Organic electroluminescent element

1. An organic electroluminescent device containing one or more light emitting layers and one or more electron transport layers between opposing anode and cathode, wherein at least one of the electron transport layers contains a compound represented by general formula (1) below and an electron donor, wherein, in a case of two or more electron transport layers, a first electron transport layer contains the compound represented by general formula (1) without the electron donor, and a second transport layer contains the compound represented by general formula (1) and the electron donor:

wherein, ring A represents an aromatic hydrocarbon ring represented by formula (1a), ring B represents a heterocyclic ring represented by formula (1b), and ring A and ring B are condensed with a ring adjacent to ring A and ring B at arbitrary locations,

L represents a single bond or aromatic hydrocarbon group having 6 to 12 carbon atoms,

X represents N or C—Ar 1 and at least one of X represents N,

Y and Ar 1 respectively and independently represent a hydrogen atom, substituted or unsubstituted aromatic hydrocarbon group having 6 to 18 carbon atoms, substituted or unsubstituted aromatic heterocyclic group having 3 to 18 carbon atoms, or a linked aromatic group obtained by linking 2 to 5 of these aromatic rings,

R 1 independently represents an aliphatic hydrocarbon group having 1 to 10 carbon atoms, a substituted or unsubstituted aromatic hydrocarbon group having 6 to 10 carbon atoms, or a substituted or unsubstituted aromatic heterocyclic group having 3 to 12 carbon atoms, and a, b and c respectively and independently represent an integer of 0 to 3,

Z represents N—Ar 2 , C(R 2 ) 2 , O or S, wherein Ar 2 represents a substituted or unsubstituted aromatic hydrocarbon group having 6 to 18 carbon atoms, a substituted or unsubstituted aromatic heterocyclic group having 3 to 18 carbon atoms, or a linked aromatic group obtained by linking 2 to 5 of these aromatic rings, and R 2 independently represents a hydrogen atom, aliphatic hydrocarbon group having 1 to 10 carbon atoms, substituted or unsubstituted aromatic hydrocarbon group having 6 to 10 carbon atoms, or substituted or unsubstituted aromatic heterocyclic group having 3 to 12 carbon atoms.

2. The organic electroluminescent device according to claim 1 , wherein the heterocyclic ring represented by formula (1b) is a heterocyclic ring represented by formula (1d):

where, Ar 1 has the same meaning as in general formula (1).

3. The organic electroluminescent device according to claim 1 , wherein L in general formula (1) represents a single bond.

4. The organic electroluminescent device according to claim 1 , wherein the electron transport layer is formed of two layers, which are the first electron transport layer being adjacent to the light emitting layer and the second electron transport layer being adjacent to the first layer.

5. The organic electroluminescent device according to claim 1 , wherein the electron donor is an alkaline metal compound or alkaline metal complex.

6. The organic electroluminescent device according to claim 5 , wherein the electron donor is quinolilato-lithium.

7. A method of manufacturing the organic electroluminescent device according to claim 1 , comprising:

depositing a premix of a compound represented by general formula (1) and electron donor to obtain the electron transport layer.

8. An organic electroluminescent device containing one or more light emitting layers and one or more electron transport layers between opposing anode and cathode, wherein at least one of the electron transport layers contains a compound represented by general formula (1) below and an electron donor:

wherein, ring A represents an aromatic hydrocarbon ring represented by formula (1a), ring B represents a heterocyclic ring represented by formula (1b), and ring A and ring B are condensed with a ring adjacent to ring A and ring B at arbitrary locations,

L represents a single bond or aromatic hydrocarbon group having 6 to 12 carbon atoms,

X represents N or C—Ar 1 and at least one of X represents N,

Y and Ar 1 respectively and independently represent a hydrogen atom, substituted or unsubstituted aromatic hydrocarbon group having 6 to 18 carbon atoms, substituted or unsubstituted aromatic heterocyclic group having 3 to 18 carbon atoms, or a linked aromatic group obtained by linking 2 to 5 of these aromatic rings,

R 1 independently represents an aliphatic hydrocarbon group having 1 to 10 carbon atoms, a substituted or unsubstituted aromatic hydrocarbon group having 6 to 10 carbon atoms, or a substituted or unsubstituted aromatic heterocyclic group having 3 to 12 carbon atoms, and a, b and c respectively and independently represent an integer of 0 to 3,

Z represents N—Ar 2 , C(R 2 ) 2 , O or S, wherein Ar 2 represents a substituted or unsubstituted aromatic hydrocarbon group having 6 to 18 carbon atoms, a substituted or unsubstituted aromatic heterocyclic group having 3 to 18 carbon atoms, or a linked aromatic group obtained by linking 2 to 5 of these aromatic rings, and R 2 independently represents a hydrogen atom, aliphatic hydrocarbon group having 1 to 10 carbon atoms, substituted or unsubstituted aromatic hydrocarbon group having 6 to 10 carbon atoms, or substituted or unsubstituted aromatic heterocyclic group having 3 to 12 carbon atoms,

wherein the light emitting layer contains a host material and a luminescent material, the light emitting layer containing as the host material a compound represented by general formula (1).