IP Library Granted Patent US 11,450,448
Granted Patent B2
US 11,450,448 · App. 16/139,904 · Granted Sep 20, 2022

Use of a linear octafluorobutene as a dielectric compound in an environmentally safe dielectric-insulation or arc-extinction fluid

Inventors: Charles Doiron (Basel, CH); Thomas Alfred Paul (Wädenswil, CH); Branimir Radisavljevic (Zürich, CH); Nitesh Ranjan (Niederrohrdorf, CH); Anna Di-Gianni (Dättwil, CH); Saskia Scheel (Lenzburg, CH)
Assignee: HITACHI ENERGY SWITZERLAND AG
H01B3/24H01B3/421H01B3/427H01B3/46H01B3/56H01H33/22C07C19/08
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Quick Facts
Patent No.
US 11,450,448
App. No.
16/139,904
Granted
Sep 20, 2022
Kind
B2
Abstract

The present invention relates to the use of a linear octafluorobutene as a dielectric compound in an environmentally safe dielectric-insulation or arc-extinction fluid for an apparatus for the generation, the transmission, the distribution and/or the usage of electrical energy.

Claims (34)

1. A combination, comprising:

a linear octafluorobutene utilized as a dielectric compound in an environmentally safe dielectric-insulation or arc-extinction fluid for an apparatus for the generation, the transmission, the distribution and/or the usage of electrical energy, wherein the proportion of the linear octafluorobutene dielectric compound in the dielectric-insulation or arc-extinction fluid is in a range from about 3% to less than 1%,

wherein the dielectric-insulation or arc-extinction fluid is free of SF 6 , and

wherein the second component B comprises a carrier gas that comprises one of oxygen, nitrous oxide, a mixture of oxygen and carbon dioxide, a mixture of nitrogen and oxygen and a mixture of nitrous oxide and oxygen.

2. The combination according to claim 1 , wherein the dielectric-insulation or arc-extinction fluid is non-ozone depleting and has a Global Warming Potential over a time horizon of 100 years of less than 10.

3. The combination according to claim 1 , wherein the dielectric-insulation of arc-extinction fluid is inert towards the material of the apparatus, with which the fluid gets into direct contact during its use in the apparatus.

4. The combination according to claim 1 , wherein the median lethal dose (LC50; lethal concentration 50%; measured on rats) of the dielectric compound is higher than 4′000 ppm.

5. The combination according to claim 1 , wherein a second component of the dielectric-insulation or arc-extinction fluid comprises a carrier gas selected from the group consisting of: oxygen, nitrous oxide, and mixtures thereof.

6. The combination according to claim 5 , wherein the second component of the dielectric-insulation or arc-extinction fluid further comprises a carrier gas comprising nitrogen, carbon dioxide, and mixtures thereof.

7. A dielectric-insulation or arc-extinction fluid for an apparatus for the generation, the transmission, the distribution and/or the usage of electrical energy, the fluid comprising:

a) a linear octafluorobutene as a first component A in mixture with

b) a second component B different from the first component A, the proportion of the first component A in the dielectric insulation of arc-extinction fluid being in a range from about 3% to less than 10%,

wherein the dielectric-insulation or arc-extinction fluid is free of SF 6 , and

wherein the second component B comprises a carrier gas that comprises one of oxygen, nitrous oxide, a mixture of oxygen and carbon dioxide, a mixture of nitrogen and oxygen and a mixture of nitrous oxide and oxygen.

8. The dielectric-insulation or arc-extinction fluid according to claim 7 , wherein the dew point is less than a minimum operating temperature corresponding to an indoor use of the apparatus.

9. The dielectric-insulation or arc-extinction fluid according to claim 7 , having a dew point of lower than −20° C., wherein the partial pressure of component A as measured at 293.15 K is higher than 250 mbar; or

having a dew point of lower than −25° C., wherein the partial pressure of component A as measured at 293.15 K is higher than 150 mbar.

