Methane oxidation catalyst, process to prepare the same and method of using the same
The present invention provides a method of treating an exhaust gas comprising methane and NO. The exhaust gas is contacted with a catalyst in the presence of oxygen to oxidize at least part of the methane in the gas stream to carbon dioxide and water and at least part of the NO into NO 2 obtaining a treated gas stream. The catalyst comprises one or more noble metals supported on non-modified zirconia, wherein the zirconia comprises tetragonal zirconia and monoclinic zirconia, and wherein the weight ratio of tetragonal zirconia to monoclinic zirconia is in the range of from 1:1 to 31:1.
1. A method of treating an exhaust gas comprising methane and NO by contacting said exhaust gas with a catalyst in the presence of oxygen and oxidizing at least part of the methane in the gas stream to carbon dioxide and water and at least part of the NO into NO 2 obtaining a treated gas stream;
wherein the catalyst comprises one or more noble metals supported on non-modified zirconia, wherein the zirconia comprises tetragonal zirconia and monoclinic zirconia, and wherein the weight ratio of tetragonal zirconia to monoclinic zirconia is in the range of from 1:1 to 31:1.
2. A method according to claim 1 wherein the treated gas stream obtained in claim 1 is contacted with an SCR (selective catalytic reduction) catalyst to reduce NO and/or NO 2 to N 2 .
3. A method according to claim 2 , wherein the stream comprising methane is an exhaust gas from a natural gas-fueled engine.
4. A method according to claim 2 wherein the SCR catalyst comprising titanium(IV)oxide (TiO 2 ), tungsten(VI)oxide (WO 3 ), vanadium(V)oxide (V 2 O 5 ), molybdenum(VI) oxide, noble metals, transition metal-exchanged zeolite or a zeolite.
5. A method according to claim 2 wherein the exhaust gas comprises less than 5000 ppmv of methane, based on the volume of the total gas stream.
6. A method according to claim 2 wherein the T 50 (CH 4 ) of the methane oxidation catalyst may be equal to or less than 405° C.