Processes for preparing 2,5-furandicarboxylic acid and esters thereof
View Patent ↗A process for producing furan dicarboxylic acid or an ester thereof from a feedstock comprising hydroxymethyl furfural (HMF) and humins is disclosed. Humins are a byproduct from reactions forming HMF from sugars and are typically removed from the HMF prior to any further processing. A humins-containing HMF feedstock is utilized to produce furan dicarboxylic acids and ester substantially free from humins.
1. A process, comprising:
i) oxidizing a feedstock comprising hydroxymethyl furfural and humins in a solvent to produce a mixture comprising crude humins-containing 2,5-furan dicarboxylic acid; and
ii) filtering the mixture under a high temperature of from 50° C. to 275° C. to obtain a filtrate comprising 2,5-furan dicarboxylic acid having a content of 100 ppm or less of humins, wherein the 2,5-furan dicarboxylic acid is soluble in the solvent during the filtering.
2. The process of claim 1 , wherein the high temperature of the filtering step ii) is in the range of from 50° C. to 200° C.
3. The process of claim 1 , further comprising a step iii) crystallizing the 2,5-furan dicarboxylic acid having a content of 100 ppm or less of humins to obtain further purified 2,5-furan dicarboxylic acid.
4. The process of claim 1 , wherein the solvent is acetic acid or a mixture of acetic acid and water.