Food packaging film and manufacturing method for making the same
The present invention relates to a multilayer film, especially to a multilayer thermoplastic film, which may be used for food packaging, wherein the multilayer film according to the present invention may be provided, on its inner side, with a food additive, particularly with a flavoring and/or coloring and/or an aroma producing food additive (such as e.g. a liquid smoke), which food additive is then released and transferred onto the surface of a foodstuff encased in the multilayer film during cooking and/or processing of the foodstuff.
1. A thermoplastic multilayer film to be used for food packaging, wherein the multilayer film comprises at least three polymeric layers and/or layer composites:
(A) an inner layer composite, which inner layer composite is an inner food contacting layer composite, wherein the inner layer composite comprises a plurality of single inner layers attached and/or adhered to one another, wherein the single inner layers are each composed of at least one foamed polymer comprising at least one polyolefin and wherein the single inner layers each comprise a multitude of voids selected among open cells and pores and being capable of reversibly retaining and/or absorbing at least one food additive;
wherein the inner layer composite comprises at least three single inner layers, wherein the various single inner layers, same or different and independently from one another, each comprise at least one polyolefinic polymer, copolymer, or terpolymer;
(B) an outer layer composite, wherein the outer layer composite comprises a plurality of single outer layers attached and/or adhered to one another, wherein the single outer layers each comprise at least one polyamide;
(C) an adhesive layer in the form of a tie layer disposed between the inner layer composite and the outer layer composite and adhered to the inner layer composite and the outer layer composite;
wherein the thickness ratio [outer layer composite:inner layer composite:adhesive layer] is [55-75:25-45:1-10];
wherein the multilayer film has a relative volume-based porosity, based on the overall volume of the multilayer film, in the range of from 15 to 70 Vol.-%, wherein the porosity of the multilayer film is provided by the multitude of voids comprised by the single inner layers of the inner layer composite;
wherein the multilayer film has a relative weight-based loadability or absorption capacity with the respect to the at least one food additive, based on the overall dry weight of the multilayer film, in the range of from 10 wt. % to 150 wt. %; and
wherein the multilayer film has a water vapor transmission rate in the range of from 5 to 500 g/m 2 /24 hours, as determined according to ASTM F1249-06.
2. The multilayer film according to claim 1 ,
wherein the layers and/or layer composites of the multilayer film are adhered or attached to one another by coextrusion.
3. The multilayer film according to claim 1 ,
wherein the multilayer film has a shrinkage value (shrinkability) in the range of from 10% to 70% at a temperature of 90° C. in the longitudinal and/or transverse direction, as determined according to ASTM D2732.
4. The multilayer film according to claim 1 ,
wherein the multilayer film has an oxygen transmission rate (O 2 transmission rate) in the range of from 1 to 90 cm 3 /m 2 /24 hours, at a pressure of 1 atmosphere (101.325 kPa) and at a temperature of 23° C., as determined according to ASTM D-3985-81.
5. The multilayer film according to claim 1 ,
wherein the multilayer film has a tensile strength in the longitudinal and/or transverse direction in the range of from 15 to 100 MPa, as determined according to ASTM D-882, Method A.
6. The multilayer film according to claim 1 ,
wherein the multilayer film has an elongation at break in the longitudinal and/or transverse direction in the range of from 20 to 300%, as determined according to ASTM D-882, Method A.
7. The multilayer film according to claim 1 ,
wherein the multilayer film has a tensile modulus in the longitudinal and/or transverse direction in the range of from 100 to 400 MPa.
8. The multilayer film according to claim 1 ,
wherein the inner layer composite has a thickness in the range of from 5 to 200 micrometers.
9. The multilayer film according to claim 1 ,
wherein the outer layer composite has a thickness in the range of from 5 to 300 micrometers.
10. The multilayer film according to claim 1 ,
wherein the at least one food additive comprises a flavoring and/or coloring and/or odoring food additive.
11. The multilayer film according to claim 1 ,
wherein the at least one food additive comprises a liquid smoke or caramel.
12. The multilayer film according to claim 1 ,
wherein the various single inner layers, same or different and independently from one another, each comprise at least one polyolefinic polymer, copolymer or terpolymer selected from the group consisting of LDPEs, LLDPEs, VLDPEs as well as blends and copolymers and terpolymers thereof.
13. The multilayer film according to claim 1 ,
wherein the various single inner layers, same or different and independently from one another, each comprise at least one polyolefin having a density in the range of from 0.910 to 0.940 g/cm 3 .
14. The multilayer film according to claim 1 ,
wherein the various single inner layers, same or different and independently from one another, each comprise at least 60 wt. % of at least one polyolefin, based on the overall dry weight of the respective single inner layer.
15. The multilayer film according to claim 1 ,
wherein the multitude of voids are generated by (co-)extrusion of the single inner layers in the presence of at least one foaming agent.
16. The multilayer film according to claim 1 ,
wherein the voids of the single inner layers are open voids in the form of open cells or pores.
17. The multilayer film according to claim 1 ,
wherein the various single outer layers, same or different and independently from one another, each comprise at least one polyamide selected from the group consisting of aliphatic, semiaromatic and aromatic polyamides as well as blends thereof.
18. The multilayer film according to claim 1 ,
wherein the various single outer layers, same or different and independently from one another, each comprise at least one polyamide selected from the group consisting of PA 6, PA 66, PA 6.66, PA 6.11, PA 6.12, PA 11 and PA 12 as well as blends thereof.
19. The multilayer film according to claim 1 ,
wherein the various single outer layers, same or different and independently from one another, each comprise at least 70 wt. % of at least one polyamide, based on the overall dry weight of the respective single outer layer.
20. The multilayer film according to claim 1 ,
wherein the outer layer composite comprises at least two single outer layers, which single outer layers are attached and/or adhered to one another via coextrusion and which single outer layers, independently from one another, each comprise at least one polyamide selected from the group consisting of aliphatic, semiaromatic and aromatic polyamides as well as blends thereof.
21. The multilayer film according to claim 1 ,
wherein the outer layer composite comprises at least two single outer layers, which single outer layers are attached and/or adhered to one another via coextrusion and which single outer layers, independently from one another, each comprise at least one polyamide selected from the group consisting of PA 6, PA 66, PA 6.66, PA 6.11, PA 6.12, PA 11 and PA 12 as well as blends thereof.
22. The multilayer film according to claim 1 ,
wherein the inner layer composite comprises at least four single inner layers, which single inner layers are attached and/or adhered to one another via coextrusion and which single inner layers, independently from one another, each comprise at least one polyolefinic polymer, copolymer or terpolymer selected from the group consisting of LDPEs, LLDPEs, VLDPEs as well as blends and copolymers and terpolymers thereof and having a density in the range of from 0.910 to 0.940 g/cm 3 .