IP Library Granted Patent US 10,879,479
Granted Patent B2
US 10,879,479 · App. 16/081,390 · Granted Dec 29, 2020

Systems and methods for organic semiconductor devices with sputtered contact layers

Inventors: Scott R. Hammond (Seattle, WA); Marinus Franciscus Antonius Maria van Hest (Lakewood, CO)
Assignees: SolarWindow Technologies, Inc.; Alliance for Sustainable Energy, LLC
H01L51/442H01L51/0008H01L51/0021H01L51/5012H01L51/5056H01L51/5072H01L51/5215H01L51/5234H01L2251/305H01L2251/308Y02E10/549
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Quick Facts
Patent No.
US 10,879,479
App. No.
16/081,390
Granted
Dec 29, 2020
Kind
B2
Abstract

Systems and methods for organic semiconductor devices with sputtered contact layers are provided. In one embodiment, an organic semiconductor device comprises: a first contact layer ( 140 ) comprising a first sputter-deposited transparent conducting oxide; an electron transport layer ( 130 ) interfacing with the first contact layer; a second contact layer ( 110 ) comprising a second sputter-deposited transparent conducting oxide; a hole transport layer interfacing with the second contact layer; and an organic semiconductor active layer ( 120 ) having a first side facing the electron transport layer and an opposing second side facing the hole transport layer; wherein either the electron transport layer or the hole transport layer comprises a buffering transport layer.

Claims (37)

1. An organic semiconductor device, the device comprising:

a first contact layer comprising a first sputter-deposited transparent conducting oxide;

an electron transport layer interfacing with the first contact layer;

a second contact layer comprising a second sputter-deposited transparent conducting oxide;

a hole transport layer interfacing with the second contact layer;

an organic semiconductor active layer having a first side facing the electron transport layer and an opposing second side facing the hole transport layer; and

a plurality of scribes that extend into the electron transport layer, the hole transport layer, and the organic semiconductor active layer;

wherein either the electron transport layer or the hole transport layer comprises a buffering transport layer;

wherein either the first sputter-deposited transparent conducting oxide or the second sputter-deposited transparent conducting oxide extends into the plurality of scribes and is configured to electrically connect the first contact layer on a first side of each of the plurality of scribes to the second contact layer on a second side of each of the plurality of scribes.

2. The device of claim 1 , wherein the buffering transport layer comprises a transparent polymer material, a semi-transparent polymer material, a transparent oxide material or semi-transparent oxide material.

3. The device of claim 1 , wherein the organic semiconductor active layer comprises either an organic bulk heterojunction structure or a bilayer structure.

4. The device of claim 1 , wherein the organic semiconductor active layer comprises an organic bulk heterojunction absorber layer.

5. The device of claim 1 , wherein the organic semiconductor active layer comprises an organic emissive electroluminescent layer.

6. The device of claim 1 , wherein the first sputter-deposited transparent conducting oxide and the second sputter-deposited transparent conducting oxide both comprise sputter-deposited indium zinc oxide (IZO).

7. The device of claim 1 , wherein at least one of the first sputter-deposited transparent conducting oxide or the second sputter-deposited transparent conducting oxide comprise at least one of:

sputtered indium zinc oxide (IZO);

sputtered indium tin oxide (ITO);

sputtered aluminum doped zinc oxide (AZO); or

sputtered gallium doped zinc oxide (GZO).

8. The device of claim 1 , further comprising a substrate layer adjacent to either the first contact layer or the second contact layer.

9. An organic semiconductor device, the device comprising:

a substrate;

one or more backside device layers adjacent to the substrate;

an organic semiconductor active layer having an interface with the one or more backside device layers;

a buffering transport layer applied over the organic semiconductor active layer;

a plurality of scribes that extend into the buffering transport layer, the organic semiconductor active layer and the one or more backside device layers; and

a sputter-deposited transparent material contact layer applied over the buffering transport layer and into the plurality of scribes, wherein the sputter-deposited transparent material contact layer defines a front contact layer on a first side of each of the plurality of scribes and is configured to electrically connect the front contact layer to a back contact layer within the one or more backside device layers on a second side of each of the plurality of scribes.

10. The device of claim 9 , wherein the sputtered transparent material contact layer comprises a sputter-deposited transparent conducting oxide.

11. The device of claim 10 , wherein the sputter-deposited transparent conducting oxide comprises a sputtered indium zinc oxide (IZO).

12. The device of claim 9 , wherein the buffering transport layer comprises at least one of, a transparent polymer material, a semi-transparent polymer material, a transparent oxide material or semi-transparent oxide material.

13. The device of claim 9 , wherein the organic semiconductor active layer comprises either an organic bulk heterojunction structure or a bilayer structure.

14. A device comprising in order:

a front contact layer comprising a sputter-deposited transparent conducting oxide;

a buffering transport layer;

an organic semiconductor active layer; and

a plurality of scribes that extend into the buffering transport layer and the organic semiconductor active layer;

wherein the sputter-deposited transparent conducting oxide is applied over the buffering transport layer and into the plurality of scribes, wherein the sputter-deposited transparent conducting oxide is configured to electrically connect the front contact layer on a first side of each of the plurality of scribes to a back contact layer on a second side of each of the plurality of scribes.

Assignments (4)
CHANGE OF NAME Recorded Dec 16, 2025
From: ALLIANCE FOR SUSTAINABLE ENERGY, LLC
To: ALLIANCE FOR ENERGY INNOVATION, LLC
Reel/Frame 073993/0276 →
CONFIRMATORY LICENSE Recorded Mar 26, 2019
From: NATIONAL RENEWABLE ENERGY LABORATORY
To: UNITED STATES DEPARTMENT OF ENERGY
Reel/Frame 048703/0957 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 10, 2019
From: HAMMOND, SCOTT R.
To: SOLARWINDOW TECHNOLOGIES, INC.
Reel/Frame 047956/0834 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 2, 2018
From: VAN HEST, MARINUS FRANCISCUS ANTONIUS MARIA
To: ALLIANCE FOR SUSTAINABLE ENERGY, LLC
Reel/Frame 047029/0898 →