Barrier film laminate for a touch-sensing display, method of manufacture, and displays comprising the barrier film laminate

1. A barrier film laminate ( 10 ) for a touch-sensing display, the laminate comprising

a barrier layer ( 1 ) having a first surface ( 2 ) and a second surface ( 3 ) opposite the first surface;

an optically clear adhesive layer ( 4 ) disposed on the first surface of the barrier layer, wherein a 50 micrometer-thick sample of the optically clear adhesive transmits greater than 85% of visible light as determined according to ASTM D1003-00;

an optically clear polymer film ( 5 ) disposed on the optically clear adhesive on a side opposite the barrier layer, the polymer film comprising a thermoplastic polymer, wherein a 100 micrometer-thick sample of the optically clear polymer film transmits greater than 85% of visible light as determined according to ASTM D1003-00; and

a touch-sensing layer ( 6 ) directly on the polymer film on a side opposite the optically clear adhesive layer, wherein a 5 micrometer-thick sample of the touch-sensing layer transmits greater than 80% of visible light as determined according to ASTM D1003-00.

2. The barrier film laminate of claim 1 , wherein the barrier film laminate

transmits greater than 85% of visible light as determined according to ASTM D1003-00;

is flexible; or

has a water vapor transmission rate of 10 −6 to 10 −3 g/m 2 per day, as determined according to ASTM F1249-06.

3. The barrier film laminate of claim 1 ,

wherein the barrier layer has a thickness of 50 micrometers to 1 millimeter;

wherein the optically clear adhesive has a thickness of 1 to 2000 micrometers; and

wherein the polymer film has a thickness of 1 micrometer to 10 millimeters.

4. The barrier film laminate of claim 1 , wherein the barrier layer is a glass layer comprising chemically strengthened glass, non-strengthened glass, tempered glass, or optically transparent synthetic crystal; and wherein the optically clear adhesive layer comprises an epoxy, acrylate, amine, urethane, silicone, thermoplastic urethane, ethyl vinyl acetate, hindered amine light stabilizer free ethyl vinyl acetate, or a combination comprising at least one of the foregoing.

5. The barrier film laminate of claim 1 , wherein the barrier layer is a barrier film comprising two or more thin films comprising different materials.

6. The barrier film laminate of claim 1 , wherein the polymer film comprises a polycarbonate, a polyester, a polyolefin, or a combination comprising at least one of the foregoing, preferably a bisphenol A polycarbonate homopolymer, a bisphenol A polycarbonate copolymer, poly(ethylene terephthalate), poly(ethylene naphthalate), polypropylene, or a combination comprising at least one of the foregoing.

7. The barrier film laminate of claim 1 , wherein the touch-sensing layer is a capacitive touch-sensing layer.

8. The barrier film laminate of claim 1 , wherein the touch-sensing layer comprises indium tin oxide, carbon nanotubes, graphene, conductive metal nanowires, conductive metal nanoparticles, a conductive nanomesh, a conductive polymer or a combination comprising at least one of the foregoing, preferably silver nanoparticles, silver nanowires, carbon nanotubes, graphene, a conductive polymer, or a combination comprising at least one of the foregoing.

9. A method of manufacturing a barrier film laminate for a touch-sensing display, the laminate comprising a barrier layer ( 1 ) have a first surface ( 2 ) and a second surface ( 3 ) opposite the first surface; an optically clear adhesive layer ( 4 ) disposed on the first surface of the barrier layer, wherein a 50 micrometer thick sample of the optically clear adhesive transmits greater than 85% of visible light as determined according to ASTM D1003-00; an optically clear polymer film ( 5 ) disposed on the optically clear adhesive on a side opposite the barrier layer, the polymer film comprising a thermoplastic polymer, where a 100 micrometer-thick sample of the optically clear polymer film transmits greater than 85% of visible light as determined according to ASTM D10003-00; and a touch sensing later ( 6 ) directly on the polymer film on a side opposite the optically clear adhesive layer, wherein a 5 micrometer-thick sample of the touch-sensing layer transmits greater than 80% of visible light as determined according to ASTM D1003-00, the method comprising:

applying the touch-sensing layer directly to the polymer film;

applying the optically clear adhesive to at least a portion of the first surface of the barrier layer; and

applying the polymer film to the optically clear adhesive on a side opposite the touch-sensing layer.

10. A touch-sensing display comprising the barrier film laminate of claim 1 .

11. The touch-sensing display ( 20 ) of claim 10 , wherein the barrier film laminate ( 10 ) is disposed between a light emitting layer ( 21 ) and a polarizer ( 22 ) such that the second surface of the barrier layer of the barrier film laminate is in contact with the light emitting layer and the touch-sensing layer of the barrier film laminate is in contact with the polarizer.

12. The touch-sensing display of claim 10 , further comprising

a thin film transistor ( 23 ) disposed on the light emitting layer ( 21 );

a flexible polymer-containing substrate ( 24 ) disposed on the thin film transistor ( 23 ) on a side opposite the light emitting layer; and

a cover lens ( 25 ) adhered to the polarizer on a side opposite the touch-sensing barrier layer via a second optically clear adhesive layer ( 26 ).

13. The touch-sensing display of claim 10 , wherein the display is an organic light emitting diode display and the light emitting layer is an organic light emitting layer.

14. The touch-sensing display of claim 12 , wherein the flexible polymer-containing substrate is a polyimide-containing substrate.

15. The touch-sensing display of claim 10 , wherein the display is a curved display, a curvilinear display, a foldable display, or a flexible display.