IP Library Granted Patent US 12,504,227
Granted Patent B2
US 12,504,227 · App. 16/113,215 · Granted Dec 23, 2025

System and method for natural gas liquid production with flexible ethane recovery or rejection

Inventor: Rayburn C. Butts (Midland, TX)
Assignee: BCCK Holding Company
F25J3/0295F25J3/0209F25J3/0238F25J3/0242F25J2200/02F25J2200/92F25J2200/94F25J2210/60F25J2215/62F25J2215/64F25J2280/02
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Quick Facts
Patent No.
US 12,504,227
App. No.
16/113,215
Granted
Dec 23, 2025
Kind
B2
Abstract

A system and method for processing an NGL product stream from a natural gas feed stream in either an ethane retention or ethane rejection mode utilizing heat exchange of particular process streams. In ethane rejection mode, there are preferably two stages of heat exchange between the feed stream and a first separator bottoms stream and a side stream withdrawn from a fractionation tower is cooled through heat exchange with both the fractionation tower and second separator overhead streams, and optionally with an external refrigerant, resulting in 5-15% ethane and at least 97% propane recovery. In ethane retention mode, a portion of the feed stream and portions of a first separator overhead and bottoms streams are preferably separately cooled through heat exchange with other process streams, including the entireties of a recycled residue gas and fractionation column overhead streams, resulting in around 99% ethane and around 100% propane recovery.

Claims (61)

1 . A method for processing a feed stream comprising methane, ethane, propane, and other components using a single fractionation column in an ethane retention mode to produce an NGL product stream and a residue gas stream, the method comprising:

splitting the feed stream into two portions, a first portion having 40% to 75% of a molar flow rate of the feed stream and a second portion having a balance of the molar flow rate of the feed stream;

combining the first portion of the feed stream and the second portion of the feed stream to form a combined feed stream;

separating the combined feed stream in a first separator into a first overhead stream and a first bottoms stream;

splitting the first overhead stream into a first portion and a second portion;

splitting the first bottoms stream into a first portion and a second portion;

separating the first portion of the first overhead stream, the second portion of the first overhead stream, the first portion of the first bottoms stream, the second portion of the first bottoms stream, and a recycled stream in the single fractionation column into a second overhead stream, a side stream, and a second bottoms stream;

exchanging heat in a first heat exchanger by simultaneously passing each of the first portion of the feed stream, the recycled stream, an entirety of the second overhead stream, and the side stream through the first heat exchanger;

exchanging heat in a second heat exchanger by simultaneously passing each of the entirety of the second overhead stream, the recycled stream, the first portion of the first bottoms stream, and the first portion of the first overhead stream through the second heat exchanger;

cooling the second portion of the feed stream in a tube side of a reboiler of the single fractionation column, prior to the combining the second portion of the feed stream with the first portion of the feed stream, by heat exchange with the second bottoms stream; and

reboiling the second bottoms stream on a shell side of the reboiler of the single fractionation column to produce a vapor stream and the NGL product stream;

compressing the entirety of the second overhead stream after passing through the first heat exchanger;

wherein in the first heat exchanger: (1) the first portion of the feed stream is cooled prior to the combining with the second portion of the feed stream, (2) the recycled stream is cooled prior to passing through the second heat exchanger, (3) the entirety of the second overhead stream is warmed after passing through the second heat exchanger, and (4) the side stream withdrawn from the single fractionation column is warmed prior to returning to the single fractionation column;

wherein in the second heat exchanger: (1) the entirety of the second overhead stream is warmed prior to passing through the first heat exchanger, (2) the recycled stream is cooled after passing through the first heat exchanger and prior to the single fractionation column, (3) the first portion of the first bottoms stream is cooled prior to the single fractionation column, and (4) the first portion of the first overhead stream is cooled prior to the single fractionation column;

wherein the residue gas stream comprises the second overhead stream after the compressing;

wherein the side stream is the only side stream withdrawn from the single fractionation column for heat exchange with any portion of the feed stream, and the side stream exchanges heat with the first portion of the feed stream in the first heat exchanger and the side stream does not exchange heat with the second portion of the feed stream;

wherein no portion of the first bottoms stream exchanges heat with the first portion of the feed stream; and

wherein no portion of the first bottoms stream exchanges heat with the second portion of the feed stream;

wherein the recycled stream is a portion of the residue gas stream;

wherein the NGL product stream comprises greater than 98% of the ethane from the feed stream; and

wherein the other components comprise 0.14% or less CO 2 .

2 . The method of claim 1 further comprising combining the first portion of the first bottoms stream and the first portion of the first overhead stream prior to passing the first portion of the first bottoms stream and the first portion of the first overhead stream to the second heat exchanger;

wherein the NGL product stream comprises 99% to less than 100% of the ethane from the feed stream.

3 . The method of claim 2 further comprising after cooling the second portion of the feed stream in the tube side of the reboiler, supplying external refrigerant to a third heat exchanger to cool in the third heat exchanger the second portion of the feed stream prior to combining the second portion of the feed stream with the first portion of the feed stream.

4 . The method of claim 1 wherein there is no heat exchange between only the second overhead stream and the recycled stream.

