Amphiphilic diblock copolymer and use of same for producing polymeric filter membranes
Provided is a an amphiphilic diblock copolymer including from 40 to 60% by weight, relative to the weight of the copolymer, of a hydrophilic block including a unit derived from an n-butyl acrylate monomer and a derived from a hydroxyethyl methacrylate monomer. The copolymer also includes from 40 to 60% by weight, relative to the weight of the copolymer, of a hydrophobic block including at least one unit derived from a methyl methacrylate monomer. Also provided is a polymeric membrane that includes the block copolymer and a hydrophobic polymeric matrix. This membrane is useful for treating an effluent, for example, water.
1. An amphiphilic diblock copolymer consisting of:
50% by weight, relative to the weight of the copolymer, of a hydrophilic block consisting of:
77% by weight of units derived from an n-butyl acrylate monomer, relative to the weight of said hydrophilic block, and
23% by weight of units derived from a hydroxyethyl methacrylate monomer, relative to the weight of said hydrophilic block, and
50% by weight, relative to the weight of the copolymer, of a hydrophobic block comprising at least 99% by weight of polymethyl methacrylate relative to the weight of said hydrophobic block.
2. The copolymer as claimed in claim 1 , wherein said hydrophilic block is composed of a statistical copolymer containing at least one unit derived from an n-butyl acrylate monomer and at least one unit derived from a hydroxyethyl methacrylate monomer.
3. The copolymer as claimed in claim 1 , wherein said copolymer is a (poly-n-butyl acrylate-co-polyhydroxyethyl methacrylate-b-hydrophobic block) copolymer, the hydrophobic block comprising at least 99% by weight of polymethyl methacrylate, relative to the weight of the copolymer, and a mixture of units derived from methacrylate or acrylate monomers.
4. The copolymer as claimed in claim 1 , wherein the weight-average molecular weight of said copolymer ranges from 10 to 400 kg/mol.
5. A polymeric membrane, comprising at least one hydrophobic polymeric matrix and at least one copolymer as defined in claim 1 .
6. The polymeric membrane as claimed in claim 5 , wherein the hydrophobic polymeric matrix is a fluoropolymer.
7. The polymeric membrane as claimed in claim 5 , which comprises from 5 to 99.9% by weight of said hydrophobic polymeric matrix, relative to the weight of the membrane, and from 0.1 to 95% by weight of said copolymer relative to the weight of the membrane.
8. The polymeric membrane as claimed in claim 5 , obtained by a phase inversion process, from a solution comprising at least one hydrophobic polymeric matrix, at least one copolymer as defined in claim 1 and optionally one or more other additives, in solution in a solvent.
9. The polymeric membrane as claimed in claim 8 , obtained by said phase inversion process from a solution comprising:
from 4.9 to 50% by weight of said hydrophobic polymeric matrix, relative to the weight of the solution;
from 0.1 to 35% by weight of said copolymer, relative to the weight of the solution;
from 15 to 95% by weight of solvent, relative to the weight of the solution; and
optionally from 0 to 20% by weight of one or more additives, relative to the weight of the solution.
10. A method of making the polymeric membrane as defined in claim 5 , comprising combining the hydrophobic polymeric matrix and the copolymer.
11. A method of treating an effluent, comprising contacting the effluent with the polymeric membrane as defined in claim 5 .
12. The method as defined in claim 11 , wherein the effluent is water.