7. An electrochemical device comprising a positive electrode, a negative electrode and a separator interposed between the positive electrode and negative electrode, wherein the negative electrode comprises lithium metal and the separator is defined in claim 1 .
8. The separator for an electrochemical device according to claim 1 ,
wherein the porous coating layer comprises a mixture of the plate-like inorganic particles a), the spherical inorganic particles b) and a binder resin, wherein the binder resin is present in an amount of 3-10 wt % based on the total weight of the porous coating layer, and
wherein the binder resin is at least one binder resin selected from the group consisting of polyvinylidene fluoride-co-hexafluoropropylene, polyvinylidene fluoride-co-trichloroethylene, polymethylmethacrylate, polyethyl acrylate, polymethyl acrylate, polybutyl acrylate, polyacrylonitrile, polyvinyl pyrrolidone, polyvinyl acetate, polyethylene-co-vinyl acetate, polyethylene oxide, polyarylate, cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate, cyanoethylpullulan, cyanoethyl polyvinylalcohol, cyanoethyl cellulose, cyanoethyl sucrose, pullulan and carboxymethyl cellulose.