3D printing support structures incorporating sacrificial materials
The present teachings according to various embodiments provides a support material for 3D printing. The support material includes poly(alkylene carbonate) having a decomposition temperature of from 100 ° C. to about 300 ° C.
1. A support material for 3 D printing, the support material comprising:
poly(alkylene carbonate) core/shell particles having a size of from 3 to 250 microns;
wherein the core comprises an inert material of from 5 weight percent to about 50 weight percent of the support material; and
wherein the poly(alkylene carbonate), has a decomposition temperature of from 100° C. to about 300° C.
2. The support material according to claim 1 , wherein the poly(alkylene carbonate) is selected from the group consisting of: poly(propylene carbonate), poly(ethylene carbonate), poly(butylene carbonate) and poly(cyclohexene carbonate), poly(norbornene carbonate), and poly(cyclohexene propylene carbonate).
3. The support according to claim 1 , wherein the poly(alkylene carbonate) has a molecular weight (Mw) ranging from about 10,000 to about 500,000.
4. The support material according to claim 1 , wherein the inert material is selected from the group consisting of: silica, titania, alumina, carbon, glass, metal, cellulose, and a synthetic polymer.
5. The support material according to claim 1 , further comprising an additive selected from a group consisting of: a cyclodextrin, an organic acid, a photo acid generator, a photo base generator, a thermal acid generator, and a thermal base generator.
6. The support material according to claim 5 , wherein the concentration of the additive is about 0.1 to about 5 weight percent based on the weight of the poly(alkylene carbonate).
7. The support material according to claim 5 , wherein the organic acid comprises a carboxylic acid containing from about 5 to about 30 carbon atoms.
8. The support material according to claim 5 , wherein the photo acid generator or the thermal acid generator comprises a diphenyliodonium salt, a benzyl sulfonate ester, an imino sulfonate ester, and a spiropyran-based sulfonic acid.
9. The support material according to claim 5 , wherein the photo base generator comprises 2-(9-oxoxanthen-2-yl)propionic Acid 1,5,7-Triazabicyclo[4.4.0]dec-5-ene salt or 1,5,7 e triaza-bicyclo [4.4.0]dec-5-ene tetraphenylborate.