Lithium-rich antiperovskite compound, lithium secondary battery electrolyte comprising same, and lithium secondary battery comprising same
The present invention relates to a Li-rich antiperovskite compound and the use thereof, and more particularly, to a Li-rich antiperovskite compound having a novel structure in which a dopant is substituted in a Li 3 OCl compound, wherein the dopant is substituted for an O site rather than an anionic Cl site, as known in the art, and an electrolyte using the same. The Li-rich antiperovskite compound has high lithium ion conductivity and excellent thermal stability, and thus can be applied as an electrolyte for lithium secondary batteries which are driven at a high temperature.
1. A compound having a lithium-rich antiperovskite (LiRAP) crystal structure represented by the following Formula 1, 2 or 3:
Li 3-x ClO 1-x Hal x [Formula 1]
wherein Hal is F, Cl, Br, or I, and x is 0<x<1;
Li 3-y-x M y O 1-x Hal x Cl [Formula 2]
wherein M is Na, K, Rb, or Cs, Hal is F, Cl, Br, or I, and x and y are 0<x<1 and 0<y<2;
Li 3-2y-x M y O 1-x Hal x Cl [Formula 3]
wherein M is Mg, Ca, Sr, or Ba, Hal is F, Cl, Br, or I, and x and y are 0<x<1 and 0<y<1.
2. The compound of claim 1 , wherein the compound has an ion conductivity of 10 to 10 −10 S/cm.
3. An electrolyte for lithium secondary batteries comprising the compound having a lithium-rich antiperovskite (LiRAP) crystal structure represented by the following Formula 1, 2 or 3:
Li 3-x ClO 1-x Hal x [Formula 1]
wherein Hal is F, Cl, Br, or I, and x is 0<x<1;
Li 3-y-x M y O 1-x Hal x Cl [Formula 2]
wherein M is Na, K, Rb, or Cs, Hal is F, Cl, Br, or I, and x and y are 0<x<1 and 0<y<2;
Li 3-2y-x M y O 1-x Hal x Cl [Formula 3]
wherein M is Mg, Ca, Sr, or Ba, Hal is F, Cl, Br, or I, and x and y are 0<x<1 and 0<y<1.
4. The electrolyte of claim 3 , wherein the compound has an ion conductivity of 10 to 10 −10 S/cm.
5. A lithium secondary battery comprising the electrolyte for lithium secondary batteries defined in claim 3 .
6. The lithium secondary battery of claim 5 , wherein the lithium secondary battery comprises one selected from a lithium-air battery, a lithium oxide battery, a lithium-sulfur battery, a lithium metal battery, and an all-solid-state battery.