Polyamide resin composition and molded article
View Patent ↗Provided is a polyamide resin composition capable of yielding highly abrasion-resistant molded article, while keeping high mechanical strength, and, a molded article using the polyamide resin composition. The polyamide resin composition contains (A) polyamide resin, (B) polyolefin wax, and (C) at least one metal salt selected from alkali metal salt and alkali earth metal salt, and the (A) polyamide resin contains (a-1) semiaromatic polyamide resin.
1. A polyamide resin composition comprising:
(A) polyamide resin,
(B) polyolefin wax,
(C) at least one metal salt selected from CaCO 3 and/or BaCO 3 , and
glass fiber,
the (A) polyamide resin containing (a-1) a polyamide resin that comprises a structural unit derived from diamine and a structural unit derived from dicarboxylic acid, 70 mol % or more of the structural unit derived from diamine being derived from at least either meta-xylylenediamine or para-xylylenediamine, and 70 mol % or more of the structural unit derived from dicarboxylic acid being derived from a straight chain aliphatic α, ω-dicarboxylic acid having 4 to 20 carbon atoms, and
50 mol % or more of the structural unit derived from diamine being derived from meta-xylylenediamine;
the (B) polyolefin wax being contained in an amount of 4 parts by mass or above and 25 parts by mass or below, per 100 parts by mass of the (A) polyamide resin; and
the mass ratio of the glass fiber and the metal salt is 86:11 to 157:5.
2. The polyamide resin composition of claim 1 ,
wherein the (C) metal salt has a particle form with an aspect ratio of smaller than 5.
3. The polyamide resin composition of claim 1 ,
wherein the (C) metal salt has a particle form with an aspect ratio of smaller than 5, and is calcium carbonate.
4. The polyamide resin composition of claim 1 , further comprising:
(a-2) polyamide resin having a melting point higher than a melting point of the (a-1) polyamide resin that comprises the structural unit derived from diamine and the structural unit derived from dicarboxylic acid.
5. The polyamide resin composition of claim 4 ,
wherein the (a-2) polyamide resin is polyamide 66.
6. The polyamide resin composition of claim 1 ,
wherein the glass fiber is present in an amount of 10 to 200 parts by mass per 100 parts by mass of the (A) polyamide resin.
7. The polyamide resin composition of claim 1 , further comprising:
0.1 to 10 parts by mass of a nucleating agent, per 100 parts by mass of the (A) polyamide resin.
8. The polyamide resin composition of claim 1 , further comprising:
0.1 to 10 parts by mass of a black colorant, per 100 parts by mass of the (A) polyamide resin.
9. The polyamide resin composition of claim 1 ,
wherein the (A) polyamide resin further comprises (a-3) aliphatic polyamide resin having a melting point lower than a melting point of the (a-1) polyamide resin that comprises the structural unit derived from diamine and the structural unit derived from dicarboxylic acid, and having a glass transition temperature 20° C. or more lower than a glass transition temperature of the (a-1) polyamide resin that comprises the structural unit derived from diamine and the structural unit derived from dicarboxylic acid.
10. The polyamide resin composition of claim 1 , wherein the metal salt has a particle size of 0.1 to 50 μm.
11. The polyamide resin composition of claim 8 , wherein the black colorant is a carbon black having a DBP oil absorption of 40 to 60 g/cm 3 .
12. The polyamide resin composition of claim 4 , which has a ratio by mass of the (a-1) polyamide resin that comprises the structural unit derived from diamine and the structural unit derived from dicarboxylic acid and the (a-2) polyamide resin, namely (a-1)/(a-2), of 3.0 to 8.0.
13. The polyamide resin composition of claim 9 ,
which further comprises (a-2) polyamide resin having a melting point higher than a melting point of the (a-1) polyamide resin that comprises the structural unit derived from diamine and the structural unit derived from dicarboxylic acid;
has a total content of the (a-1) polyamide resin that comprises the structural unit derived from diamine and the structural unit derived from dicarboxylic acid and the (a-2) polyamide resin and the (a-3) aliphatic polyamide resin accounts for 95% by mass or more; and
has a ratio by mass of the (a-1) polyamide resin that comprises the structural unit derived from diamine and the structural unit derived from dicarboxylic acid and the (a-3) aliphatic polyamide resin, namely (a-1)/(a-3), of 0.5 to 5.0.
14. A molded article formed by using the polyamide resin composition described in claim 1 .
15. A sliding part formed by using the polyamide resin composition described in claim 1 .
16. The polyamide resin composition of claim 1 ,
wherein the (C) metal salt has a particle form with an aspect ratio of smaller than 5, and is calcium carbonate,
the polyamide resin composition further comprising (a-2) polyamide resin having a melting point higher than a melting point of the (a-1) polyamide resin that comprises the structural unit derived from diamine and the structural unit derived from dicarboxylic acid.