Titanium product and method for producing the same
A titanium product includes an inner layer portion and a surface layer portion joined to the inner layer portion. The surface layer portion has a composition consisting of, by mass %, O: 0.4% or less, Fe: 0.5% or less, Cl: 0.020% or less, the balance: Ti and impurities. The inner layer portion 3 has pores and a composition consisting of, by mass %, O: 0.4% or less, Fe: 0.5% or less, Cl: more than 0.020% and 0.60%, the balance: Ti and impurities. The area fraction of the pores in the inner layer portion in a cross-section perpendicular to the longitudinal direction of the titanium product is more than 0% and not more than 30%. The Cl content (Cl I ) of the inner layer portion, a thickness (t S ) of the surface layer portion, and a thickness (t I ) of the inner layer portion satisfy the expression [Cl I ≤0.03+0.02×t S /t I ].
1. A titanium product comprising an inner layer portion and a surface layer portion, wherein:
a chemical composition of the surface layer portion consists, by mass %, of:
O: 0.40% or less,
Fe: 0.50% or less,
Cl: 0.020% or less,
N: 0.050% or less,
C: 0.080% or less,
H: 0.013% or less, and
the balance: Ti and impurities;
a porosity of the surface layer portion is less than 0.1%;
a chemical composition of the inner layer portion consists, by mass %, of:
O: 0.40% or less,
Fe: 0.50% or less,
Cl: more than 0.020 and not more than 0.60%,
N: 0.050% or less,
C: 0.080% or less,
H: 0.013% or less, and
the balance: Ti and impurities;
the inner layer portion has pores;
in a cross-section perpendicular to a longitudinal direction of the titanium product, an area fraction of the pores of the inner layer portion is more than 0% and not more than 5%, the area fraction of the pores being measured with an optical microscope at 500× magnification; and
the titanium product satisfies formula (i) below:
Cl I ≤0.03+0.02× t S /t I (i)
where, the meaning of each symbol in formula (i) above is as follows:
Cl I : Cl content (mass %) of inner layer portion
t S : thickness of surface layer portion
t I : thickness of inner layer portion.
2. The titanium product according to claim 1 , wherein a thickness of the titanium product is 100 mm or less.
3. The titanium product according to claim 1 , wherein the area fraction of the pores of the inner layer portion is 0.1% or more.
4. The titanium product according to claim 1 , further comprising a boundary between the surface layer portion and the inner layer portion, the boundary distinguishable by polishing and etching a cross-section of the titanium product perpendicular to a rolling direction of the titanium product.
5. A method for producing a titanium product, the titanium product being according to claim 1 , comprising:
a step of fabricating a titanium package having a chemical composition consisting, by mass %, of,
O: 0.40% or less,
Fe: 030% or less,
Cl: 0,020% or less,
N: 0.050% or less,
C: 0,080% or less,
H: 0.013% or less, and
the balance: Ti and impurities;
a step of filling the titanium package with one or more types selected from titanium sponge and a briquette obtained by compressing the titanium sponge,
the titanium sponge having a chemical composition consisting, by mass %, of,
O: 0.40% or less,
Fe: 0.50% or less,
Cl: more than 0.020 and not more than 0.60%,
N: 0.050% or less,
C: 0.080% or less,
H: 0.013% or less, and
the balance: Ti and impurities;
a step of making a degree of vacuum inside the titanium package 10 Pa or less, and thereafter hermetically sealing a circumference of the titanium package so that the degree of vacuum inside the titanium package is maintained, to thereby form a titanium packing body; and
a step of performing hot working on the titanium packing body.
6. The method for producing a titanium product according to claim 2 , further comprising:
a step of performing cold working and annealing after the step of performing hot working.