Ti-containing ferritic stainless steel sheet for exhaust pipe flange member, production method, and flange member
A Ti-containing ferritic stainless steel sheet for an exhaust pipe flange member has a composition containing, in mass percentage, from 0.003 to 0.030% of C, 2.0% or less of S i, 2.0% or less of Mn, 0.050% or less of P, 0.040% or less of S, from 10.0 to 19.0% of Cr, 0.030% or less of N, from 0.07 to 0.50% of Ti, from 0.010 to 0.20% of Al, from 0 to 1.50% of Mo, and from 0 to 0.0030% of B, with the balance Fe and unavoidable impurities, has a K value of 150 or more, has a sheet surface hardness of 170 HV or less, and has a sheet thickness of from 5.0 to 11.0 mm. The K value equals −0.07×Cr−6790×Free(C+N)−1.44×d+267, wherein Free(C+N) corresponds to the solid-dissolved (C+N) concentration (% by mass), and d represents an average crystal grain diameter (μm).
1. A Ti-containing ferritic stainless steel sheet for an exhaust pipe flange member, having a chemical composition containing, in terms of percentage by mass, from 0.003 to 0.030% of C, 2.0% or less of Si, 2.0% or less of Mn, 0.050% or less of P, 0.040% or less of S, from 10.0 to 19.0% of Cr, 0.030% or less of N, from 0.07 to 0.50% of Ti, and from 0.010 to 0.20% of Al, with the balance of Fe and unavoidable impurities, having a K value defined by the following expression (1) of 150 or more, having a hardness of a sheet surface of 170 HV or less, and having a sheet thickness of from 5.0 to 11.0 mm:
K value=−0.07×Cr−6790×Free(C+N)−1.44 ×d+ 267 (1)
wherein in the expression (1), Cr represents a Cr content (% by mass) in the steel; Free(C+N) represents a value (% by mass) obtained by subtracting a total content (% by mass) of C and N present in an extraction residue recovered by an electrolytic extraction method, from a total content (% by mass) of C and N present in the steel; and d represents an average crystal grain diameter (μm) obtained for an observation surface obtained by a polished cross section (L cross section) in parallel to a rolling direction and a sheet thickness direction, by an intercept method with a linear testing line defined in Annex C of JIS G0551:2013.
2. The Ti-containing ferritic stainless steel sheet for an exhaust pipe flange member according to claim 1 , wherein the Ti-containing ferritic stainless steel sheet has the chemical composition further containing, in terms of percentage by mass, 1.50% or less of Mo.
3. The Ti-containing ferritic stainless steel sheet for an exhaust pipe flange member according to claim 1 , wherein the Ti-containing ferritic stainless steel sheet has the chemical composition further containing, in terms of percentage by mass, 0.0030% or less of B.
4. A method for producing the Ti-containing ferritic stainless steel sheet for an exhaust pipe flange member according to claim 1 , comprising:
a step of heating a slab of a steel having a chemical composition in a heating furnace, then taking out the slab at a temperature of from 950 to 1,120° C. from the furnace, rolling the slab with a roughing mill to provide an intermediate slab having a sheet thickness of from 20 to 50 mm and a surface temperature of from 700 to 850° C., then hot-rolling the intermediate slab to a thickness of from 5.0 to 11.0 mm, and then coiling at a surface temperature of from 650 to 800° C., so as to provide a hot rolled steel sheet; and
a step of annealing the hot rolled steel sheet at from 800 to 1,100° C., thereby providing a hot rolled and annealed steel sheet having a hardness of a sheet surface of 170 HV or less.
5. A flange member comprising the Ti-containing ferritic stainless steel sheet according to claim 1 .
6. The flange member according to claim 5 , wherein the flange member is an exhaust pipe flange member of an automobile.