5 . The method of claim 4 wherein the NGL product stream comprises at least 98.64% but less than 100% of the ethane from the feed stream.

6 . The method of claim 4 wherein the feed stream comprises 15% ethane and the NGL product stream comprises at least 99% but less than 100% of the ethane from the feed stream.

7 . The method of claim 1 wherein the first heat exchanger consists of a single heat exchanger for heat exchange between the first portion of the feed stream, the recycled stream, the entirety of the second overhead stream, and the side stream passing through the first heat exchanger.

8 . The method of claim 7 wherein the second heat exchanger consists of a single heat exchanger for heat exchange between the entirety of the second overhead stream, the recycled stream, the first portion of the first bottoms stream, and the first portion of the first overhead stream passing through the second heat exchanger.

9 . The method of claim 8 further comprising combining the first portion of the first bottoms stream and the first portion of the first overhead stream prior to the passing the first portion of the first bottoms stream and the first portion of the first overhead stream to the second heat exchanger; and

wherein no external refrigerant is supplied to the first heat exchanger.

10 . The method of claim 1 wherein the other components in the feed stream comprise nitrogen and wherein the NGL product stream comprises 98.64% to 99% of the ethane from the feed stream.

11 . A method for processing a feed stream comprising methane, ethane, propane, and other components using a single fractionation column in an ethane retention mode to produce an NGL product stream and a residue gas stream, the method comprising:

splitting the feed stream into two portions, a first portion and a second portion, wherein the second portion has 25% to 65% of a molar flow rate of the feed stream;

combining the first portion of the feed stream and the second portion of the feed stream to form a combined feed stream;

separating the combined feed stream in a first separator into a first overhead stream and a first bottoms stream;

splitting the first overhead stream into a first portion and a second portion;

splitting the first bottoms stream into a first portion and a second portion;

separating the first portion of the first overhead stream, the second portion of the first overhead stream, the first portion of the first bottoms stream, the second portion of the first bottoms stream, and a recycled stream in the single fractionation column into a second overhead stream and a second bottoms stream;

exchanging heat in a first heat exchanger by simultaneously passing each of a first set of streams through the first heat exchanger;

exchanging heat in a second heat exchanger by simultaneously passing each of a second set of streams through the second heat exchanger;

cooling the second portion of the feed stream in a tube side of a reboiler of the single fractionation column, prior to the combining the second portion of the feed stream with the first portion of the feed stream, by heat exchange with the second bottoms stream; and

reboiling the second bottoms stream on a shell side of the reboiler of the single fractionation column to produce a vapor stream and the NGL product stream;

compressing an entirety of the second overhead stream after passing through the first heat exchanger;

wherein in the first set of streams in the first heat exchanger consists of: (1) the first portion of the feed stream, which is cooled prior to the combining with the second portion of the feed stream, (2) the recycled stream, which is cooled prior to passing through the second heat exchanger, (3) the entirety of the second overhead stream, which is warmed after passing through the second heat exchanger, and (4) a single side stream withdrawn from the single fractionation column, which is warmed prior to returning to the single fractionation column;

wherein in the second set of streams in the second heat exchanger consists of: (1) the entirety of the second overhead stream, which is warmed prior to passing through the first heat exchanger, (2) the recycled stream, which is cooled after passing through the first heat exchanger and prior to the single fractionation column, (3) the first portion of the first bottoms stream, which is cooled prior to the single fractionation column, and (4) the first portion of the first overhead stream, which is cooled prior to the single fractionation column;

wherein the residue gas stream comprises the second overhead stream after the compressing;

wherein no portion of the first bottoms stream exchanges heat with the first portion of the feed stream; and

wherein no portion of the first bottoms stream exchanges heat with the second portion of the feed stream;

wherein the recycled stream is a portion of the residue gas stream;

wherein greater than 98% of the ethane from the feed stream is in the NGL product stream; and

wherein the other components comprise 0.14% or less CO 2 .

12 . The method of claim 11 wherein 99% or more of the ethane from the feed stream is in the NGL product stream.

13 . The method of claim 1 wherein the NGL product stream comprises at least 99% of the ethane from the feed stream.

14 . The method of claim 1 wherein no portion of the NGL product stream exchanges heat with any portion of the feed stream.

15 . The method of claim 2 wherein no portion of the NGL product stream exchanges heat with any portion of the feed stream.

16 . The method of claim 11 wherein no portion of the NGL product stream exchanges heat with any portion of the feed stream.

17 . The method of claim 2 wherein no portion of the NGL product stream passes through the first heat exchanger;

wherein no portion of the NGL product stream passes through the second heat exchanger.

18 . The method of claim 11 wherein no portion of the NGL product stream passes through the first heat exchanger;

wherein no portion of the NGL product stream passes through the second heat exchanger.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 16, 2020
From: BUTTS PROPERTIES, LTD.
To: BCCK HOLDING COMPANY
Reel/Frame 052947/0807 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 21, 2018
From: BUTTS, RAYBURN C.
To: BUTTS PROPERTIES, LTD.
Reel/Frame 046941/0019 →
Continuity (1)
Related Publication 20200064064A1 · Feb 27, 2020
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