10. The dielectric-insulation or arc-extinction fluid according to claim 7 , having a dew point of lower than 0° C., wherein the partial pressure of component A as measured at 293.15 K is higher than 900 mbar; or

having a dew point of lower than −5° C., wherein the partial pressure of component A as measured at 293.15 K is higher than 750 mbar.

11. The dielectric-insulation or arc-extinction fluid according to claim 7 , the total pressure of which being at least 6 bar as measured at 293.15 K.

12. The dielectric-insulation or arc-extinction fluid according to claim 7 , being non-ozone depleting and having a Global Warming Potential over a time horizon of 100 years of less than 10.

13. The dielectric-insulation or arc-extinction fluid according to claim 7 , wherein the first component A is octafluorobut-1-ene or octafluorobut-2-ene.

14. The dielectric-insulation or arc-extinction fluid according to claim 7 , wherein the second component B comprises a carrier gas, which has a boiling point of −60° C. at most.

15. The dielectric-insulation or arc-extinction fluid according to claim 7 , wherein the second component B comprises a carrier gas, which itself has a lower dielectric strength than the first component A.

16. The dielectric-insulation or arc-extinction fluid according to claim 7 , wherein the second fluid component B comprises a carrier gas selected from the group consisting of: oxygen, nitrogen, carbon dioxide, nitrous oxide, and mixtures thereof.

17. The dielectric-insulation or arc-extinction fluid according to claim 7 , wherein the second fluid component B comprises carbon dioxide and/or nitrogen.

18. The dielectric-insulation or arc-extinction fluid according to claim 17 , wherein the second fluid component B further comprises oxygen.

19. The dielectric-insulation or arc-extinction fluid according to claim 7 , wherein the second fluid component B comprises a mixture of carbon dioxide and oxygen or of a mixture of nitrogen and oxygen or of a mixture of carbon dioxide and oxygen and nitrogen.

20. The dielectric-insulation or arc-extinction fluid according to claim 7 , wherein it comprises as the second fluid component B or as a third fluid component C a further fluorinated organic compound different from the linear octafluorobutene of the first gas component A.

21. The dielectric-insulation or arc-extinction fluid according to claim 20 , wherein the further fluorinated organic compound is at least one compound selected from the group consisting of: fluoroethers, fluoroketones, fluoroolefins other than a linear octafluorobutene, fluoronitriles, and mixtures thereof.

22. The dielectric-insulation or arc-extinction fluid according to claim 7 , wherein the partial pressure of component A, as measured at 293.15 K is chosen in a range of 800 mbar to 1100 mbar; or

in a range of 750 mbar to 950 mbar; or

in a range of 250 mbar to 520 mbar; or in a range of 150 mbar to 420 mbar.

23. The dielectric-insulation or arc-extinction fluid according to claim 7 , wherein the carrier gas further comprises at least one of nitrogen, carbon dioxide, and mixtures thereof.

Assignments (4)
MERGER Recorded Nov 13, 2023
From: HITACHI ENERGY SWITZERLAND AG
To: HITACHI ENERGY LTD
Reel/Frame 065549/0576 →
CHANGE OF NAME Recorded Dec 31, 2021
From: ABB POWER GRIDS SWITZERLAND AG
To: HITACHI ENERGY SWITZERLAND AG
Reel/Frame 058601/0692 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 15, 2021
From: ABB SCHWEIZ AG
To: ABB POWER GRIDS SWITZERLAND AG
Reel/Frame 055589/0769 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 14, 2020
From: DOIRON, CHARLES; PAUL, THOMAS ALFRED; RADISAVLJEVIC, BRANIMIR; RANJAN, NITESH; DI-GIANNI, ANNA; SCHEEL, SASKIA
To: AB SCHWEIZ AG
Reel/Frame 052934/0183 →
Priority Claims (1)
WO PCT/EP2016/056390 · Mar 23, 2016 · international
Continuity (2)
Continuation PCTEP2017056538 · Mar 20, 2017
Related Publication 20190027268A1 · Jan 24, 2019
Cited By (1)
US 12,456,851