Renewably derived polyesters and methods of making and using the same
Polyester compositions are disclosed herein, as well as methods of making and using such polyesters. In some embodiments, the polyesters are formed from monomers derived from natural oils. In some embodiments, the polyesters have lower glass transition temperatures than polyesters of comparable molecular weight.
1. A block copolymer, which comprises a first block and a second block, wherein the first block comprises a polyester polymer, which comprises constitutional units formed from a reaction mixture comprising one of more monomers of Formula (I):
wherein:
R 1 is —OH or —OR 3 ;
R 2 is C 1-6 alkyl;
R 3 is C 1-6 alkyl or C 1-6 oxyalkyl; and
X 1 is C 4-10 alkylene;
wherein the second block comprises a poly(alkylene oxide).
2. The block copolymer of claim 1 , wherein the poly(alkylene oxide) is selected from the group consisting of poly(ethylene oxide), poly(1,2-propylene oxide), and poly(1,3-propylene oxide).
3. The block copolymer of claim 1 , wherein R 1 is —OH.
4. The block copolymer of claim 1 , wherein R 1 is —OR 3 .
5. The block copolymer of claim 4 , wherein R 3 is methyl, ethyl, or isopropyl.
6. The block copolymer of claim 1 , wherein R 2 is methyl, ethyl, or n-propyl.
7. The block copolymer of claim 1 , wherein X 1 is —(CH 2 ) 5 —, —(CH 2 ) 6- , or —(CH 2 ) 7 .
8. The block copolymer of claim 1 , wherein the polyester polymer comprises constitutional units formed from at least two monomers selected from the group consisting of:
a first monomer, a second monomer, and a third monomer, wherein:
the first monomer is a compound of Formula (I) where R 2 is methyl and X 1 is —(CH 2 )7;
the second monomer is a compound of Formula (I) where R 2 is ethyl and X 1 is —(CH 2 ) 6- ; and
the third monomer is a compound of Formula (I) where R 2 is n-propyl and X 1 is —(CH 2 ) 5- .
9. The block copolymer of claim 8 , which comprises constitutional units formed from the first monomer and the second monomer.
10. The block copolymer of claim 8 , which comprises constitutional units formed from the first monomer and the third monomer.
11. The block copolymer of claim 8 , which comprises constitutional units formed from the second monomer and the third monomer.
12. The block copolymer of claim 8 , which comprises constitutional units formed from the first monomer, the second monomer, and the third monomer.
13. The block copolymer of claim 1 , wherein the polyester polymer is an AB-type polymer.
14. The block copolymer of claim 1 , wherein the reaction mixture further comprises one or more cross-linking agents.