Antireflection film
The present invention relates to an antireflection film which exhibits one extremum at a thickness of 35 nm to 55 nm from the surface and exhibiting one extremum at a thickness of 85 nm to 105 nm from the surface in a graph showing the result of Fourier transform analysis for the result of X-ray reflectivity measurement using Cu—K-alpha rays.
1. An antireflection film comprising a hard coating layer, and a low refractive index layer disposed on the hard coating layer, the low refractive index layer containing a binder resin, and hollow inorganic nanoparticles and solid inorganic nanoparticles dispersed in the binder resin,
the low refractive index layer exhibiting one extremum at a thickness of 35 nm to 55 nm and another extremum at a thickness of 85 nm to 105 nm, in a graph showing a result of Fourier transform analysis for X-ray reflectivity measurement using Cu—K-alpha rays,
wherein each of the thickness of 35 nm to 55 nm and the thickness of 85 nm to 105 nm is a thickness from a surface of the low refractive index layer,
wherein 70% by volume or more of the entire solid inorganic nanoparticles are present within 50% of the total thickness of the low refractive index layer from the interface between the hard coating layer and the low refractive index layer.
2. The antireflection film of claim 1 , wherein the graph showing the result of Fourier transform analysis for X-ray reflectivity measurement using Cu—K-alpha rays represents a Fourier transform magnitude of y-axis relative to the film thickness from a surface of the low refractive index layer of x-axis.
3. The antireflection film of claim 2 , wherein the X-ray reflectivity measurement using Cu—K-alpha rays is performed for an antireflection film having a size of 1 cm*1 cm (width*length) using Cu—K-alpha rays having a wavelength of 1.5418 Å.
4. The antireflection film of claim 1 , wherein the X-ray reflectivity measurement using Cu—K-alpha rays is performed for an antireflection film having a size of 1 cm*1 cm (width*length) using Cu—K-alpha rays having a wavelength of 1.5418 Å.
5. The antireflection film of claim 1 , wherein 30% by volume or more of the entire hollow inorganic nanoparticles are present at a greater distance in the thickness direction of the low refractive index layer from the interface between the hard coating layer and the low refractive index layer, compared to the solid inorganic nanoparticles.
6. The antireflection film of claim 1 , wherein 70% by volume or more of the entire solid inorganic nanoparticles are present within 30% of the total thickness of the low refractive index layer from the interface between the hard coating layer and the low refractive index layer.
7. The antireflection film of claim 6 , wherein 70% by volume or more of the entire hollow inorganic nanoparticles are present in a region exceeding 30% of the total thickness of the low refractive index layer from the interface between the hard coating layer and the low refractive index layer.
8. The antireflection film of claim 1 , wherein the low refractive index layer includes a first layer containing 70% by volume or more of the entire solid inorganic nanoparticles and a second layer containing 70% by volume or more of the entire hollow inorganic nanoparticles, and the first layer is located closer to the interface between the hard coating layer and the low refractive index layer, compared to the second layer.
9. The antireflection film of claim 8 , wherein 70% or more by volume of the entire solid inorganic nanoparticles are present within 50% of the total thickness of the low refractive index layer from the interface between the hard coating layer and the low refractive index layer.
10. The antireflection film of claim 1 , wherein the solid inorganic nanoparticles have a higher density by 0.50 g/m 3 or more compared to the hollow inorganic nanoparticles.
11. The antireflection film of claim 1 , wherein each of the solid inorganic nanoparticles and the hollow inorganic nanoparticles has on the surface thereof at least one reactive functional group selected from the group consisting of a (meth)acrylate group, an epoxide group, a vinyl group, and a thiol group.
12. The antireflection film of claim 1 , wherein the binder resin contained in the low refractive index layer may include a crosslinked (co)polymer between a (co)polymer of a photopolymerizable compound and a fluorine-containing compound containing a photoreactive functional group.
13. The antireflection film of claim 12 , wherein the low refractive index layer includes 10 to 400 parts by weight of the hollow inorganic nanoparticles and 10 to 400 parts by weight of the solid inorganic nanoparticles, relative to 100 parts by weight of the (co)polymer of the photopolymerizable compound.
14. The antireflection film of claim 12 , wherein each of the fluorine-containing compounds containing the photoreactive functional group has a weight average molecular weight of 2000 to 200,000.
15. The antireflection film of claim 12 , wherein the binder resin includes 20 to 300 parts by weight of the fluorine-containing compound containing the photoreactive functional group based on 100 parts by weight of the (co)copolymer of the photopolymerizable compound.
16. The antireflection film of claim 1 , wherein the hard coating layer includes a binder resin containing a photocurable resin, and organic or inorganic fine particles dispersed in the binder resin.
17. The antireflection film of claim 16 , wherein the organic fine particles have a particle diameter of 1 to 10 μm, and the inorganic fine particles have a particle diameter of 1 nm to 500 nm.