Polarizer protecting film, polarizer plate comprising the same, liquid crystal display comprising the polarizer plate, and coating composition for polarizer protecting film
The present disclosure relates to a polarizer protecting film, a polarizing plate including the same, a liquid crystal display including the polarizing plate, and a coating composition for polarizer protecting film. More specifically, it relates to a coating composition capable of producing a polarizer protecting film exhibiting excellent physical and optical characteristics while absorbing and emitting light in a specific wavelength range to enhance visibility of a laser pointer, a polarizer protecting film produced by using the same, a polarizing plate including the polarizer protecting film, and a liquid crystal display including the polarizing plate.
1. A polarizer protecting film, comprising
a substrate and a photocurable resin layer provided on at least one face of the substrate,
wherein the photocurable resin layer comprises a cured product of a photocurable binder and a dye, and
wherein a maximum absorption wavelength is 520 nm to 540 nm and a maximum excitation wavelength is 540 nm to 600 nm, or a maximum absorption wavelength is 610 nm to 660 nm and a maximum excitation wavelength is 640 nm to 680 nm.
2. The polarizer protecting film of claim 1 ,
wherein average light transmittance at a wavelength of 520 nm to 540 nm or 610 nm to 660 nm is less than 85%.
3. The polarizer protecting film of claim 1 ,
wherein average light transmittance at a wavelength of 400 nm to 500 nm is 90% or more.
4. The polarizer protecting film of claim 1 ,
wherein a pencil hardness under a load of 500 g is HB or higher.
5. The polarizer protecting film of claim 1 ,
wherein the film does not have any scratches after moving the same 10 times back and forth in a friction tester with #0 steel wool under a load of 200 g.
6. The polarizer protecting film of claim 1 ,
wherein the substrate comprises at least one selected from the group consisting of polyethylene terephthalate (PET), ethylene vinyl acetate (EVA), a cyclic olefin polymer (COP), a cyclic olefin copolymer (COC), polyacrylate (PAC), polycarbonate (PC), polyethylene (PE), polymethylmethacrylate (PMMA), polyetheretherketone (PEEK), polyethylene naphthalate (PEN), polyetherimide (PEI), polyimide (PI), methyl methacrylate (MMA), fluorine resin, and triacetylcellulose (TAC).
7. The polarizer protecting film of claim 1 ,
wherein a relative luminance value measured by the following Formula 1 is 1.5 or more:
A relative luminance= B/A: [Formula 1]
wherein, in Formula 1,
A is a luminance value measured when a 535 nm or 635 nm laser is irradiated in 60° from a normal direction, after the polarizer protecting film not containing the dye is placed on a backlight side, and
B is a luminance value measured when a 535 nm or 635 nm laser is irradiated in 60° from a normal direction, after the polarizer protecting film containing the dye is placed on a backlight side.
8. A polarizing plate, comprising:
a polarizer; and
the polarizer protecting film of claim 1 provided on at least one face of the polarizer.
9. A liquid crystal display comprising the polarizing plate of claim 8 .
10. A coating composition for a polarizer protecting film, comprising:
a binder containing a photocurable functional group, a dye comprising at least one selected from the group consisting of a compound having a maximum absorption wavelength of 520 nm to 540 nm and a maximum excitation wavelength of 540 nm to 600 nm, and a compound having a maximum absorption wavelength of 610 nm to 660 nm and a maximum excitation wavelength of 640 nm to 680 nm;
a photopolymerization initiator; and
a solvent.
11. The coating composition for a polarizer protecting film of claim 10 ,
wherein the binder containing a photocurable functional group comprises at least one selected from the group consisting of a polyfunctional acrylate-based monomer, a polyfunctional acrylate-based oligomer, and a polyfunctional acrylate-based elastic polymer.
12. The coating composition for a polarizer protecting film of claim 11 ,
wherein the polyfunctional acrylate-based monomer comprises at least one selected from the group consisting of hexanediol diacrylate (HDDA), tripropylene glycol diacrylate (TPGDA), ethylene glycol diacrylate (EGDA), trimethylolpropane triacrylate (TMPTA), tri methylolpropaneethoxy triacrylate (TMPEOTA), glycerin propoxylated triacrylate (GPTA), pentaerythritol tri(tetra)acrylate (PETA), and dipentaerythritol hexaacrylate (DPHA).
13. The coating composition for a polarizer protecting film of claim 10 ,
wherein the composition comprises 0.1 to 5 parts by weight of the dye, 0.1 to 10 parts by weight of the photopolymerization initiator, and 50 to 200 parts by weight of the solvent, based on 100 parts by weight of the binder containing the photocurable functional group.
14. The coating composition for a polarizer protecting film of claim 10 ,
further comprising an organic fine particle or an inorganic fine particle.