IP Library Granted Patent US 11,268,179
Granted Patent B2
US 11,268,179 · App. 16/114,405 · Granted Mar 8, 2022

Creep resistant titanium alloys

Inventors: John V. Mantione (Indian Trail, NC); David J. Bryan (Indian Trail, NC); Matias Garcia-Avila (Matthews, NC)
Assignee: ATI PROPERTIES LLC
C22F1/183C22C14/00
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Quick Facts
Patent No.
US 11,268,179
App. No.
16/114,405
Granted
Mar 8, 2022
Kind
B2
Abstract

A non-limiting embodiment of a titanium alloy comprises, in weight percentages based on total alloy weight: 5.5 to 6.5 aluminum; 1.5 to 2.5 tin; 1.3 to 2.3 molybdenum; 0.1 to 10.0 zirconium; 0.01 to 0.30 silicon; 0.1 to 2.0 germanium; titanium; and impurities. A non-limiting embodiment of the titanium alloy comprises a zirconium-silicon-germanium intermetallic precipitate, and exhibits a steady-state creep rate less than 8×10 −4 (24 hrs) −1 at a temperature of at least 890° F. under a load of 52 ksi.

Claims (96)

1. A titanium alloy comprising, in weight percentages based on total alloy weight:

5.5 to 6.5 aluminum;

1.5 to 2.5 tin;

1.3 to 2.3 molybdenum;

0.1 to 10.0 zirconium;

0.01 to 0.30 silicon;

0.1 to 2.0 germanium;

titanium; and

impurities;

wherein the titanium alloy comprises an intermetallic precipitate comprising zirconium, silicon, and germanium.

2. The titanium alloy of claim 1 comprising, in weight percentages based on total alloy weight:

5.5 to 6.5 aluminum;

1.7 to 2.1 tin;

1.7 to 2.1 molybdenum;

3.4 to 4.4 zirconium;

0.03 to 0.11 silicon;

0.1 to 0.4 germanium;

titanium; and

impurities.

3. The titanium alloy of claim 1 comprising, in weight percentages based on total alloy weight:

5.9 to 6.0 aluminum;

1.9 to 2.0 tin;

1.8 to 1.9 molybdenum;

3.5 to 4.3 zirconium;

0.06 to 0.11 silicon;

0.1 to 0.4 germanium;

titanium; and

impurities.

4. The titanium alloy of claim 1 further comprising, in weight percentages based on total alloy weight:

0 to 0.15 oxygen;

0 to 0.30 iron;

0 to 0.05 nitrogen;

0 to 0.05 carbon;

0 to 0.015 hydrogen; and

0 to 0.1 each of niobium, tungsten, hafnium, nickel, gallium, antimony, vanadium, tantalum, manganese, cobalt, and copper.

5. The titanium alloy of claim 1 , wherein the titanium alloy exhibits a steady-state creep rate less than 7.97×10 −4 (24 hrs) −1 at a temperature of at least 475° C. under a load of 52 ksi.

6. The titanium alloy of claim 1 , wherein the titanium alloy exhibits an ultimate tensile strength of at least 130 ksi at 482° C.

7. A titanium alloy consisting essentially of, in weight percentages based on total alloy weight:

5.5 to 6.5 aluminum;

1.5 to 2.5 tin;

1.3 to 2.3 molybdenum;

0.1 to 10.0 zirconium;

0.01 to 0.30 silicon;

0.1 to 2.0 germanium;

0 to 0.15 oxygen;

0 to 0.30 iron;

0 to 0.05 nitrogen;

0 to 0.05 carbon;

0 to 0.015 hydrogen;

0 to 0.1 of each of niobium, tungsten; hafnium, nickel, gallium, antimony, vanadium, tantalum, manganese, cobalt; and copper;

titanium; and

impurities,

wherein the titanium alloy comprises an intermetallic precipitate comprising zirconium, silicon, and germanium.

8. The titanium alloy of claim 7 , wherein an aluminum content in the alloy is, in weight percentages based on total alloy weight, 5.9 to 6.0.

