Non-scaling wet air oxidation process
View Patent ↗There is provided a system and a method for regenerating a material that reduce the incidence of scaling due to scale forming contaminants. The method may include reducing a temperature of a treated material exiting a wet air oxidation unit in a scale reducing heat exchanger prior to delivery of the treated material to a second heat exchanger which heats a source waste material comprising a scale forming contaminant therein with heat from the first treated material to form a heated waste material comprising the scale forming contaminant.
1. A treatment process comprising:
reducing a temperature of a regenerated carbon material exiting a wet air oxidation unit in a first heat exchanger;
delivering the reduced temperature regenerated carbon material from the first heat exchanger to a second heat exchanger, wherein the second heat exchanger heats a spent carbon material comprising spent carbon and a scale forming contaminant with heat from the regenerated carbon material to generate a heated spent carbon material; and
delivering the heated spent material to the wet air oxidation unit for regeneration of the heated spent carbon material;
wherein the temperature is reduced to a temperature less than a solubility temperature limit of the scale forming contaminant at a given concentration of the scale forming contaminant.
2. The process of claim 1 , wherein the temperature is reduced to a temperature of about 100° C. to about 185° C.
3. The process of claim 1 , wherein the regenerated carbon material further comprises an oxygen depleted gas mixture, wherein the oxygen depleted gas mixture is also utilized to heat the spent carbon material.
4. The process of claim 1 , wherein the scale forming contaminant comprises a member selected from the group consisting of aluminum, calcium, carbonate, iron, magnesium, phosphorus, sulfate, and combinations thereof.
5. The process of claim 1 , wherein the scale forming contaminant comprises calcium sulfate.
6. The process of claim 1 , further comprising:
additionally reducing a temperature of a material exiting the second heat exchanger with a third heat exchanger.
7. The process of claim 1 , wherein the reducing is done via regulating a fluid flowing through the first heat exchanger via a fluid flow controller.
8. A treatment process comprising:
reducing a temperature of a regenerated material exiting a wet air oxidation unit in a first heat exchanger;
delivering the reduced temperature regenerated material from the first heat exchanger to a second heat exchanger, wherein the second heat exchanger heats a regenerable material comprising a scale forming contaminant therein with heat from the regenerated material to generate a heated regenerable material; and
delivering the heated regenerable material to the wet air oxidation unit for regeneration of the heated regenerable material;
wherein the temperature is reduced to a temperature less than a solubility temperature limit of the scale forming contaminant at a given concentration of the scale forming contaminant.