Method for producing porous carbon material and spherical porous carbon material
A novel method for producing a porous carbon material which makes it possible to easily produce a porous carbon material having a desired shape; and a spherical porous carbon material are provided. The method includes immersing a carbon-containing material having a desired shape and composed of a compound, alloy or non-equilibrium alloy containing carbon in a metal bath, the metal bath having a solidification point that is lower than a melting point of the carbon-containing material, the metal bath being controlled to a lower temperature than a minimum value of a liquidus temperature within a compositional fluctuation range extending from the carbon-containing material to carbon by decreasing the other non-carbon main components, to thereby selectively elute the other non-carbon main components into the metal bath while maintaining an external shape of the carbon-containing material to give a porous carbon material having microvoids.
1. A spherical porous carbon material with a plurality of pores, wherein
the spherical porous carbon material is of a spherical shape,
the plurality of pores including first pores having a diameter in the range of from 2 nm to 60 nm and second pores having a diameter of 60 nm or more,
80%-91% of pores of the spherical porous carbon material range in size between 2 nm and 200 nm in a volume of all pores, and
the spherical porous carbon material has a BET specific surface area of 100 m 2 /g or more and 128 m 2 /g or less.
2. The spherical porous carbon material according to claim 1 , wherein the spherical porous carbon material is produced by:
bringing a carbon-containing material having a spherical shape and composed of a compound, alloy or non-equilibrium alloy containing carbon into contact with a molten metal, the molten metal having a solidification point that is lower than a melting point of the carbon-containing material, the molten metal being controlled to a lower temperature than a minimum value of a liquidus temperature within a compositional fluctuation range extending from the carbon-containing material to the carbon by decreasing the other non-carbon main components, to thereby selectively elute the other non-carbon main components into the molten metal while maintaining an external shape of the carbon-containing material to form the spherical porous carbon material.
3. A spherical porous carbon material with a plurality of pores, wherein
the spherical porous carbon material is of a spherical shape,
the plurality of pores including first pores having a diameter in the range of from 2 nm to 60 nm and second pores having a diameter of 60 nm or more,
80%-91% of pores of the spherical porous carbon material range in size between 2 nm and 200 nm in a volume of all pores,
the spherical porous carbon material has a BET specific surface area of 100 m 2 /g or more and 128 m 2 /g or less, and
the spherical porous carbon material consists essentially of carbon, the spherical porous carbon material consisting essentially of carbon being produced by
bringing a carbon-containing material having a spherical shape and composed of a compound, alloy or non-equilibrium alloy containing carbon into contact with a molten bismuth, the molten bismuth having a solidification point that is lower than a melting point of the carbon-containing material, the molten bismuth being controlled to a lower temperature than a minimum value of a liquidus temperature within a compositional fluctuation range extending from the carbon-containing material to the carbon by decreasing the other non-carbon main components, to thereby form a composite in which the other non-carbon main components are selectively eluted into the molten bismuth while maintaining an external shape of the carbon-containing material,
the formation of the composite being followed by cooling the composite, and introducing the cooled composite into an aqueous nitric acid solution to dissolve elements other than carbon and subsequently carrying out filtration and pure-water washing to obtain the spherical porous carbon material consisting essentially of carbon.