IP Library Granted Patent US 10,818,757
Granted Patent B2
US 10,818,757 · App. 16/088,221 · Granted Oct 27, 2020

Nitride semiconductor substrate, semiconductor device, and method for manufacturing nitride semiconductor substrate

Inventor: Yoshinobu Narita (Ibaraki, JP)
Assignees: SCIOCS COMPANY LIMITED; SUMITOMO CHEMICAL COMPANY, LIMITED
H01L29/365H01L21/0254H01L21/0262H01L21/02584H01L29/2003H01L29/8613H01L29/872
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Quick Facts
Patent No.
US 10,818,757
App. No.
16/088,221
Granted
Oct 27, 2020
Kind
B2
Abstract

There is provided a nitride semiconductor substrate, including: a substrate configured as an n-type semiconductor substrate; and a drift layer provided on the substrate and configured as a gallium nitride layer containing donors and carbons, wherein a concentration of the donors in the drift layer is 5.0×10 16 /cm 3 or less, and is equal to or more than a concentration of the carbons that function as acceptors in the drift layer, over an entire area of the drift layer, and a difference obtained by subtracting the concentration of the carbons that function as acceptors in the drift layer from the concentration of the donors in the drift layer, is gradually decreased from a substrate side toward a surface side of the drift layer.

Claims (43)

1. A nitride semiconductor substrate, comprising:

a substrate configured as an n-type semiconductor substrate; and

a drift layer provided on the substrate and configured as a gallium nitride layer containing donors and carbons,

wherein a concentration of the donors in the drift layer is 5.0×10 16 /cm 3 or less, and is equal to or more than a concentration of the carbons that function as acceptors in the drift layer, over an entire area of the drift layer,

the concentration of the donors in the drift layer is gradually decreased from a substrate side toward a surface side of the drift layer,

a total concentration of the carbons in the drift layer is gradually increased from the substrate side toward the surface side of the drift layer, and

a difference obtained by subtracting the concentration of the carbons that function as the acceptors in the drift layer from the concentration of the donors in the drift layer, is gradually decreased from the substrate side toward the surface side of the drift layer.

2. A nitride semiconductor substrate, comprising:

a substrate configured as an n-type semiconductor substrate; and

a drift layer provided on the substrate and configured as a gallium nitride layer containing donors and carbons,

wherein a concentration of the donors in the drift layer is 5.0×10 16 /cm 3 or less, and is equal to or more than a concentration of the carbons that function as acceptors in the drift layer, over an entire area of the drift layer,

the concentration of the donors in the drift layer is gradually decreased from a substrate side toward a surface side of the drift layer,

a total concentration of the carbons in the drift layer is constant from the substrate side toward the surface side of the drift layer, and

a difference obtained by subtracting the concentration of the carbons that function as the acceptors in the drift layer from the concentration of the donors in the drift layer, is gradually decreased from the substrate side toward the surface side of the drift layer.

3. A nitride semiconductor substrate, comprising:

a substrate configured as an n-type semiconductor substrate; and

a drift layer provided on the substrate and configured as a gallium nitride layer containing donors and carbons,

wherein a concentration of the donors in the drift layer is 5.0×10 16 /cm 3 or less, and is equal to or more than a concentration of the carbons that function as acceptors in the drift layer, over an entire area of the drift layer,

the concentration of the donors in the drift layer is gradually decreased from a substrate side toward a surface side of the drift layer,

a total concentrations of the carbon in the drift layer is gradually decreased from the substrate side toward the surface side of the drift layer, and

a difference obtained by subtracting the concentration of the carbons that function as the acceptors in the drift layer from the concentration of the donors in the drift layer, is gradually decreased from the substrate side toward the surface side of the drift layer.

4. A nitride semiconductor substrate, comprising:

a substrate configured as an n-type semiconductor substrate; and

a drift layer provided on the substrate and configured as a gallium nitride layer containing donors and carbons,

wherein a concentration of the donors in the drift layer is 5.0×10 16 /cm 3 or less, and is equal to or more than a concentration of the carbons that function as acceptors in the drift layer, over an entire area of the drift layer, and

a difference obtained by subtracting the concentration of the carbons that function as the acceptors in the drift layer from the concentration of the donors in the drift layer, is monotonically decreased from a substrate side toward a surface side of the drift layer.

5. The nitride semiconductor substrate according to claim 4 , wherein the difference obtained by subtracting the concentration of the carbons that function as the acceptors in the drift layer from the concentration of the donors in the drift layer, is linearly decreased from the substrate side toward the surface side of the drift layer.

6. A nitride semiconductor substrate, comprising:

a substrate configured as an n-type semiconductor substrate; and

a drift layer provided on the substrate and configured as a gallium nitride layer containing donors and carbons,

wherein a concentration of the donors in the drift layer is 5.0×10 16 /cm 3 or less, and is equal to or more than a concentration of the carbons that function as acceptors in the drift layer, over an entire area of the drift layer, and

a difference obtained by subtracting the concentration of the carbons that function as the acceptors in the drift layer from the concentration of the donors in the drift layer, is decreased gradually and stepwise from the substrate side toward the surface side of the drift layer.

7. A nitride semiconductor substrate, comprising:

a substrate configured as an n-type semiconductor substrate; and

a drift layer provided on the substrate and configured as a gallium nitride layer containing donors and carbons,

wherein a concentration of the donors in the drift layer is 5.0×10 16 /cm 3 or less, and is equal to or more than a concentration of the carbons that function as acceptors in the drift layer, over an entire area of the drift layer, and

a difference obtained by subtracting the concentration of the carbons that functions as the acceptors in the drift layer from the concentration of the donors in the drift layer, is gradually and nonlinearly decreased from the substrate side toward the surface side of the drift layer.

8. The nitride semiconductor substrate according to claim 1 , 2 , or 3 , wherein the concentration of the donors in the drift layer is ⅓ times or more of the a total concentration of the carbons in the drift layer over the entire area of the drift layer.

9. The nitride semiconductor substrate according to claim 4 , 6 , or 7 , wherein the concentration of the donors in the drift layer is ⅓ times or more of a total concentration of the carbons in the drift layer over the entire area of the drift layer.

10. The nitride semiconductor substrate according to claim 1 , 2 , 3 , 4 , 6 , or 7 , wherein the drift layer contains hydrogen, and a concentration of the hydrogen in the drift layer is 5.0×10 16 /cm 3 or less.

11. A semiconductor device, comprising the nitride semiconductor substrate according to claim 1 , 2 , 3 , 4 , 6 , or 7 .

12. A method for manufacturing the nitride semiconductor substrate according to claim 1 , 2 , 3 , 4 , 6 , or 7 comprising:

forming the drift layer as the gallium nitride layer containing the donors and the carbons on the n-type semiconductor substrate.

Assignments (2)
MERGER Recorded Dec 16, 2022
From: SCIOCS COMPANY LIMITED
To: SUMITOMO CHEMICAL COMPANY LIMITED
Reel/Frame 062142/0384 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 25, 2018
From: NARITA, YOSHINOBU
To: SCIOCS COMPANY LIMITED; SUMITOMO CHEMICAL COMPANY, LIMITED
Reel/Frame 046962/0730 →
Priority Claims (1)
JP 2016-070543 · Mar 31, 2016 · national
Continuity (1)
Related Publication 20200127101A1 · Apr 23, 2020