Process for producing epoxidized polymers
A process for forming an epoxidized rubber including dissolving a rubber in a solvent and epoxidizing the rubber in the presence of an epoxidation reagent. The solvent is selected such that the rubber is soluble therein but the epoxidized rubber precipitates.
1. A process for forming an epoxidized polymer comprising dissolving a polymer in a solvent and epoxidizing said polymer in the presence of an epoxidation reagent having an aqueous phase pH in a range of 1.5 to 7.0, said epoxidation reagent comprising one or more peracid selected from the group consisting of peracetic, perbenzoic, meta-perachlorobenzoic, perpropionic and perbutyric, and a buffer, wherein said solvent and reaction conditions are selected such that a majority of the polymer is soluble in the solvent and a majority of the epoxidized polymer precipitates from the solvent.
2. The process of claim 1 , wherein said polymer comprises a diene containing polymer.
3. The process of claim 1 , wherein said solvent is selected from pentane, hexane, heptane and isomers thereof.
4. The process of claim 1 , wherein said buffer comprises a bicarbonate.
5. The process of claim 1 , wherein said peracetic acid comprises a solution having a pH range of about 2-3.
6. The process of claim 1 , wherein the precipitated epoxidized polymer is collected by filtration.
7. The process of claim 1 , wherein the polymer precipitates without the assistance of other chemicals or changes in conditions.
8. A process for forming an epoxidized polymer comprising dissolving a polymer in a solvent and epoxidizinq said polymer in the presence of an epoxidation reagent, wherein said epoxidation reagent comprises a metal based catalyst, peroxide and an acid, and wherein said solvent and reaction conditions are selected such that a majority of the polymer is soluble in the solvent and a majority of the epoxidized polymer precipitates from the solvent.
9. A process for forming an epoxidized polymer comprising dissolving a diene containing polymer in a solvent selected from pentane, hexane, heptane, and isomers thereof, and epoxidizing said polymer in the presence of a performic acid epoxidation agent, wherein the performic acid is directly introduced into the solvent containing the dissolved polymer, said epoxidizing being performed in (i) a temperature range of about −20° C. to 35° C. at substantially atmospheric pressure or (ii) a temperature range of between about −20° C. to 80° C. at elevated pressure, and wherein the epoxidized polymer precipitates from the solvent.
10. The process of claim 7 , further including the addition of a buffer.
11. The process of claim 9 , wherein said polymer is selected from guayule natural rubber, polyisoprene containing polymers, polybutadiene, butyl rubber and mixtures thereof.
12. The process of claim 11 , wherein said polymer comprises guayule having a molecular weight of at least 1,000,000 or a polybutadiene having a molecular weight of at least 400,000.
13. The process of claim 9 , wherein the precipitated epoxidized polymer is collected by filtration.
14. The process of claim 9 , wherein or the performic acid is in the form of an aqueous solution having a pH range between about 1.5 and 5.5.
15. A process for forming an epoxidized polymer comprising dissolving a guayule natural rubber having a molecular weight of at least 1,000,000 or a polybutadiene polymer having a molecular weight of at least 400,000 in a solvent selected from pentane, hexane, heptane, and isomers thereof, and epoxidizing said polymer in the presence of an epoxidation agent selected from peracetic and performic acid, said epoxidizing being performed in (i) a temperature range of about −20° C. to 35° C. at substantially atmospheric pressure or (ii) a temperature range of between about −20° C. to 80° C. at elevated pressure, and wherein the epoxidized polymer precipitates from the solvent.