Foldable cover assembly, method of manufacture, and device comprising the foldable cover assembly

1. A foldable cover assembly ( 10 ), comprising

a glass layer ( 1 ) having a first surface ( 2 ), a second surface ( 3 ) opposite the first surface ( 2 ), a first thickness (T 1 ) at a first location ( 4 ) and a second thickness (T 2 ) at a second location ( 5 ), wherein the second thickness is less than the first thickness, and is effective to provide bendability to the glass layer; and

an optically clear polymer film ( 6 ) disposed on the first surface of the glass layer, the polymer film comprising a thermoplastic polymer, a thermoset polymer, or a combination comprising at least one of the foregoing, wherein a 100 micrometer-thick sample of the optically clear polymer film transmits greater than 85% of visible light as determined according to ASTM D1003-00;

wherein the second thickness at a center point of the second location is less than the second thickness at a periphery of the second location.

2. The foldable cover assembly of claim 1 , wherein the cover assembly transmits greater than 85% of visible light as determined according to ASTM D1003-00.

3. The foldable cover assembly of claim 1 , wherein the cover assembly has a surface hardness of at least 7H as measured according to ASTM 3363, a flexibility at the second location of 3R or less as measured according to JIS K6902, or both.

4. The foldable cover assembly of claim 1 , wherein the first thickness of the glass layer is 50 micrometers to 1 millimeter.

5. The foldable cover assembly of claim 1 , wherein the second thickness of the glass layer is 10 to 750 micrometers.

6. The foldable cover assembly of claim 1 , wherein the glass layer comprises chemically strengthened glass, non-strengthened glass, tempered glass, or optically transparent synthetic crystal.

7. The foldable cover assembly of claim 1 , wherein the first location is adjacent to the second location.

8. The foldable cover assembly of claim 1 , wherein the polymer film comprises poly(ethylene terephthalate, poly(ethylene naphthalate), poly(1,4-cyclohexane-dimethanol-1,4-cyclohexane dicarboxylate), poly(cyclohexanedimethylene terephthalate)-co-poly(ethylene terephthalate), polypropylene, a bisphenol A polycarbonate homopolymer, a bisphenol A polycarbonate copolymer, poly(4,4′-oxydiphenylene-pyromellitimide), poly(methyl methacrylate), polystyrene, polyoxymethylene, poly(ethylene-vinyl acetate, polymethylpentene, or a combination comprising at least one of the foregoing.

9. The foldable cover assembly of claim 1 , wherein the polymer film has a thickness of 5 micrometers to 20 millimeters.

10. The foldable cover assembly of claim 1 , wherein the cover assembly further comprises an optically clear adhesive layer disposed between the first surface of the glass layer and the polymer film, wherein a 50 micrometer-thick sample of the optically clear adhesive transmits greater than 85% of visible light as determined according to ASTM D1003-00.

11. The foldable cover assembly of claim 1 , further comprising an optically clear coating ( 7 ) disposed on at least a portion of the second surface ( 3 ) of the second location ( 5 ) of the glass layer, wherein the coating provides a difference in refractive index of the second location and refractive of the first location that is less than or equal to 0.05, and wherein the optically clear coating has a thickness of 10 to 50 micrometers.

12. A method of manufacturing the foldable cover assembly of claim 1 , the method comprising

applying the polymer film to the first surface of the glass layer;

contacting a masking layer with the second surface of the glass layer, wherein the masking layer comprises an aperture such that the first location of the glass layer is covered by the masking layer and the second location of the glass layer is exposed;

etching at least a portion of the exposed second location of the glass layer to provide the glass layer having a first thickness at the first location and a second thickness at the second location, wherein the second thickness is less than the first thickness; and

removing the masking layer from the cover assembly.

13. The method of claim 12 , further comprising applying an optically clear coating ( 7 ) on at least a portion of the second surface of the second location of the glass layer, wherein the coating provides a difference in refractive index of the second location and refractive of the first location that is less than or equal to 0.05.

14. An electronic device comprising the foldable cover assembly of claim 1 .

15. The electronic device of claim 14 , comprising the foldable cover assembly disposed on a display of the electronic device.

16. The electronic device of claim 14 , wherein the device is a foldable device.

17. The electronic device of claim 14 , wherein the device is a cellular telephone, a smart telephone, a laptop computer, a notebook computer, a tablet computer, a smart watch, an automobile display device, or a medical device.

18. The electronic device of claim 14 , wherein the cover assembly is laminated onto the device, or molded onto the device, or adhered onto the device via an adhesive layer, wherein a 50 micrometer-thick sample of the adhesive layer transmits greater than 85% of visible light as determined according to ASTM D1003-00.

19. An accessory for an electronic device comprising the foldable cover assembly of claim 1 .