Polyalkylene glycol-based lubricant composition
View Patent ↗A lubricant composition includes: an oil selected from among polyalkylene glycols (PAG); and a nitrogen compound selected from among amine phosphates or amine tungstates. The lubricant composition is particularly suitable for lubricating a vehicle engine, preferably a motor vehicle engine. Also disclosed is an engine lubrication method utilizing such composition.
1. Lubricating composition comprising from 1 to 30 wt % of an oil selected from polyalkyl glycols (PAG or polyalkylene glycols), a nitrogen compound selected from amine tungstates and further comprising a friction modifier selected from organomolybdenum compounds, and derivatives thereof.
2. Lubricating composition according to claim 1 for which the nitrogen compound is chosen from:
amine tungstates obtained from at least one fatty amine comprising at least one linear alkyl group comprising from 8 to 15 carbon atoms;
amine tungstates obtained from at least one fatty amine comprising at least one branched alkyl group comprising from 8 to 15 carbon atoms;
a mixture of at least one amine tungstate obtained from at least one fatty amine comprising at least one linear alkyl group comprising from 8 to 15 carbon atoms, and an amine tungstate obtained from at least one fatty amine comprising at least one branched alkyl group comprising from 8 to 15 carbon atoms.
3. Lubricating composition according to claim 1 , wherein the PAG is a block polymer of formula (II) or a random polymer of formula (II)
in which:
R3 represents a linear or branched C 1 -C 30 -alkyl group;
n represents a number ranging from 2 to 60;
R4 and R5, identical or different, independently represent a hydrogen atom or a C 1 -C 2 -alkyl group.
4. Lubricating composition according to claim 1 for which the PAG is chosen from a block polymer of formula (IIA) or a random polymer of formula (IIA)
in which:
R3 represents a linear or branched C 1 -C 30 -alkyl group;
m represents a number ranging from 2 to 60;
R6 and R7 represent a hydrogen atom; or R6 represents a hydrogen atom and R7 represents a methyl group; or R6 represents a methyl group and R7 represents a hydrogen atom; or R6 and R7 represent a methyl group; or R6 represents an ethyl group and R7 represents a hydrogen atom; or R6 represents a hydrogen atom and R7 represents an ethyl group;
a block polymer of formula (IIB) or a random polymer of formula (IIB)
in which:
R3 represents a linear or branched C 1 -C 30 -alkyl group;
p and q independently represent a number ranging from 1 to 30;
R8 and R9 represent a hydrogen atom; or R8 represents a hydrogen atom and R9 represents a methyl group; or R8 represents a methyl group and R9 represents a hydrogen atom; or R8 and R9 represent a methyl group; or R8 represents an ethyl group and R9 represents a hydrogen atom; or R8 represents a hydrogen atom and R9 represents an ethyl group;
R10 and R11 represent a hydrogen atom; or R10 represents a hydrogen atom and R11 represents a methyl group; or R10 represents a methyl group and R11 represents a hydrogen atom; or R10 and R11 represent a methyl group; or R10 represents an ethyl group and R11 represents a hydrogen atom; or R10 represents a hydrogen atom and R11 represents an ethyl group.
5. Lubricating composition according to claim 1 for which the PAG is chosen from a block polymer of formula (III) or a random polymer of formula (III)
in which:
R3 represents a linear or branched C 4 -C 12 -alkyl group;
p represents a number ranging from 1 to 30;
q represents a number ranging from 1 to 30, or a block polymer of formula (IV) or a random polymer of formula (IV)
in which:
R3 represents a linear or branched C 8 -C 12 -alkyl group;
p represents a number ranging from 2 to 6;
q represents a number ranging from 2 to 5;
a block polymer of formula (V) or a random polymer of formula (V)
in which:
R3 represents a linear or branched C 4 -C 12 -alkyl group;
r represents a number ranging from 2 to 60.
6. Lubricating composition according to claim 1 , wherein the PAG is a block polymer of formula (VI) or a random polymer of formula (VI)
in which:
R12 represents a linear or branched C 1 -C 30 -alkyl group;
s and t independently represent an average number ranging from 1 to 5.
7. Lubricating composition according to claim 1 , comprising from 1 to 20% by weight of PAG.
8. Lubricating composition according to claim 1 , comprising from 1 to 15% by weight of PAG.
9. Lubricating composition according to claim 1 , comprising from 0.1 to 3% by weight of nitrogen compound.
10. Lubricating composition according to claim 1 , comprising a lubricating base oil.
11. Method for the lubrication of an engine or for the lubrication of an automobile engine comprising at least one step of bringing the motor into contact with the lubricating composition according to claim 1 .