Process for preparing propylene copolymer compositions
The present invention relates to an olefin polymerization process for producing propylene copolymer composition (P), wherein propylene, C 4 to C 10 α-olefin and optionally ethylene are reacted in the presence of a Ziegler-Natta catalyst in a multistage polymerization process comprising at least two polymerization reactors, wherein the copolymer composition is bimodal with respect to the content of C 4 to C 10 α-olefin and, if present, to ethylene. Further, the invention is directed to the propylene copolymer composition being bimodal with respect to the content of C 4 to C 10 α-olefin and optionally to ethylene, and use of said propylene copolymer compositions for producing articles.
1. An olefin polymerization process for producing a propylene copolymer composition (P), wherein propylene, C 4 to C 10 α-olefin and optionally ethylene are reacted in the presence of a Ziegler-Natta catalyst in a multistage polymerization process comprising at least two slurry polymerization reactors, wherein the copolymer composition is bimodal with respect to the content of C 4 to C 10 α-olefin and, if present, to ethylene, and wherein the process comprises
feeding a fresh propylene monomer (C3) via a first line ( 1 ) into a monomer feed tank (A),
feeding circulated unreacted monomers from a product receiver (D) into the monomer feed tank (A) via a third line ( 3 ),
dividing a monomer mixture from the monomer feed tank (A) in a fourth feed line ( 4 ) into a first divided fourth feed line ( 4 -C), which feeds the monomer mixture to a second reactor (C), and to a second divided fourth feed line ( 4 -B) which feeds to a first reactor (B),
feeding a fresh C4 to C10 α-olefin monomer and optionally ethylene into the second divided fourth feed line ( 4 -B) via a fifth line ( 5 ) forming a second combined monomer mixture feed in a sixth line ( 6 ),
feeding the second combined monomer mixture via the sixth line ( 6 ) to the first reactor (B),
polymerizing the second monomer mixture in the first reactor (B) to produce a first product mixture comprising a first polymer fraction (P1) and unreacted monomers,
transferring the first product mixture from the first reactor (B) to the second reactor (C) via a seventh line ( 7 ),
continuing the polymerization in the second reactor (C) to produce a second product mixture comprising a second polymer fraction (P2) and unreacted monomers,
taking the second product mixture with unreacted monomers out from the second reactor (C) and feeding the second product mixture via an eighth line ( 8 ) to the product receiver (D),
separating the unreacted monomers from the second product mixture in the product receiver (D),
circulating at least part of the unreacted monomers back to the monomer feed tank (A) via the third line ( 3 ), and
removing a final copolymer composition (P) from the product receiver (D) via a ninth line ( 9 ).
2. The process according to claim 1 , wherein the polymerization reactors are loop reactors.
3. The process of claim 1 , wherein the C 4 to C 10 α-olefin comprises C 4 to C 8 α-olefin.
4. The process of claim 1 , wherein the weight ratio of the amount of the polymer produced in the first and second reactor is in the range of 55:45 to 75:25.
5. The process of claim 1 , wherein the C 4 to C 10 α-olefin in the first polymer fraction (P1), is present in the range of 4 to 12 wt-%.
6. The process of claim 1 , wherein the weight ratio of C 4 to C 10 α-olefin in the second polymer fraction (P2) to C 4 to C 10 α-olefin in the first polymer fraction (P1) is in the range of 0.35 to 0.65.
7. The process of claim 1 , wherein the C 4 to C 10 α-olefin in the final propylene copolymer composition (P) is present in the range of 1 to 12 wt %.
8. The process of claim 1 , wherein ethylene in the final propylene copolymer composition (P) is present in the range of 0 to 3 wt %.
9. The process of claim 1 , wherein a polymerization temperature is in the range of 50 to 80° C.
10. The process of claim 1 , wherein the process comprises an in-line pre-polymerization step.
11. The process of claim 1 , wherein the Ziegler-Natta catalyst comprises a MgCl 2 supported catalyst component or a self-supported catalyst component prepared by an emulsion-solidification method or by a precipitation method.
12. The process of claim 11 , wherein the catalyst comprises a cocatalyst of a compound of Group 13 metal and an external donor.
13. The process of claim 1 , wherein the C 4 to C 10 α-olefin comprises C 4 to C 6 α-olefin.
14. The process of claim 1 , wherein the C4 to C 10 α-olefin comprises 1-butene.
15. The process of claim 1 , wherein the weight ratio of the amount of the polymer produced in the first and second reactor is in the range of 60:40 to 70:30.
16. The process of claim 12 , wherein the cocatalyst comprises aluminum.
17. The process of claim 12 , wherein the external donor comprises a silane compound.