Photocurable silicone composition and cured product thereof
View Patent ↗A photocurable silicone composition comprises: (A) an organopolysiloxane represented by the average composition formula: R 1 a R 2 b SiO (4-a-b)/2 where R 1 is an alkenyl group having from 2 to 12 carbons, R 2 is an alkyl group having from 1 to 12 carbons, an aryl group having from 6 to 12 carbons, or an aralkyl group having from 7 to 12 carbons; provided that, at least 30 mol % of R 2 are the aryl groups or the aralkyl groups; and “a” and “b” are positive numbers satisfying: 1≤(a+b)≤2.5 and 0.001≤a/(a+b)≤0.2; (B) an organic compound having at least two ether bonds and at least one aliphatic carbon-carbon double bond in a molecule; (C) a compound having at least two thiol groups in a molecule; (D) a photoradical initiator having a phosphorus atom; and (E) a hindered phenol compound.
1. A photocurable silicone composition comprising:
(A) 100 parts by mass of an organopolysiloxane represented by the average composition formula:
R 1 a R 2 b SiO (4-a-b)/2
where R 1 is an alkenyl group having from 2 to 12 carbons, R 2 is an alkyl group having from 1 to 12 carbons, an aryl group having from 6 to 12 carbons, or an aralkyl group having from 7 to 12 carbons; provided that, at least 30 mol % of R 2 are the aryl groups or the aralkyl groups; and “a” and “b” are positive numbers satisfying: 1≤(a+b)≤2.5 and 0.001≤a/(a+b)≤0.2;
(B) from 3 to 30 parts by mass of an organic compound having at least two ether bonds and at least one aliphatic carbon-carbon double bond in a molecule;
(C) a compound having at least two thiol groups in a molecule, in an amount that the amount of the thiol groups in component (C) is from 0.2 to 2.0 mol per 1 mol of the total aliphatic carbon-carbon double bonds in the photocurable silicone composition;
(D) from 0.05 to 1.0 part by mass of a photoradical initiator having a phosphorus atom;
(E) from 0.001 to 1.0 part by mass of a hindered phenol compound; and
(F) from 0.0001 to 1 part by mass of a radical scavenger selected from the group consisting of N,N′,N″,N′″-tetrakis(4,6-bis(butyl-(N-methyl-2,2,6,6-tetramethylpiperidin-4-yl)amino)-triazin-2-yl)-4,7-diazadecane-1,10-diamine, bis(1,2,2,6,6-pentamethyl-4-piperidyl)[[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]methyl]butylmalonate, methyl-1,2,2,6,6-pentamethyl-4-piperidyl)sebacate, bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate, bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate, 8-acetyl-3-dodecyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro]4.5]decane-2,4-dione, methylhydroquinone, 1,4-naphthoquinone, 4-methoxynaphthol, tert-butylhydroquinone, aluminum-N-nitroso-N-phenylhydroxylamine, and pyrogallol.
2. The photocurable silicone composition according to claim 1 , wherein component (B) is an organic compound having at least two ether bonds and at least one acryloyl group or methacryloyl group in a molecule.
3. The photocurable silicone composition according to claim 2 , further comprising (G) an organic compound having an aliphatic carbon-carbon double bond other than components (A) and (B), in an amount of 10 parts by mass or less per 100 parts by mass of component (A).
4. The photocurable silicone composition according to claim 1 , further comprising (G) an organic compound having an aliphatic carbon-carbon double bond other than components (A) and (B), in an amount of 10 parts by mass or less per 100 parts by mass of component (A).
5. A cured product obtained by irradiating the photocurable silicone composition according to claim 1 with light.