Processes and systems for the recycle of process water in the production of ethylene glycol

1. A process for the production of ethylene carbonate and/or ethylene glycol comprising:

a) supplying an overhead absorber stream withdrawn from an absorber to a vapor-liquid separator to yield an aqueous bottoms stream and a recycle gas stream;

b) supplying an aqueous process stream comprising one or more impurities to a distillation apparatus to yield an overhead impurities stream and a purified aqueous process stream;

c) supplying at least a portion of the purified aqueous process stream and an ethylene oxide product stream to the absorber; and

d) contacting the ethylene oxide product stream with the purified aqueous process stream in the absorber in the presence of one or more carboxylation and hydrolysis catalysts to yield a fat absorbent stream comprising ethylene carbonate and/or ethylene glycol.

2. The process according to claim 1 wherein the aqueous process stream supplied to the distillation apparatus comprises at least a portion of one or more streams selected from the group consisting of: the aqueous bottoms stream withdrawn from the vapor-liquid separator, an overhead dehydrator stream—withdrawn from a dehydrator, and a combination thereof.

3. The process according to claim 1 , wherein the one or more impurities are selected from the group consisting of: formaldehyde, acetaldehyde, 2,3-epoxy-1,4-dioxane, 1,3-dioxolane, 1,4-dioxane, 2-methyl-1,3-dioxolane, 2-methoxy ethanol, 2,2′-bis-1,3-dioxolane, 2-chloro-methyl-1,3-dioxolane, 2-chloroethanol, and a combination thereof.

4. The process according to claim 1 further comprising:

supplying the aqueous process stream to a preheater and a flash vessel prior to supplying the aqueous process stream to the distillation apparatus.

5. The process according to claim 4 , wherein the preheater is heated via heat integration with a hot process stream withdrawn from a separator.

6. The process according to claim 1 , wherein heat is supplied to the distillation apparatus using a reboiler, and wherein the reboiler is heated by heat integration with a hot process stream withdrawn from a separator.

7. The process according to claim 1 further comprising:

e) supplying at least a portion of the fat absorbent stream to one or more finishing reactors to yield a finishing reactor product stream, and

f) supplying at least a portion of the finishing reactor product stream to a dehydrator to yield a dehydrator bottom stream and an overhead dehydrator stream.

8. The process according to claim 7 further comprising:

g) supplying at least a portion of the dehydrator bottom stream to a separator to yield a glycol product stream and a hot process stream; and

h) supplying at least a portion of the hot process stream to the absorber.