Lubricant for a two-stroke marine engine
Relating to the field of lubricant, more particularly relates to lubricant for marine engine, notably for a two-stroke marine engine. More particularly, relates to a lubricant for a marine engine including at least one lubricant base oil and at least one fatty amine.
1. Lubricant composition comprising:
at least one lubricant base oil,
at least a di-fatty-alkyl(ene) polyalkylamine composition comprising one or more polyalkylamines of formulae (I) or (II):
wherein,
each R is, independent of the other R, an alkyl moiety or an alkylene moiety with 8 to 22 carbon atoms, which is linear or branched,
n and z are independent of each other either 0, 1, 2, or 3, and
when z is superior than 0 then o and p are independent of each other either 0, 1, 2, or 3,
or derivatives thereof,
whereby said polyalkylamine composition comprises at least 3% by weight of branched compounds of formula (I) or (II), with regards to the total weight of polyalkylamine compounds (I) and (II) in the composition, branched compound signifying that:
in formula (I) at least one of n and z are superior or equal to 1,
in formula (II) n is superior or equal to 1.
2. Lubricant composition according to claim 1 , wherein the polyalkylamine composition comprises at least 4% w/w of branched compounds of formula (I) or (II), with regards to the total weight of polyalkylamine compounds (I) and (II) in the composition, branched compound signifying that:
in formula (I) at least one of n or z are superior or equal to 1,
in formula (II) n is superior or equal to 1.
3. Lubricant composition according to claim 1 , wherein the polyalkylamine composition comprises at least 5% by weight, with regards to the total weight of compounds (I) and (II), of products of formulae (I) and (II) with a linear structure, linear meaning n is 0 in formulae (I) and (II) and z is 0 in formula (I).
4. Lubricant composition according to claim 1 , wherein the polyalkylamine composition further comprises derivatives of polyalkylamines of formula (I) or (II), wherein said derivatives are alkoxylates which are optionally methylated.
5. Lubricant composition according to claim 1 , wherein the polyalkylamine composition further comprises derivatives of polyalkylamines of formula (I) or (II), wherein said derivatives are methylated.
6. Lubricant composition according to claim 1 , wherein the polyalkylamine composition has a BN measured according to standard ASTM D-2896 from 150 to 350 milligrams of potash per gram of amine compound.
7. Lubricant composition according to claim 1 , having a BN, measured according to standard ASTM D-2896, greater than or equal to 70 milligrams of potash per gram of the lubricant composition.
8. Lubricant composition according to claim 7 , wherein the percentage by mass of di-fatty-alkyl(ene) polyalkylamine mixture with respect to the total weight of the lubricant composition is from 2 to 10%.
9. Lubricant composition according to claim 1 , having a BN determined according to the standard ASTM D-2896 of at most 50 milligrams of potassium hydroxide per gram of the lubricant composition.
10. Lubricant composition according to claim 9 , wherein the percentage by mass of di-fatty-alkyl(ene) polyalkylamine mixture with respect to the total weight of the lubricant composition is comprised between 0.1 and 15%.
11. Lubricant composition according to claim 1 , further comprising additives chosen amongst a neutral detergent, an overbased detergent or mixtures thereof.
12. Lubricant composition according to claim 1 , wherein the percentage by mass of di-fatty-alkyl(ene) polyalkylamine mixture with respect to the total weight of lubricant is chosen such that the BN provided by these compounds represents a contribution comprised between 5 and 60 milligrams of potash per gram of lubricant, determined according to the standard ASTM D-2896.
13. Lubricant composition according to claim 12 , wherein the percentage by mass of di-fatty-alkyl(ene) polyalkylamine mixture with respect to the total weight of lubricant is chosen such that the BN provided by these compounds represents a contribution comprised between 10 and 30 milligrams of potash per gram of lubricant of the total BN of said cylinder lubricant, determined according to the standard ASTM D-2896.
14. A method for lubricating a marine engine, comprising contacting the engine with a lubricant composition according claim 1 as a cylinder lubricant.
15. The method of claim 14 , wherein the engine is a two-stroke marine engine.
16. The method of claim 14 , comprising operating the engine with fuels having a content of sulphur inferior than 1% by weight relative to the total weight of fuel.
17. The method of claim 16 , comprising operating the engine with fuels having a content of sulphur inferior than 0.5% by weight relative to the total weight of fuel.
18. The method of claim 14 , comprising operating the engine with fuels having a content of sulphur from 1 to 3.5% by weight relative to the total weight of fuel.
19. The method of claim 14 for reducing the formation of deposits in the hot section of a marine engine.