Poly(amide-imide) copolymer, composition for preparing poly(amide-imide) copolymer, article including poly(amide-imide) copolymer, and display device including the article
A poly(amide-imide) copolymer that is a reaction product of a substituted or unsubstituted linear aliphatic diamine including two terminals, a diamine represented by Chemical Formula 1, a dicarbonyl compound represented by Chemical Formula 2, and a tetracarboxylic acid dianhydride represented by Chemical Formula 3: wherein, in Chemical Formulae 1 to 3, A, R 3 , R 10 , R 12 , R 13 , X, n7 and n8 are the same as defined in the specification.
1. A poly(amide-imide) copolymer that is a reaction product of a substituted or unsubstituted linear aliphatic diamine comprising two terminals, a diamine represented by Chemical Formula 1, a dicarbonyl compound represented by Chemical Formula 2, and a tetracarboxylic acid dianhydride mixture comprising a tetracarboxylic acid dianhydride represented by Chemical Formula 3-1 and a tetracarboxylic acid dianhydride represented by Chemical Formula 3-2:
NH 2 -A-NH 2 Chemical Formula 1
wherein in Chemical Formula 1,
A is a ring system comprising two or more C6 to C30 aromatic rings linked by a single bond, wherein each of the two or more aromatic rings is independently unsubstituted or substituted by an electron-withdrawing group;
wherein, in Chemical Formula 2,
R 3 is a substituted or unsubstituted phenylene or a substituted or unsubstituted biphenylene group, and
each X is an identical or different halogen atom;
wherein the linear aliphatic diamine is present in an amount of greater than 20 mol % and less than 90 mol %, and the diamine represented by Chemical Formula 1 is present in an amount of less than or equal to 80 mol % and greater than or equal to 10 mol %, based on the amount of total diamine.
2. The poly(amide-imide) copolymer according to claim 1 , wherein the two terminals of the substituted or unsubstituted linear aliphatic diamine are each an amino group, and the substituted or unsubstituted linear aliphatic diamine is a substituted or unsubstituted C1 to C30 saturated or unsaturated linear aliphatic diamine.
3. The poly(amide-imide) copolymer according to claim 2 , wherein the substituted or unsubstituted linear aliphatic diamine is a substituted or unsubstituted C1 to C20 saturated linear aliphatic diamine.
4. The poly(amide-imide) copolymer according to claim 1 , wherein the substituted or unsubstituted linear aliphatic diamine is selected from methylene diamine, ethylene diamine, 1,3-propane diamine, 1,4-tetramethylene diamine, 1,5-pentamethylene diamine, 1,6-hexamethylene diamine, 1,7-heptamethylene diamine, 1,8-octamethylene diamine, 9-nonamethylene diamine, 1,10-decamethylene diamine, 1,11-undecamethylene diamine, 1,12-dodecamethylene diamine, and a combination thereof.
5. The poly(amide-imide) copolymer according to claim 1 , wherein the diamine represented by Chemical Formula 1 comprises a ring system comprising two C6 to C12 aromatic rings linked by a single bond, wherein each of the two C6 to C12 aromatic rings are independently substituted by an electron-withdrawing group selected from a halogen atom, a nitro group, a cyano group, a C1 or C2 haloalkyl group, a C2 to C6 alkanoyl group, and a C2 to C6 ester group.
6. The poly(amide-imide) copolymer according to claim 1 , wherein the diamine represented by Chemical Formula 1 comprises at least one selected from the diamines represented by chemical formulae:
7. The poly(amide-imide) copolymer according to claim 1 , wherein the diamine represented by Chemical Formula 1 comprises a diamine represented by Chemical Formula A:
8. The poly(amide-imide) copolymer according to claim 1 , wherein in Chemical Formula 2, R 3 is a phenylene group, and each X is independently Cl or Br.
9. The poly(amide-imide) copolymer according to claim 1 , wherein the mixture of tetracarboxylic acid dianhydride is a combination of 3,3′,4,4′-biphenyl tetracarboxylic dianhydride and 4,4′-(hexafluoroisopropylidene)diphthalic anhydride.
10. The poly(amide-imide) copolymer according to claim 1 , wherein the linear aliphatic diamine is greater than or equal to 30 mole percent and less than 90 mol %, and the diamine represented by Chemical Formula 1 is present in an amount of less than 70 mol % and greater than or equal to 10 mol %, based on the total amount of the linear aliphatic diamine and the diamine represented by Chemical Formula 1.
11. The poly(amide-imide) copolymer according to claim 1 , wherein a mole ratio of the dicarbonyl compound represented by Chemical Formula 2 and the tetracarboxylic acid dianhydride represented by Chemical Formula 3-1 and a tetracarboxylic acid dianhydride represented by Chemical Formula 3-2 is 20:80 to 30:70.