Method for manufacturing electrode for lithium secondary battery
Disclosed is a method for manufacturing an electrode for a lithium secondary battery, including the steps of: (S1) dry mixing a conductive material and an electrode active material; (S2) dry mixing the resultant product of step (S1) with a binder to obtain electrode mixture powder; and (S3) applying the electrode mixture powder to at least one surface of a current collector. According to an embodiment of the present disclosure, electrode mixture powder is prepared without using a solvent and is applied to a current collector to provide an electrode. Thus, there is no need for a separate drying step. Therefore, the binder and conductive material coated on the surface of electrode active material cause no surface migration phenomenon. As a result, it is possible to prevent degradation of the adhesion of the electrode, and thus to prevent degradation of the performance of the lithium secondary battery.
1. A method for manufacturing an electrode for a lithium secondary battery, comprising the steps of: (S1) dry mixing and agitating a conductive material and an electrode active material at a rotation speed of 1,000-2,000 rpm; (S2) dry mixing and agitating the resultant product of step (S1) with a binder, at a rotation speed of 1,000-2,000 rpm, to obtain a dry electrode mixture powder; and (S3) applying the dry electrode mixture powder to at least one surface of a current collector,
wherein (S1) and (S2) are each carried out through a mechano-chemical reaction.
2. The method for manufacturing an electrode for a lithium secondary battery according to claim 1 , which farther comprises, after step (S3), a step of allowing the resultant product of step (S3) to pass through hot press rolls.
3. The method for manufacturing an electrode for a lithium secondary battery according to claim 1 , wherein the electrode for a lithium secondary battery is a positive electrode, and in step (S3), the dry electrode mixture powder is applied to at least one surface of the current collector in a loading amount of 25-50 mg/cm 2 .
4. The method for manufacturing an electrode for a lithium secondary battery according to claim 1 , the electrode for a lithium secondary battery is a negative electrode, and in step (S3), the dry electrode mixture powder is applied to at least one surface of the current collector in a loading amount of 12-40 mg/cm 2 .
5. The method for manufacturing an electrode for a lithium secondary battery according to claim 1 , wherein the conductive material is any one selected from the group consisting of acetylene black, carbon black, ketjen black, graphite and a mixture thereof, or a combination of two or more of them.
6. The method for manufacturing an electrode for a lithium secondary battery according to claim 1 , wherein the electrode active material is positive electrode active material particles or negative electrode active material particles.
7. The method for manufacturing an electrode for a lithium secondary battery according to claim 6 , wherein the electrode active material is positive electrode active material particles that are at least one selected from the group consisting of LiCoO 2 , LiNiO 2 , LiMn 2 O 4 , LiCoPO 4 , LiFePO 4 , LiNi 1/3 Mn 1/3 CO 1/3 O 2 and LiNi 1-x-y-z Co x M1 y M2 z O 2 (wherein each of M1 and M2 independently represents any one of Al, Ni, Co, Fe, Mn, V, Cr, Ti, W, Ta, Mg and Mo, each of x, y and z independently represents an atomic proportion of an element forming the oxide, 0≤x<0.5, 0≤y<0.5, 0≤z<0.5, and 0<x+y+z≤1).
8. The method for manufacturing an electrode for a lithium secondary battery according to claim 6 , wherein the electrode active material is negative electrode active material particles that are at least one selected from the group consisting of: carbonaceous materials; lithium-containing titanium composite oxide (LTO) and metals (Me); alloys of the metals (Me); oxides (MeOx) of the metals (Me); and composites of the metals (Me) with carbon.
9. The method for manufacturing an electrode for a lithium secondary battery according to claim 1 , wherein the binder is any one selected from the group consisting of polyvinylidene fluoride, polyvinylidene fluoride-co-hexafluoropropylene, polyvinylidene fluoride-co-trichloroethylene, polymethyl methacrylate, polyacrylonitrile, polyvinyl pyrrolidone, polyvinyl acetate, polyethylene-co-vinyl acetate, polyethylene oxide, cellulose acetate, cellulose acetate butyrate, cellulose acetate priopionate, cyanoethyl pullulan, cyanoethyl polyvinyl alcohol, cyanoethyl cellulose, cyanoethyl sucrose, pullulan and carboxymethyl cellulose, or a combination of two or more of them.
10. The method for manufacturing an electrode for a lithium secondary battery according to claim 1 , wherein the current collector comprises any one of stainless steel; aluminum; nickel; titanium; copper; stainless steel surface treated with carbon, nickel, titanium or silver; and aluminum-cadmium alloy, or a combination of two or more of them.
11. The method for manufacturing an electrode for a lithium secondary battery according to claim 8 , wherein the negative electrode active material particles are carbonaceous materials selected from the group consisting of natural graphite and artificial graphite.
12. The method for manufacturing an electrode for a lithium secondary battery according to claim 8 , wherein the negative electrode active material particles are metals (Me) selected from the group consisting of Si, Sn, Li, Zn, Mg, Cd, Ce, Ni and Fe.