Barrier additives
View Patent ↗The present invention relates to processes for making compatibilized high aspect ratio barrier additives and polymer compositions that comprise compatibilized high aspect ratio barrier additives. The invention also relates to compositions produced by these processes, and articles formed from polymer compositions of this invention. The barrier additives provide passive barriers to gas molecules such as oxygen and carbon dioxide minimizing transit of such molecules through sidewalls of polymer articles containing the barrier additives.
1. A polymer composition comprising a preselected polymer and a barrier additive composition, wherein the barrier additive composition is prepared according to a method comprising the steps of:
(a) selecting a layered inorganic barrier additive precursor capable of intercalating small molecules, wherein the layered inorganic barrier additive precursor is a layered double hydroxide;
(b) selecting an organic compatibilization agent capable of intercalating into and bonding either ionically or covalently with the layered inorganic barrier additive precursor, wherein the organic compatibilization agent has similar solubility parameters to the preselected polymer, has a chain length when extended greater than about 2 nanometers, and is thermally stable under melt processing conditions employed for processing the preselected polymer;
(c) selecting a vehicle, wherein the vehicle has similar solubility parameters to both the preselected polymer and the organic compatibilization agent, and is thermally stable under conditions employed for melt processing the preselected polymer;
(d) reacting the organic compatibilization agent with the layered inorganic barrier additive precursor to provide a compatibilized barrier additive; and
(e) incorporating the compatibilized barrier additive with the vehicle to provide the barrier additive composition;
wherein the organic compatibilization agent is selected from the group consisting of polyethylene glycol tridecyl ether phosphate, polyethylene glycol phenyl ether phosphate, polyethylene glycol tristyrylphenyl ether phosphate, and combinations thereof.
2. A polymer composition comprising a preselected polymer and a barrier additive composition, wherein the barrier additive composition is prepared according to a method comprising the steps of:
(a) selecting a layered inorganic barrier additive precursor capable of intercalating small molecules, wherein the layered inorganic barrier additive precursor is a layered double hydroxide;
(b) selecting an organic compatibilization agent capable of intercalating into and bonding either ionically or covalently with the layered inorganic barrier additive precursor, wherein the organic compatibilization agent has similar solubility parameters to the preselected polymer, has a chain length when extended greater than about 2 nanometers, and is thermally stable under melt processing conditions employed for processing the preselected polymer;
(c) selecting a vehicle, wherein the vehicle has similar solubility parameters to both the preselected polymer and the organic compatibilization agent, and is thermally stable under conditions employed for melt processing the preselected polymer;
(d) reacting the organic compatibilization agent with the layered inorganic barrier additive precursor to provide a compatibilized barrier additive; and
(e) incorporating the compatibilized barrier additive with the vehicle to provide the barrier additive composition;
wherein the preselected polymer is a polyester or a polyamide, and wherein the vehicle is selected from the group consisting of dioleates, citrates, adipates, dibenzoates, hydrogenated and acetylated oil monoglycerides, and combinations thereof.
3. A polymer composition comprising a preselected polymer and a barrier additive composition, wherein the barrier additive composition is prepared according to a method comprising the steps of:
(a) selecting a layered inorganic barrier additive precursor capable of intercalating small molecules, wherein the layered inorganic barrier additive precursor is a layered double hydroxide;
(b) selecting an organic compatibilization agent capable of intercalating into and bonding either ionically or covalently with the layered inorganic barrier additive precursor, wherein the organic compatibilization agent has similar solubility parameters to the preselected polymer, has a chain length when extended greater than about 2 nanometers, and is thermally stable under melt processing conditions employed for processing the preselected polymer;
(c) selecting a vehicle, wherein the vehicle has similar solubility parameters to both the preselected polymer and the organic compatibilization agent, and is thermally stable under conditions employed for melt processing the preselected polymer;
(d) reacting the organic compatibilization agent with the layered inorganic barrier additive precursor to provide a compatibilized barrier additive; and
(e) incorporating the compatibilized barrier additive with the vehicle to provide the barrier additive composition;
wherein the preselected polymer is a polyolefin, and wherein the vehicle is selected from the group consisting of mineral oils, unsaturated vegetable oils, and combinations thereof.
4. A polymeric article comprising the polymer composition according to claim 1 .
5. A polymeric article comprising the polymer composition according to claim 2 .
6. A polymeric article comprising the polymer composition according to claim 3 .