Method for producing sintered R-T-B based magnet and diffusion source
A method for producing a sintered R-T-B based magnet includes the steps of: providing a sintered R1-T-B based magnet work (where R1 is a rare-earth element; T is Fe, or Fe and Co); providing a powder of an alloy in which a rare-earth element R2 accounts for 40 mass % or more of the entire alloy, the rare-earth element R2 always including Dy and/or Tb; subjecting the powder to a heat treatment to obtain a diffusion source; and heating the sintered R1-T-B based magnet work with the diffusion source to allow the at least one of Dy and Tb contained in the diffusion source to diffuse from the surface into the interior of the sintered R1-T-B based magnet work. The alloy powder is a powder produced by atomization.
1. A method for producing a sintered R-T-B based magnet, comprising:
providing a sintered R1-T-B based magnet work, where R1 is a rare-earth element; T is Fe, or Fe and Co;
providing a powder of an alloy in which a rare-earth element R2 accounts for 40 mass % or more of the entire alloy, the rare-earth element R2 always including at least one of Dy and Tb;
subjecting the alloy powder to a heat treatment at a temperature which is not lower than a temperature that is 250° C. below a melting point of the alloy powder and which is not higher than the melting point, to obtain a diffusion source from the alloy powder; and
placing the sintered R1-T-B based magnet work and the diffusion source in a process chamber, and heating the sintered R1-T-B based magnet work and the diffusion source to a temperature which is not higher than a sintering temperature of the sintered R1-T-B based magnet work, to allow the at least one of Dy and Tb contained in the diffusion source to diffuse from the surface into an interior of the sintered R1-T-B based magnet work, wherein
the alloy powder is a powder produced by atomization and is composed of particles of an intermetallic compound having an average crystal grain size exceeding 3 μm.
2. The method for producing a sintered R-T-B based magnet of claim 1 , wherein an oxygen content in the diffusion source is not less than 0.5 mass % and not more than 4.0 mass %.
3. The method for producing a sintered R-T-B based magnet of claim 1 , wherein the alloy is an RHRLM1M2 alloy, where RH is one or more selected from the group consisting of Sc, Y, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, always including at least one of Tb and Dy; RL is one selected from the group consisting of La, Ce, Pr, Nd, Pm, Sm and Eu, always including at least one of Pr and Nd; and each of M1 and M2 is one or more selected from the group consisting of Cu, Fe, Ga, Co, Ni and Al, where possibly M1=M2.
4. The method for producing a sintered R-T-B based magnet of claim 1 , wherein the alloy is an RHM1M2 alloy, where RH is one or more selected from the group consisting of Sc, Y, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, always including at least one of Tb and Dy; and each of M1 and M2 is one or more selected from the group consisting of Cu, Fe, Ga, Co, Ni and Al, where possibly M1=M2.