9. The titanium alloy of claim 7 , wherein a tin content in the alloy is, in weight percentages based on total alloy weight, 1.7 to 2.1.

10. The titanium ahoy of claim 7 ; wherein a tin content in the alloy is, in weight percentages based on total alloy weight, 1.9 to 2.0.

11. The titanium alloy of claim 7 , wherein a molybdenum content in the alloy is, in weight percentages based on total alloy weight, 1.7 to 2.1.

12. The titanium alloy of claim 7 , wherein a molybdenum content in the alloy is, in weight percentages based on total alloy weight, 1.8 to 1.9.

13. The titanium alloy of claim 7 , wherein a zirconium content in the alloy is, in weight percentages based on total alloy weight, 3.4 to 4.4.

14. The titanium alloy of claim 7 , wherein a zirconium content in the alloy is, in weight percentages based on total alloy weight, 3.5 to 4.3.

15. The titanium alloy of claim 7 , wherein a silicon content in the alloy is, in weight percentages based on total alloy weight, 0.03 to 0.11.

16. The titanium alloy of claim 7 , wherein a silicon content in the alloy is, in weight percentages based on total alloy weight, 0.06 to 0.11.

17. The titanium alloy of claim 7 , wherein a germanium content n the alloy is, in weight percentages based on total alloy weight, 0.1 to 0.4.

18. The titanium alloy of claim 7 ; wherein in the titanium alloy;

an oxygen content is 0 to 0.15;

an iron content is 0 to 0.30;

a nitrogen content is 0 to 0.05;

a carbon content is 0 to 0.05;

a hydrogen content is 0 to 0.015; and

a content of each of niobium, tungsten, hafnium, nickel, gallium, antimony, vanadium, tantalum, manganese, cobalt, and copper is 0 to 0.1,

all in weight percentages based on total weight of the titanium alloy.

19. The titanium alloy of claim 7 , wherein the titanium alloy exhibits a steady-state creep rate less than 7.97×10 −4 (24 hrs) −1 at a temperature of at least 475° C. under a load of 52 ksi.

20. The titanium alloy of claim 7 , wherein the titanium alloy exhibits an ultimate tensile strength of at least 130 ksi at 482° C.

21. A titanium alloy comprising, in weight percentages based on total alloy weight:

2 to 7 aluminum;

0 to 5 tin;

0 to 5 molybdenum;

0.1 to 10.0 zirconium;

0.01 to 0.30 silicon;

0.05 to 2.0 germanium;

0 to 0.30 oxygen;

0 to 0.30 iron;

0 to 0.05 nitrogen;

0 to 0.05 carbon;

0 to 0.015 hydrogen;

titanium; and

impurities;

wherein the titanium ahoy comprises an intermetallic precipitate comprising zirconium, silicon, and germanium.

22. The titanium alloy of claim 21 , wherein the titanium alloy exhibits a steady-state creep rate less than 8×10 −4 (24 hrs) −1 at a temperature of at least 890° F. under a load of 52 ksi.

23. The titanium alloy of claim 21 further comprising, in weight percentages based on total alloy weight:

0 to 5 chromium.

24. The titanium alloy of claim 21 further comprising, in weight percentages based on total alloy weight:

0 to 6.0 each of niobium, tungsten, vanadium, tantalum, manganese, nickel, hafnium, gallium, antimony, cobalt, and copper.

25. The titanium alloy of claim 24 , wherein the titanium alloy exhibits a steady-state creep rate less than 8×10 −4 (24 hrs) −1 at a temperature of at least 890° F. under a load of 52 ksi.

26. The titanium alloy of claim 24 further comprising, in weight percentages based on total alloy weight:

0 to 5 chromium.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 31, 2018
From: MANTIONE, JOHN V.; BRYAN, DAVID J.; GARCIA-AVILA, MATIAS
To: ATI PROPERTIES LLC
Reel/Frame 046769/0795 →
Continuity (1)
Related Publication 20200071806A1 · Mar 5, 2020
Cited By (3)
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