Negative electrode for lithium metal secondary battery and method for manufacturing the same
The present disclosure is directed to providing improved processability by forming a protective film on the surface of lithium metal used as an electrode layer through a simple process, and to improving the cycle characteristics of a lithium metal secondary battery by forming a stable protective film. The present disclosure provides a method for manufacturing a negative electrode, including the steps of: (S1) preparing lithium metal; and (S2) dipping the lithium metal in an acid solution for 60-120 seconds to form a LiF film on the surface of lithium metal.
1. A negative electrode for a lithium metal secondary battery, comprising: an electrode active material layer including lithium metal; and a protective film formed on the surface of the electrode layer, wherein the protective film comprises LiF ingredient and has a thickness of 1 μm-20 μm and a porosity of 25%-50%.
2. The negative electrode for a lithium metal secondary battery according to claim 1 , wherein the electrode active material layer comprises lithium metal foil which has a thickness of 20 μm-40 μm.
3. A method for manufacturing a negative electrode for a lithium metal secondary battery, comprising the steps of:
(S11) preparing a negative electrode material provided with an electrode active material layer; and
(S12) dipping the negative electrode material in an acid solution for a period of time equal to or more than 60 seconds and less than 200 seconds to form a LiF protective film on the surface of the electrode active material layer, wherein the electrode active material layer comprises lithium metal.
4. The method for manufacturing a negative electrode for a lithium metal secondary battery according to claim 3 , wherein the acid solution comprises HF.
5. The method for manufacturing a negative electrode for a lithium metal secondary battery according to claim 3 , wherein the acid solution comprises polyethylene glycol (PEG).
6. The method for manufacturing a negative electrode for a lithium metal secondary battery according to claim 3 , wherein the electrode active material layer comprises lithium metal foil which has a thickness of 20 μm-40 μm, and the LiF protective film has a thickness of 1 μm-20 μm.
7. The method for manufacturing a negative electrode for a lithium metal secondary battery according to claim 3 , which further comprises a step of activating the surface of the electrode layer by carrying out mechanical etching, chemical etching, electrochemical etching or plasma etching of the surface of the electrode active material layer, before carrying out step (S12).
8. An electrode assembly comprising a negative electrode, a positive electrode and a separator interposed between the negative electrode and the positive electrode, wherein the negative electrode is defined in claim 1 .
9. A method for manufacturing a secondary battery, comprising the steps of:
(S21) preparing a negative electrode, a positive electrode and a separator;
(S22) interposing the separator between the negative electrode and the positive electrode to provide an electrode assembly; and
(S23) inserting the electrode assembly to a battery casing material and injecting an electrolyte thereto, wherein the negative electrode is defined in claim 1 .