Method of fabricating an interconnect for a fuel cell stack
Methods for fabricating an interconnect for a fuel cell stack that include providing a protective layer over at least one surface of an interconnect formed by powder pressing pre-alloyed particles containing two or more metal elements and annealing the interconnect and the protective layer at elevated temperature to bond the protective layer to the at least one surface of the interconnect.
1. A method of fabricating an interconnect for a fuel cell stack, comprising:
incorporating an interconnect comprising chromium and formed by powder metallurgy into a fuel cell stack; and
annealing the interconnect in the fuel cell stack at elevated temperature in an oxygen containing environment to oxidize both surfaces and an interior volume of the interconnect to reduce a porosity of the interconnect by forming chromium oxide within the pores of the interconnect to cause the pores to fill with the chromium oxide, and to flow and set seals in the fuel cell stack during the annealing.
2. A method of fabricating an interconnect for a fuel cell stack, comprising:
providing a powder mixture comprising chromium, manganese and cobalt in a die cavity of a powder press apparatus;
compressing the powder mixture in the powder press apparatus to form a pressed powder interconnect; and
oxidizing the pressed powder interconnect in an oxygen-containing environment at an elevated temperature to oxidize the manganese and cobalt and form a metal oxide protective layer comprising manganese cobalt oxide over at least one surface of the pressed powder interconnect.
3. The method of claim 2 , wherein the powder mixture further comprises iron.
4. The method of claim 2 , wherein the powder mixture comprises 0-1 wt % iron, and a wt % of cobalt in the powder mixture is selected to provide an interconnect having a coefficient of thermal expansion (CTE) that is within about 1% of the CTE of a solid oxide fuel cell electrolyte.
5. The method of claim 2 , wherein the powder mixture comprises pre-alloyed particles containing chromium, manganese and cobalt.
6. The method of claim 2 , wherein the powder mixture comprises pre-alloyed particles containing chromium, iron, manganese and cobalt.
7. The method of claim 2 , wherein the powder mixture comprises elemental chromium particles and pre-alloyed particles containing manganese and cobalt.
8. The method of claim 2 , wherein the powder mixture comprises a first set of pre-alloyed particles containing chromium and iron and a second set of pre-alloyed particles containing manganese and cobalt.
9. The method of claim 2 , wherein the powder mixture comprises chromium, manganese and cobalt elemental particles; and
wherein the powder mixture further comprises iron elemental particles.
10. The method of claim 2 , wherein the powder mixture has a variable composition within the die cavity such that the compressed powder interconnect is formed having a relatively higher concentration of manganese and cobalt proximate to the at least one outer surface of the interconnect than within an interior portion of the interconnect.