IP Library Granted Patent US 10,829,594
Granted Patent B2
US 10,829,594 · App. 16/067,295 · Granted Nov 10, 2020

Method of making polyetherimide

Inventors: Thomas Link Guggenheim (Mt. Vernon, IN); Karthik Venkataraman (Evansville, IN)
Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
C08G73/1053C08G73/1014C08G73/1017C08G73/1028C08G73/1046
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Quick Facts
Patent No.
US 10,829,594
App. No.
16/067,295
Granted
Nov 10, 2020
Kind
B2
Abstract

A method of making a polyetherimide comprising: reacting an aromatic bis(ether anhydride) with an aromatic diamine in a solvent to form a first solid/liquid mixture having a first solids content within 5% of a first target solids content; cooling the first solid/liquid mixture to a temperature within 5% of a target temperature; separating a portion of the liquid component from the cooled first solid/liquid mixture to form a second solid/liquid mixture having a second solids content within 10% of a second target solids content; and melt polymerizing the second solid/liquid mixture to form the polyetherimide.

Claims (11)

1. A method of making a polyetherimide comprising:

reacting an aromatic bis(ether anhydride) with an aromatic diamine in a solvent to form a first solid/liquid mixture having a first solids content within 5% of a first target solids content;

cooling the first solid/liquid mixture to a temperature within 5% of a target temperature;

separating a portion of the liquid component from the cooled first solid/liquid mixture to form a second solid/liquid mixture having a second solids content within 10% of a second target solids content; and

melt polymerizing the second solid/liquid mixture to form the polyetherimide.

2. The method of claim 1 , wherein reacting the aromatic bis(ether anhydride) with the aromatic diamine in a solvent occurs at a temperature of 100° C. to the boiling point of the solvent under the reaction conditions.

3. The method of claim 1 , wherein the first target solids content is in the range of 10 to 40%.

4. The method of claim 1 , further comprising reacting a chain terminating agent with the bis(ether anhydride) and aromatic diamine.

5. The method of claim 1 , wherein the second target solids content is in the range of 40 to 60% and is greater than the first target solids content.

6. The method of any of claim 1 , wherein the first solids content is within 3% of the first target solids content.

7. The method of claim 1 , further comprising drying the second solid/liquid mixture to a solvent content less than or equal to 20 weight percent, based on the total weight of the dried mixture, prior to melt polymerization.

Assignments (3)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE THE APPLICATION NUMBER 15039474 PREVIOUSLY RECORDED AT REEL: 054528 FRAME: 0467. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Mar 23, 2021
From: SABIC GLOBAL TECHNOLOGIES B.V.
To: SHPP GLOBAL TECHNOLOGIES B.V.
Reel/Frame 057453/0680 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 26, 2020
From: SABIC GLOBAL TECHNOLOGIES B.V.
To: SHPP GLOBAL TECHNOLOGIES B.V.
Reel/Frame 054528/0467 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 2, 2018
From: GUGGENHEIM, THOMAS LINK; VENKATARAMAN, KARTHIK
To: SABIC GLOBAL TECHNOLOGIES B.V.
Reel/Frame 046250/0560 →