Positive electrode active material slurry including rubber-based binder and positive electrode prepared therefrom
View Patent ↗The present invention relates to positive electrode active material slurry of which degree of non-crystallinity is controlled by including a rubber-based binder in a specific ratio, a positive electrode including a positive electrode active material layer formed therefrom, and a lithium secondary battery including the positive electrode. The positive electrode active material layer formed from the positive electrode active material slurry has enhanced flexibility and rolling property, and internal short circuits, high voltage defects and capacity decline of the lithium secondary battery using the positive electrode including the same are capable of being suppressed.
1. A method for preparing positive electrode active material slurry comprising:
1) preparing a pre-dispersion solution by mixing a first conductor and a first binder;
2) preparing a conductor and binder mixed solution by adding a second conductor and a second binder to the pre-dispersion solution and mixing the result; and
3) adding a positive electrode active material to the mixed solution and mixing the result.
2. The method for preparing positive electrode active material slurry of claim 1 , wherein the first conductor is a graphite-based conductor, and the graphite-based conductor is a carbon black-based material and has a specific surface area of 10 m 2 /g to 300 m 2 /g.
3. The method for preparing positive electrode active material slurry of claim 1 , wherein the second conductor is carbon nanotubes, carbon nanofibers or a combination thereof.
4. The method for preparing positive electrode active material slurry of claim 1 , wherein, as for the first conductor and the second conductor, the first conductor and the second conductor are used in amounts to have a weight ratio of 5:5 to 9:1 in the positive electrode active material slurry.
5. The method for preparing positive electrode active material slurry of claim 1 , wherein the first binder is a rubber-based binder, and the rubber-based binder is one or more types selected from the group consisting of nitrile-butadiene rubber, hydrated nitrile-butadiene rubber, styrene-butadiene rubber and hydrated styrene-butadiene rubber.
6. The method for preparing positive electrode active material slurry of claim 1 , wherein the second binder is a fluorine-based binder, and the fluorine-based binder is one or more types selected from the group consisting of substituted or unsubstituted polyvinylidene fluoride (PVDF), a vinylidene fluoride-hexafluoropropylene copolymer (PVDF-co-HEP), chlorotrifluoroethylene (CFTF) and polytetrafluoroethylene (PTFE).
7. The method for preparing positive electrode active material slurry of claim 1 , wherein, as for the first binder and the second binder, the first binder and the second binder are used in amounts to have a weight ratio of 3:7 to 8:2 in the positive electrode active material slurry.
8. The method for preparing positive electrode active material slurry of claim 1 , further comprising adding an organic solvent after the adding of positive electrode active material in the step 3).